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161.
A. M. Flakina A. N. Chekhlov M. G. Kaplunov K. V. Van R. N. Lyubovskaya 《Russian Chemical Bulletin》2008,57(1):99-104
The new conducting radical cation salt, bis(ethylenedithio)tetrathiafulvalene cyanurate, was synthesized. This salt is an
organic metal down to 4 K. The crystal structure, conductivity, and optical properties of the salt were studied.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 96–101, January, 2008. 相似文献
162.
WANG Ling ZHANG Xiao-xia YUAN Hong-ming CHEN Yan DONG Zhong-ping PANG Guang-sheng FENG Shou-hua 《高等学校化学研究》2008,24(1):1-3
Cu2O particles with different morphologies and scales were prepared sonochemically on the solid-liquid interface of CuCl and water, by adjusting the reaction factors. The products were characterized by powder X-ray diffraction(XRD) and scanning electron microscopy(SEM). The formation and morphology of Cu2O crystals were influenced by high-intensity ultrasound, reaction temperature, and addition of CuCl. The results indicate that micrometer Cu2O was crystallized in cubic and octahedral shapes, whereas, nanometer Cu2O was not produced in well-shaped crystals. 相似文献
163.
The propagation of elastic waves is studied in a porous solid saturated with two immiscible viscous fluids.The propagation of three longitudinal waves is represented through three scalar potential functions.The lone transverse wave is presented by a vector potential function.The displacements of particles in different phases of the aggregate are defined in terms of these potential functions.It is shown that there exist three longitudinal waves and one transverse wave.The phenomena of reflection and refraction due to longitudinal and transverse waves at a plane interface between an elastic solid half-space and a porous solid half-space saturated with two immiscible viscous fluids are investigated.For the presence of viscosity in pore-fluids,the waves refracted to the porous medium attenuate in the direction normal to the interface.The ratios of the amplitudes of the reflected and refracted waves to that of the incident wave are calculated as a nonsingular system of linear algebraic equations.These amplitude ratios are used to further calculate the shares of different scattered waves in the energy of the incident wave.The modulus of the amplitude and the energy ratios with the angle of incidence are computed for a particular numerical model.The conservation of the energy across the interface is verified.The effects of variations in non-wet saturation of pores and frequencies on the energy partition are depicted graphically and discussed. 相似文献
164.
在轴向应力波传播和反射过程中弹性有限长圆柱壳非对称动态屈曲 总被引:2,自引:0,他引:2
本文讨论弹性有限长圆柱壳端部受冲击载荷作用,在轴向应力波传播和反射过程中的非对称动态屈曲问题。通过建立和求解扰动方程得到了动态屈曲的分叉条件,临界载荷和屈曲模态。数值结果表明:当壳壁厚不很薄时,轴对称屈曲临界载荷比非轴对称临界载荷高;反之,轴对称临界载荷会比非对称临界载荷低;由于应力波的反射,临界载荷降低,因而更容易发生屈曲,屈曲模态也有其不同特点。 相似文献
165.
气相爆轰波在分叉管中传播现象的数值研究 总被引:1,自引:0,他引:1
数值研究气相爆轰波在分叉管中的传播现象.用二阶附加半隐龙格-库塔法和5阶WENO格式求解二维欧拉方程,用基元反应描述爆轰化学反应过程,得到了密度、压力、温度、典型组元质量分数场及数值胞格结构和爆轰波平均速度.结果表明:气相爆轰波在分叉管中传播,分叉口左尖点的稀疏波导致诱导激波后压力、温度急剧下降,诱导激波和化学反应区分离,爆轰波衰减为爆燃波(即爆轰熄灭).分离后的诱导激波在垂直支管右壁面反射,并导致二次起爆.畸变的诱导激波在水平和垂直支管中均发生马赫反射.分叉口上游均匀胞格区和分叉口附近大胞格区的边界不是直线,其起点通常位于分叉口左尖点上游或恰在左尖点.水平支管中马赫反射三波点迹线始于右尖点下游.分叉口左尖点附近的流场中出现了复杂的旋涡结构、未反应区及激波与旋涡作用.旋涡加速了未反应区的化学反应速率.反射激波与旋涡作用并使旋涡破碎.反射激波与未反应区作用,加速其反应消耗,并形成一个内嵌的射流.数值计算得到的波系演变和胞格结构与实验定性一致. 相似文献
166.
研究了(Ti,Al)薄膜的光学特性,对其反射和透射光谱作了仔细分析。运用Hadley方程,算出一定成分(Ti,Al)N膜的折射率n,消光系数k随波长的变化关系。又根据透射曲线,计算出了(Ti,Al)N膜的光隙能。 相似文献
167.
168.
The quantum fluctuation of photon counting limits the field application of optical time domain reflection. A method of photon counts modulation optics time domain reflection with single photon detection at 1.55 μm is presented. The influence of quantum fluctuation can be effectively controlled by demodulation technology since quantum fluctuation shows a uniform distribution in the frequency domain. Combined with the changing of the integration time of the lock-in amplifier, the signal to noise ratio is significantly enhanced. Accordingly the signal to noise improvement ratio reaches 31.7 dB compared with the direct photon counting measurement. 相似文献
169.
传统磁镊的测量精度受限于磁球的布朗涨落, 当磁力小于约10 pN时, 磁球的布朗涨落明显增大, 对应磁镊的空间分辨率显著下降. 为了提高传统磁镊在小力条件下的测量精度, 本文将全内反射荧光技术引入到磁镊技术中, 并建立相适应的“磁球-手柄-荧光微球-待测生物分子”单分子连接系统, 在小力条件下(小于10 pN)获得纳米量级的测量精度. 应用改进的磁镊对DNA发卡的折叠-去折叠态的转变过程进行了研究, 依据DNA发卡的折叠-去折叠态转变的性质对全内反射场的穿透深度进行了校正, 并结合实验结果对改进后的磁镊的测量精度进行分析. 观察了Bloom解旋酶的解旋动力学过程, 获得初步实验结果, 证实了改进的磁镊在单分子研究中的实用性.
关键词:
磁镊
全内反射荧光
DNA发卡
解旋酶 相似文献
170.
The distinctive features of the atomic and electronic structure of thin surface layers of substances in the process of formation
of epitaxial silicon films on silicon are studied using the procedures of reflection and scattering of ultrasoft x-ray radiation.
The angular distribution of the scattered x-ray radiation (the scattering indicatrices) and the near fine structure of SiL2,3 spectra of reflection are investigated. The assumption of the sensitivity of the observed peak of anomalous scattering (the
Yoneda peak) of x-ray radiation to the presence, in the surface regions of the materials, of extended double-boundary defects,
the defects of packing, grain boundaries, dislocations, etc. is made. It is shown that the experimental procedure used makes
it possible to obtain information on the surface layers of substances.
Translated from Zhurnal Priklaldnoi Spektroskopii, Vol. 67, No. 4, pp. 496–498, July–August, 2000. 相似文献