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81.
82.
Cupric oxide is a p‐type semiconductor with a narrow band‐gap which is suitable for catalysis, electrochemical cells, field emission devices and gas sensor applications. Despite considerable efforts devoted to the preparation of the nanosized CuO, there is a lack of information about ultrasonic‐assisted (US) preparation methods. Nanosized cupric oxide was successfully prepared through different ultrasonic‐assisted (US) preparation methods. Furthermore, the influence of preparation method on the structure, morphology and optical properties of nanosized CuO has been reported. XRD patterns were identical to the single‐phase pure CuO with a monoclinic structure. The enhancement of the crystallinity and crystallite size was observed for the sample prepared through the US thermal decomposition. The absorption band of CuO nanocrystals prepared through the US liquid hydrolysis shows a clear red shift of about 40 nm compared to those obtained with other preparation methods. Our results indicated that almost spherical CuO nanoparticles with an average size of 65 nm were prepared during the US thermal decomposition, while CuO rod‐like nanostructures with an average diameter of about 16 nm were obtained via the US liquid hydrolysis method. The band gap values of nanosized CuO samples were larger than the reported value for the bulk CuO. Synthesized CuO samples by US methods with adjustable and controllable properties make the applicability of cupric oxide even more versatile. 相似文献
83.
M.A. BramantyaT. Sawada 《Journal of magnetism and magnetic materials》2011,323(10):1330-1333
Structure of magnetorheological (MR) fluids depends on the strength of the magnetic field applied and on the mode of its application. The ultrasonic wave propagation velocity changes under the effect of an external magnetic field as a result of formation of clusters arranged along the direction of the field in the MR fluids. Therefore, we propose a qualitative analysis of these clustering structures by measuring properties of ultrasonic propagation. Since the MR fluids are opaque, the non-contact inspection using this ultrasonic technique can be very useful. In this study, we measured ultrasonic propagation velocity in MR fluid influenced by an external magnetic field for different swept rate precisely. With increasing magnetic field intensity, the changes of the ultrasonic wave velocity are more pronounced. Sedimentation effect takes place in certain time for different swept rate due to magnetic particle size and it follows linear relationship in log scale. Significant differences of the ultrasonic wave velocity are established between the case when the field is swept at a constant rate and the case when it is stepped up. 相似文献
84.
R.K. Shukla Atul Kumar Alok Shukla Kirti Srivastava 《Journal of Molecular Liquids》2008,140(1-3):117-122
Density, ultrasonic velocity, surface tension, excess volume and viscosity of quaternary non-electrolyte solution n-pentane+tolune+n-heptane+cyclohexane has been experimentally determined at 25 °C over a wide range of composition. Assuming a quaternary fluid solution to be made of six binaries, a statistical approach of Prigogine–Flory–Patterson (PFP) theory has been extended to develop the expressions for dynamic viscosity, surface tension excess volume and ultrasonic velocity of quaternary fluid system. A reasonable agreement has been achieved between theory and experiment. An attempt has also bee made to explain the nature of molecular interactions involved in the light of excess thermodynamic functions whose sign and magnitude depend upon the chain length and size of the component fluids and also studied the role of order breakers (toluene and cyclohexane) on these properties. 相似文献
85.
酸浆宿萼总黄酮提取工艺的研究 总被引:1,自引:0,他引:1
采用乙醇浸泡法、回流提取法、超声提取法探讨了从酸浆宿萼中提取总黄酮类物质的最佳工艺.试验结果表明超声提取效果最好.其最佳条件是:用浓度为70%、按料液比1 : 30的比例的乙醇浸泡24 h,再用超声提取45 min,其宿萼中总黄酮类物质的提出率可达1.702 mg·g-1;对超声提取酸浆宿萼黄酮的浓缩液用聚酰胺树脂进行纯化.并通过样品的总黄酮与FeCl3、浓H2SO4.等试剂的特征反应对所得提取物进行了定性分析,确定了所得提取物为黄酮类物质. 相似文献
86.
