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111.
112.
Summary Based on a thorough knowledge of the actual system precision significance testing of the primary eigen values, resulting from principal component analysis of the two-dimensional data array of HPLC with photodiode-array detection, is a powerful means to uncover unresolved chromatographic peaks. The implementation of this chemometric technique for assuring peak homogeneity and results showing the efficiency for two-component peaks in regard to spectral characteristics, chromatographic resolution and absorbance ratio of the investigated compounds are presented. 相似文献
113.
要 在集成光解电解一体化反应器中, 以邻氯酚(2-CP)为模型污染物, 通过产物和动力学分析详细探讨了光电复合作用的协同效应机理, 建立了光电复合作用的动力学模式. 表观动力学常数的对比表明复合协同作用对于总有机碳(TOC)的去除具有显著的协同效应. 研究表明, 光电复合作用在研究条件下对污染物的降解具有多层次、多途径的互补效应, 降解反应的途径不止是单独的光解与电解途径的简单累加, 而是通过新的作用途径组合构成光电协同效应. 通过紫外光辐射激发和定向直流电场作用控制电极中毒和污染物分子的激发态及其迁移趋势, 从而大大提高了降解反应的效率. 通过光电复合作用能够触发构成高级氧化的多种自由基链反应, 从而取得水中有机污染物的快速、完全的矿化. 动力学分析表明, 光电协同作用在溶液中形成的羟基自由基(OH·)反应是去除TOC的主要途径. 相似文献
114.
稀土离子(Gd3+,Eu3+)加载于纳米介孔ZrO2中的发光 总被引:2,自引:0,他引:2
水热合成法制备的高度有序多孔ZrO2具有规则六角排列,均匀纳米孔洞(约1.8nm),丰富的表面,界面态及比表面积和强的蓝-(近)紫外光发射,使其较常规体材料有更优异的性质,以稀土离子为探针,研究了Gd^3 ,Eu^3 在这些纳米微孔中的发光行为,结果表明,500摄氏度下,介孔ZrO2与稀土离子相作用并有效地将能量传递给稀土离子,增进稀土离子发光,而在ZrO2:Gd-Eu体系中,Gd^3 在ZrO2与Eu3 间起桥梁作用,使基质ZrO2→Eu^3 的能量传递更为有效。 相似文献
115.
116.
Xiaoping Zhan 《European Polymer Journal》2007,43(4):1588-1594
Oral clonidine, used as an antihypertensive, can result in some side effects such as dry mouth, drowsiness, dizziness and sedation; thus, clonidine transdermal drug delivery (TDD) was considered. Use of the controlled release membrane was one of the methods in TDD systems to regulate the permeation properties. A new type of copolymer membrane that controlled clonidine linear release in TDD system was synthesized by UV radiation. This membrane consisted of three monomers: 2-hydroxy-3-phenoxypropylacrylate, 4-hydroxybutyl acrylate and diethyl maleate. The membrane had both fine permeation properties and perfect physical properties when three monomers were in the weight ratio of 4:4:2; this type of membrane was chosen as an optimized membrane. It was found that the membrane controlled clonidine zero-order release, the permeation rates decreased with the thicknesses of membranes increasing, and the permeation rates were linearly dependent on the square root of the concentration of clonidine. Furthermore, the optimized membranes were characterized by FTIR, DSC and SEM. 相似文献
117.
This paper describes the screening for metabolites of butoprozine, a new anti-anginal drug, in dog bile by means of reverse-phase HPLC. Although it does involve a simple clean-up step to remove a substantial amount of endogenous bile compounds, this screening method nevertheless avoids extraction of metabolites and thus allows all metabolites to be introduced into the chromatographic system. A single run of 100 minutes from 100% water to 100% methanol in a linear gradient effects adequate separation of the great majority of metabolites without interference from remaining endogenous compounds. Two methods of differentiating between metabolite peaks and endogenous peaks have been worked out. The first one makes use of 14C-labeled butoprozine by measuring the amount of radioactivity in the column effluent while simultaneously recording the UV absorbance. The second method compares continuous gradient chromatograms of bile recorded before and after butoprozine administration under very similar conditions. The latter method can be applied to both radioactive and non-radioactive materials. 相似文献
118.
Guihua Huang Yipeng Huang Wei Xu Qiuhong Yao Xiaofang Liu Caifeng Ding Xi Chen 《中国化学快报》2019,30(5):1021-1023
Using cesium lead halide perovskite nanocrystals, CsPb(Cl/Br)_3, as a light absorber, we report a highly effective UV and blue light blocking film. The CsPb(Cl/Br)_3 nanocrystals are well dispersed in the ethyl cellulose(EC) matrix to compose a UV and blue light shielding film, and the absorption edge of the film is tunable by adjusting Cl to Br ratio using anion exchange. The CsPbCl_2 Br-EC film exhibits a transmittance of 5% at 459 nm, 90% at 478 nm and 95% in the range of 500–800 nm, which makes it excellent for UV and blue light shielding. In addition, the as-prepared EC-CsPb(Cl/Br)_3 film shows excellent photostability under UV irradiation. Results demonstrate that this EC-CsPb(Cl/Br)_3 based materials with sharp absorbance edges, tunable blocking wavelength, and high photostability can be useful for the applications in UV and blue light blocking and optical filters 相似文献
119.
LaAl3(BO3)4的合成及其晶体结构的研究 总被引:1,自引:3,他引:1
在研究LnAl3(BO3)(Ln=稀土元素,Y)的合成及发光特性过程中,发现镧铝硼酸盐LaAl3(BO3)4具有一种新的晶体结构。本文用助熔剂法合成了LnAl3(BO3)4(Ln=Gd,La)单晶样品,LaAl3(BO3)4为薄板状,而GdAl3(BO3)4为六方的棒状,用TREOR90程序对LaAl3(BO3)4粉末样品的X射线衍射数据进行了指标化,结果为:LaAl3(BO3)4属正交晶系,晶胞参数为a=0.93586(4)nm,b=0.79904(3)nm,c=0.40626(6)nm,V=0.34595nm^3,在1000℃空气环境下,用硝酸盐热分解法合成了单相LnAl3(BO3)4:E3 (Ln=Gd,La)荧光粉并研究了其发光特性,结果表明:LnAl3(BO3)4:Eu^3 (Ln=Gd,La)是非常有前途的等离子显示器用荧光粉。 相似文献
120.
Frank?WendlerEmail author Gerhard?Grane? Thomas?Heinze 《Cellulose (London, England)》2005,12(4):411-422
The thermal stability of cellulose/N-methylmorpholine-N-oxide (NMMO) solutions were investigated using UV/VIS spectrometry with a temperature programming cuvette and caloric measurements
by means of the Systag calorimeter RADEX (mini-autoclave). Both analytical methods allow to characterize the influences of
stabilizers and additives. With the temporal course of the optical density, temperature and pressure thermal runaway reactions
with gas evolution and accumulation of chromophoric degradation products were recognized. Kinetic model calculations compared
with UV/VIS measurements demonstrate the existence of autocatalytic reactions in cellulose/NMMO solutions. Varying the heating
rate autocatalysis can be proved by dynamic caloric measurements as well. 相似文献