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41.
Schiff碱水杨醛苯甲酰腙的特性 总被引:3,自引:1,他引:2
研究了 Schiff碱水杨醛苯甲酰腙 (简称 SBH)晶体在 DMSO及其 DMSO- H2 O的混合溶剂中的红外光谱 ,通过 SBH氘代前后的 IR对比发现 ,羟基氢质子与混合溶剂 DMSO- H2 O(3∶ 1 ,V/ V)产生较大的相互作用。向溶有 SBH的 75 % DMSO- 2 5 % H2 O的溶液滴加 KOH发现 ,SBH分子上的 C O羰基基团先与 KOH作用 ,其后与 O H 羟基基团作用 相似文献
42.
43.
Ildikó Mohammed-Ziegler Ferenc Billes 《Journal of inclusion phenomena and macrocyclic chemistry》2007,58(1-2):19-42
This review summarizes different applications of optical spectroscopic methods in calixarene chemistry including UV/Vis spectrometry,
vibrational spectroscopic techniques (FTIR and Raman spectroscopy), luminescence spectroscopy (including fluorescence and
phosphorescence), ellipsometry and various optical microscopic methods. Moreover, the results of theoretical studies (AM1,
PM3, DFT, ab initio, etc.) are summarized based on selected papers in the field of conformational studies, thermodynamics and complexation features.
About 300 references are processed systematically from the results reported mainly in the recent years with emphasis on the
potential of practical application of these molecules. 相似文献
44.
45.
Zh. D. Chaplanova Yu. K. Mikhailovskii V. E. Agabekov V. K. Ol’khovik N. A. Galinovskii E. A. Gracheva 《Journal of Applied Spectroscopy》2007,74(3):333-337
We have studied the spectral properties and morphology of thin films (TVD films) formed by thermal vacuum deposition of 4,4′-bis[(E)-1-(1,3-benzoxazol-2-yl)-2-ethenyl]-1,1′-biphenyl
and its substituted derivatives. We have shown that introducing bulky 2,2′-oxyhexyl substituents into the biphenyl units leads
to a shift of the fluorescence maximum for the TVD films toward shorter wavelengths, a decrease in their photostability, and
aggregation of the films during storage.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 3, pp. 300–303, May–June, 2007. 相似文献
46.
47.
脉冲染料激光器的可见光波段辐射通过共线倍频和非共线混频实现紫外波段的连续可调谐输出.本文报道了一种闭环跟踪方法;在调谐起始波长处,将取样光束在垂直相位匹配方向分割成等光强的两部分,然后在波长调谐时比较和平衡这两部分光强.对该方法在理论上作了分析并在实验中得到成功的验证.获得的自动跟踪效率大于90%. 相似文献
48.
The subject of spectral distribution methods where one derives and applies the locally smoothed forms of observables in nuclei
is briefly reviewed. It is well understood that the local forms (with respect to energy) of the level density function, expectation
values and strength densities are Gaussian, linear (or ratio of Gaussians) and a bivariate Gaussian respectively. To accomodate
symmetries in the above forms, one has to deal with multivariate distributions in general; for example the angular-momentum
(J) decomposition leads to a bivariate Gaussian form for the level density. These results extend to indefinitely large spaces
by method of partitioning and they generate convolution forms. The origin of these remarkable spectral properties is discussed
and shell model examples are given to substantiate their applicability to nuclear systems. Spectral distribution theory is
a practical, usable theory because the smoothed forms are defined in terms of traces of low particle-rank operators, and the
trace information propagates. Finally we discuss the application of the spectral methods for a wide range of nuclear problems;
these include binding energies, orbit occupancies, electromagnetic andβ-decay sum rule quantities, analysis of operators, symmetry breaking, numerical level densities, and determination of bounds
on time-reversal non-invariant part of nucleon-nucleon interaction. 相似文献
49.
Andreas Wallner Margit Hölbling Judith Baumgartner Christoph Marschner 《Silicon Chemistry》2007,3(3-4):175-185
A number of cyclo-and bicyclosilanes have been prepared and structurally characterized by X-ray crystallography and Raman
spectroscopy. 1,1,4,4- and 1,1,3,3-tetrakis(trimethylsilyl)octamethylcyclohexasilanes were found to exhibit unusual twist- and twisted boat-conformations. The UV absorption properties of all compounds were studied and found to show absorption maxima red shifted
compared to the parent compound dodecamethylcyclohexasilane.
Dedicated to Prof. Mitsuo Kira on the occasion of his reception of the Wacker Silicon Award 2005 and in recongnition of his
numerous outstanding achievements in organosilicon chemistry. 相似文献
50.
Anette Munch Elmr Patric Jannasch 《Journal of polymer science. Part A, Polymer chemistry》2006,44(7):2195-2205
Methacrylate‐functionalized poly(ethylene oxide‐co‐ethylene carbonate) macromonomers were prepared in two steps by the anionic ring‐opening polymerization of ethylene carbonate at 180 °C, with potassium methoxide as the initiator, followed by the reaction of the terminal hydroxyl groups of the polymers with methacryloyl chloride. The molecular weight of the polymer went through a maximum after approximately 45 min of polymerization, and the content of ethylene carbonate units in the polymer decreased with the reaction time. A polymer having a number‐average molecular weight of 2650 g mol?1 and an ethylene carbonate content of 28 mol % was selected and used to prepare a macromonomer, which was subsequently polymerized by UV irradiation in the presence of different concentrations of lithium bis(trifluoromethanesulfonyl)imide salt. The resulting self‐supportive crosslinked polymer electrolyte membranes reached ionic conductivities of 6.3 × 10?6 S cm?1 at 20 °C. The coordination of the lithium ions by both the ether and carbonate oxygens in the polymer structure was indicated by Fourier transform infrared spectroscopy. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2195–2205, 2006 相似文献