一种双臂型低温导热带的性能研究

详细介绍了低温导热带的设计特点。从理论上分析了低温导热带的冷量传输性能和减振特性,得到通过利用高导热率材料可以有效地减小导热温差和降温时间。通过实验验证了低温导热带与制冷机和高温超导滤波器的耦合实验,耦合温差为2.5K。实验结果和理论值基本吻合,分析了造成温差的原因。根据实验结果,提出了新的改进和实施方案。     

Syntheses, Crystal Structures and Magnetism of Two New Coordination Polymers [Ni（bix）2Cl2]n and [Co（bix）Cl2]n

The self-assembly reactions of MIICl2 (M = Ni, Co) with the flexible bix ligand [bix = 1,4-bis(imidazole-1-ylmethyl)benzene] yielded a 2D network [NiII(bix)2Cl2]n 1 and a 1D chain [CoII(bix)Cl2]n 2. Their crystal structures have been determined by X-ray single-crystal diffraction analysis. Complex 1 characters a two-dimensional grid-type structure and crystallizes in monoclinic, space group P21/c with a = 7.7231(7), b = 12.7787(9), c = 13.9374(13) , β = 105.419(4)o, C28H28Cl2N8Ni, Mr = 606.19, Ζ = 2, V = 1326.0(2) 3, Dc = 1.518 g/cm3, μ = 0.969 mm-1, F(000) = 628, R = 0.0429 and wR = 0.0783 for 2503 observed reflections (I > 2σ(I)). Compound 2 is a one-dimensional chain and crystallizes in orthorhombic, space group Pbca with a = 11.3696(6), b = 10.2128(6), c = 14.4943(9) , C14H14Cl2CoN4, Mr = 368.12, Z = 4, V = 1683.01(17) 3, Dc = 1.453 g/cm3, μ = 1.334 mm-1, F(000) = 748, R = 0.0317 and wR = 0.0800 for 1778 observed reflections (I > 2σ(I)). Magnetic properties of the title complexes were also investigated.     

DEPLOYMENT DYNAMICS OF FLEXIBLE SOLAR ARRAYS CONSIDERING FRICTIONAL JOINT

研究了空间漂浮航天器太阳阵展开与锁定过程的刚柔耦合动力学问题. 基于Jourdain 速度变分原理和单项递推组集方法, 建立了太阳阵展开与锁定过程的刚柔耦合多体系统动力学模型,采用虚功率原理推导了铰摩擦对系统动力学方程的贡献. 在以上动力学模型中引入3-D 鬃毛摩擦模型来研究铰链的摩擦特性对太阳阵展开动力学的影响. 所建动力学模型的正确性通过与商业软件ADAMS 和NASTRAN 的联合仿真对比得到了验证,该模型能够有效地预测太阳阵的展开历程以及航天器姿态的动态行为.     

A low-temperature X-ray diffraction study of the Cu2ZnSnSe4 thin films

Low-temperature XRD measurements were performed to confirm the phase composition and structural parameters of the electrochemically deposited Cu₂ZnSnSe₄ thin films on flexible metal substrates.     

改进的布谷鸟算法求解考虑运输时间的分布式柔性流水车间调度问题

针对分布式制造环境下多车间调度问题特点,结合企业实际生产情况,考虑相邻工序间的运输时间,建立以最小化最大完工时间为优化目标的分布式柔性流水车间调度模型,提出一种改进布谷鸟算法用于求解该模型。算法改进包括设计了一种基于工序、车间和机器的三层编码方案;根据问题特点设计了混合种群初始化策略以提高种群质量;改进了布谷鸟搜索操作使其适用于求解该模型;设计了一种种群进化策略以提高算法收敛速度及解的质量。最后通过仿真实验,与多种算法对比,验证所提算法的有效性和优越性。     

FLNG低温软管内衬波纹管多目标优化设计

低温柔性管道是海上浮式液化天然气生产储卸装置系统中输送液化天然气的核心装备之一。U型波纹管作为低温柔性管道最内层结构,直接影响低温管道的安全性。本文选取波径和环板长度作为独立结构设计参数进行结构分析,解决了在传统的U型波纹管灵敏度分析中,波高会随波距的改变而改变的耦合计算问题。构建了径向基函数神经网络代理模型,采用遗传算法对U型波纹管结构开展了多目标优化,获得以拉伸刚度最大和弯曲刚度最小为优化目标时的帕累托最优解集,为U型波纹管在实际工程应用中提供有益的设计参考。

