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151.
An investigation into the rapid detection of mycotoxin-producing fungi on corn by two mid-infrared spectroscopic techniques was undertaken. Corn samples from a single genotype (RWA2, blanks, and contaminated with Fusarium graminearum) were ground, sieved and, after appropriate sample preparation, subjected to mid-infrared spectroscopy using two different accessories (diffuse reflection and attenuated total reflection). The measured spectra were evaluated with principal component analysis (PCA) and the blank and contaminated samples were classified by cluster analysis. Reference data for fungal metabolites were obtained with conventional methods. After extraction and clean-up, each sample was analyzed for the toxin deoxynivalenol (DON) by gas chromatography with electron capture detection (GC-ECD) and ergosterol (a parameter for the total fungal biomass) by high-performance liquid chromatography with diode array detection (HPLC-DAD). The concentration ranges for contaminated samples were 880–3600 g/kg for ergosterol and 300–2600 g/kg for DON. Classification efficiency was 100% for ATR spectra. DR spectra did not show as obvious a clustering of contaminated and blank samples. Results and trends were also observed in single spectra plots. Quantification using a PLS1 regression algorithm showed good correlation with DON reference data, but a rather high standard error of prediction (SEP) with 600 g/kg (DR) and 490 g/kg (ATR), respectively, for ergosterol. Comparing measurement procedures and results showed advantages for the ATR technique, mainly owing to its ease of use and the easier interpretation of results that were better with respect to classification and quantification. 相似文献
152.
CO和SCN~-在高分散Pt及Pd表面异常红外光学行为的电化学现场FTIR反射光谱研究 总被引:2,自引:0,他引:2
在玻碳基底上沉积Pt和Pd,在以CO和SCN-为探针分子的电化学现场FTIR反射光谱研究中,首次观察到异常红外光学行为,其中包括吸附物种的谱带方向倒反以及谱峰强度显著增强等. 相似文献
153.
A. M. Flakina A. N. Chekhlov M. G. Kaplunov K. V. Van R. N. Lyubovskaya 《Russian Chemical Bulletin》2008,57(1):99-104
The new conducting radical cation salt, bis(ethylenedithio)tetrathiafulvalene cyanurate, was synthesized. This salt is an
organic metal down to 4 K. The crystal structure, conductivity, and optical properties of the salt were studied.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 96–101, January, 2008. 相似文献
154.
WANG Ling ZHANG Xiao-xia YUAN Hong-ming CHEN Yan DONG Zhong-ping PANG Guang-sheng FENG Shou-hua 《高等学校化学研究》2008,24(1):1-3
Cu2O particles with different morphologies and scales were prepared sonochemically on the solid-liquid interface of CuCl and water, by adjusting the reaction factors. The products were characterized by powder X-ray diffraction(XRD) and scanning electron microscopy(SEM). The formation and morphology of Cu2O crystals were influenced by high-intensity ultrasound, reaction temperature, and addition of CuCl. The results indicate that micrometer Cu2O was crystallized in cubic and octahedral shapes, whereas, nanometer Cu2O was not produced in well-shaped crystals. 相似文献
155.
In situ scanning FTIR microscopy was built up for the first time in the present work, which consists of an FTIR apparatus, an IR microscope, an X-Y mapping stage, and the specially designed electrochemical IR cell and computer software. It has been demonstrated that this new space-resolvd in situ IR technique can be used to study vibration properties of micro-area, and to perform IR imaging of electrode surface. The chemical image obtained using this technique fur CO adsorption on Pt electrode illustrated, at a space-resolution of 10~(-2) cm, the inhomogeneity and the distribution of reactivity of micro-area of electrode surface. 相似文献
156.