回顾性分析了46例临床被证实为宫内胎物组织残留的病例。结果表明,流产后较长时间有不规则阴道流血,而作B超检查能发现特征性改变。声像图显示,子宫增大,宫内有异常光团和不规则液性暗区或宫腔局部膨隆,周边见很亮光条。认为诊断宫内残留组织,可以结合病只与声像技术较易诊断出来。本组超声诊断符合率达98%。对减少因宫内残留造成的子宫收缩不良、不规则阴道流血等现象,避免并发感染及导致绒癌发生等不良后果,有重要的 相似文献
87.
Various empirical theories of ultrasonic velocity have been applied to three binary liquid mixtures, under pressures up to
200 MPa and their validity have been tested. A pressure dependent study of ultrasonic velocities has been made at 303.15 K.
The agreement between theory and experiment is found to be quite satisfactory. 相似文献
88.
N. Herrmann Y. Hemar P. Lemaréchal D.J. McClements 《The European physical journal. E, Soft matter》2001,5(2):183-188
The flocculation of silicone oil-in-water emulsions ( φ = 0.1) containing quasi-monodisperse droplets was studied by ultrasound.
The ultrasonic attenuation spectra of emulsions with different particle sizes (200-1600 nm) were measured between 0.5 and
10 MHz using an interferometer. Flocculation was induced by adding excess sodium dodecyl sulphate micelles to the emulsions
to increase the attractive forces between the droplets. Droplet flocculation decreased the ultrasonic attenuation at low frequencies
because of overlap of the thermal waves caused by the close proximity of the droplets within the flocs. A mean-field model
which takes into account this effect was used to determine the droplet volume fraction within the flocs and thus to estimate
the distance between the droplets.
Received 17 July 2000 相似文献
89.
Bo-Chang Chen 《Applied Acoustics》2008,69(12):1299-1307
Sonar is extensively used in robot as a range sensor and the time-of-flight (TOF) information of ultrasonic echo is frequently adopted in sonar applications. This paper proposes a Jump-U model of ultrasonic echo pattern based on TOF data for a sonar ranging module. The model is established through a data regression method, utilizing TOF data and the relation between the delay time and the bearing angle of the sensor as input parameters. Because the proposed model can explain the jump phenomenon of TOF data and the shape of TOF data is similar to character U, the model is named as Jump-U. Moreover, the model includes several parameters, and one of them is intensity factor which can be regard as a relative strength of ultrasonic echo. Experiments are conducted to verify the proposed model by measuring the echo’s TOF data of a plane with distances ranging from 100 to 200 cm. The results show a close agreement between simulation and measurements. 相似文献
90.
Ultrasonic emulsification (USE) assisted by cavitation is an effective method to produce emulsion droplets. However, the role of gas bubbles in the USE process still remains unclear. Hence, in the present paper, high-speed camera observations of bubble evolution and emulsion droplets formation in oil and water were used to capture in real-time the emulsification process, while experiments with different gas concentrations were carried out to investigate the effect of gas bubbles on droplet size. The results show that at the interface of oil and water, gas bubbles with a radius larger than the resonance radius collapse and sink into the water phase, inducing (oil–water) blended liquid jets across bubbles to generate oil-in-water-in-oil (O/W/O) and water-in-oil (W/O) droplets in the oil phase and oil-in-water (O/W) droplets in the water phase, respectively. Gas bubbles with a radius smaller than the resonance radius at the interface always move towards the oil phase, accompanied with the generation of water droplets in the oil phase. In the oil phase, gas bubbles, which can attract bubbles nearby the interface, migrate to the interface of oil and water due to acoustic streaming, and generate numerous droplets. As for the gas bubbles in the water phase, those can break neighboring droplets into numerous finer ones during bubble oscillation. With the increase in gas content, more bubbles undergo chaotic oscillation, leading to smaller and more stable emulsion droplets, which explains the beneficial role of gas bubbles in USE. Violently oscillating microbubbles are, therefore, found to be the governing cavitation regime for emulsification process. These results provide new insights to the mechanisms of gas bubbles in oil–water emulsions, which may be useful towards the optimization of USE process in industry. 相似文献