有机-无机杂多酸类离子液体催化汽油超声氧化脱硫 总被引:2,自引:0,他引:2
合成了一系列有机-无机杂多酸类离子液体, 并将其应用于超声作用下的催化模拟汽油氧化脱硫反应. 结果表明, 在超声波辅助下, 不仅反应时间大大缩短, 而且脱硫效率也大幅提高. 在合成的一系列催化剂中, Zr0.25[BMIM]HPW12O40表现出最佳的催化活性. 考察了超声波功率、 超声/间隙时间、 催化剂用量、 H2O2用量、 反应温度及反应时间等因素对脱硫效果的影响. 以Zr0.25[BMIM]HPW12O40为催化剂, 在优化的条件下[n(Cat.)=0.008 mmol, V(H2O2)=40 μL, V(模拟油)=10 mL, V(乙腈)=1 mL, 温度25 ℃, 时间10 min, 超声功率300 W, 超声时间2 s, 间隙时间1.5 s], 二苯并噻吩(DBT)的脱硫率达到97.8%; 该催化剂循环使用5次后, 脱硫率仍为81.9%; 其对不同硫化物的催化活性顺序为DBT>4,6-二甲基苯并噻吩(4,6-DMDBT)>乙硫醚>苯硫醚>正丁硫醇>甲基苯基硫醚>苯并噻吩(BT)>噻吩. 相似文献
157.
在轴向应力波传播和反射过程中弹性有限长圆柱壳非对称动态屈曲 总被引:2,自引:0,他引:2
本文讨论弹性有限长圆柱壳端部受冲击载荷作用,在轴向应力波传播和反射过程中的非对称动态屈曲问题。通过建立和求解扰动方程得到了动态屈曲的分叉条件,临界载荷和屈曲模态。数值结果表明:当壳壁厚不很薄时,轴对称屈曲临界载荷比非轴对称临界载荷高;反之,轴对称临界载荷会比非对称临界载荷低;由于应力波的反射,临界载荷降低,因而更容易发生屈曲,屈曲模态也有其不同特点。 相似文献
158.
The propagation of elastic waves is studied in a porous solid saturated with two immiscible viscous fluids.The propagation of three longitudinal waves is represented through three scalar potential functions.The lone transverse wave is presented by a vector potential function.The displacements of particles in different phases of the aggregate are defined in terms of these potential functions.It is shown that there exist three longitudinal waves and one transverse wave.The phenomena of reflection and refraction due to longitudinal and transverse waves at a plane interface between an elastic solid half-space and a porous solid half-space saturated with two immiscible viscous fluids are investigated.For the presence of viscosity in pore-fluids,the waves refracted to the porous medium attenuate in the direction normal to the interface.The ratios of the amplitudes of the reflected and refracted waves to that of the incident wave are calculated as a nonsingular system of linear algebraic equations.These amplitude ratios are used to further calculate the shares of different scattered waves in the energy of the incident wave.The modulus of the amplitude and the energy ratios with the angle of incidence are computed for a particular numerical model.The conservation of the energy across the interface is verified.The effects of variations in non-wet saturation of pores and frequencies on the energy partition are depicted graphically and discussed. 相似文献
159.
气相爆轰波在分叉管中传播现象的数值研究 总被引:1,自引:0,他引:1
数值研究气相爆轰波在分叉管中的传播现象.用二阶附加半隐龙格-库塔法和5阶WENO格式求解二维欧拉方程,用基元反应描述爆轰化学反应过程,得到了密度、压力、温度、典型组元质量分数场及数值胞格结构和爆轰波平均速度.结果表明:气相爆轰波在分叉管中传播,分叉口左尖点的稀疏波导致诱导激波后压力、温度急剧下降,诱导激波和化学反应区分离,爆轰波衰减为爆燃波(即爆轰熄灭).分离后的诱导激波在垂直支管右壁面反射,并导致二次起爆.畸变的诱导激波在水平和垂直支管中均发生马赫反射.分叉口上游均匀胞格区和分叉口附近大胞格区的边界不是直线,其起点通常位于分叉口左尖点上游或恰在左尖点.水平支管中马赫反射三波点迹线始于右尖点下游.分叉口左尖点附近的流场中出现了复杂的旋涡结构、未反应区及激波与旋涡作用.旋涡加速了未反应区的化学反应速率.反射激波与旋涡作用并使旋涡破碎.反射激波与未反应区作用,加速其反应消耗,并形成一个内嵌的射流.数值计算得到的波系演变和胞格结构与实验定性一致. 相似文献
160.