     

Ultra-high Tg and ultra-low coefficient of thermal expansion polyimide films based on hydrogen bond interaction

To tolerate high processing temperature during the fabrication of low-temperature polycrystalline silicon thin-film transistors (LTPS–TFT) in flexible OLED devices, the polyimide (PI) films, which are used as substrate, should have ultra-high glass transition temperature (T_g > 450°C) and ultra-low coefficient of thermal expansion (CTE at 0–5 ppm K⁻¹). In this paper, two novel heterocyclic monomers, namely, N,N'-(xanthone-2,7-diyl)bis(4-aminobenzamide) (p-DAXBA) and N,N'-(xanthone-2,7-diyl)bis(3-aminobenzamide) (m-DAXBA), which contain a xanthone moiety, are prepared and polycondensed with pyromellitic dianhydride (PMDA), respectively. PI films (PIa and PIb) with intrinsic high T_g and low CTE are designed from the perspective of rigid conjugate xanthone structure and hydrogen bonding interaction. It is found that the PIa films prepared by p-DAXBA have better linear structure of molecular chains and show relatively higher T_g and lower CTE. The T_g of PIa-40 is greater than 450°C, and CTE can reach as low as 2.7 ppm K⁻¹, tensile strength of 179 MPa, modulus of 5.67 GPa, indicating potential application prospect as a flexible OLED substrate.     

Fabrication of Carbon Nanotube Thin Films for Flexible Transistors by Using a Cross-Linked Amine Polymer

Owing to their remarkable properties, single-walled carbon nanotube thin-film transistors (SWCNT-TFTs) are expected to be used in various flexible electronics applications. To fabricate SWCNT channel layers for TFTs, solution-based film formation on a self-assembled monolayer (SAM) covered with amino groups is commonly used. However, this method uses highly oxidized surfaces, which is not suitable for flexible polymeric substrates. In this work, a solution-based SWCNT film fabrication using methoxycarbonyl polyallylamine (Moc-PAA) is reported. The NH₂-terminated surface of the cross-linked Moc-PAA layer enables the formation of highly dense and uniform SWCNT networks on both rigid and flexible substrates. TFTs that use the fabricated SWCNT thin film exhibited excellent performance with small variations. The presented simple method to access SWCNT thin film accelerates the realization of flexible nanoelectronics.     

Flexible and Epitaxial Metal Oxide Thin Film Growth by Photoreaction Processing for Electrical and Optical Applications

This review summarizes the use of photoreactions that replace conventional heating processes for growing oxide thin films from chemical solutions. In particular, this review outlines key variables in photoreactions that affect epitaxial and polycrystalline thin film growth, including precursor materials, laser wavelength, laser fluence, and carbon. In addition, the features of the photoreaction process that can be controlled at a low temperature by oxygen non-stoichiometry are examined. Likewise, functions that are neither achieved by developing a gradient structure nor controlled by a thermal equilibrium reaction are detailed. Two new concepts are presented, known as photoreaction of nanoparticles (PRNP) and photoreaction of a hybrid solutions (PRHS), in which crystal nuclei are pre-dispersed in a metal–organic compound film. This method has successfully produced flexible phosphor films used as resistor or thermistor electronic components. Finally, thin film growth using different light sources such as flash lamps and femtosecond lasers (fs) is explored.     

Light/Electricity Energy Conversion and Storage for a Hierarchical Porous In2S3@CNT/SS Cathode towards a Flexible Li-CO2 Battery

A photoinduced flexible Li-CO₂ battery with well-designed, hierarchical porous, and free-standing In₂S₃@CNT/SS (ICS) as a bifunctional photoelectrode to accelerate both the CO₂ reduction and evolution reactions (CDRR and CDER) is presented. The photoinduced Li-CO₂ battery achieved a record-high discharge voltage of 3.14 V, surpassing the thermodynamic limit of 2.80 V, and an ultra-low charge voltage of 3.20 V, achieving a round trip efficiency of 98.1 %, which is the highest value ever reported (<80 %) so far. These excellent properties can be ascribed to the hierarchical porous and free-standing structure of ICS, as well as the key role of photogenerated electrons and holes during discharging and charging processes. A mechanism is proposed for pre-activating CO₂ by reducing In³⁺ to In⁺ under light illumination. The mechanism of the bifunctional light-assisted process provides insight into photoinduced Li-CO₂ batteries and contributes to resolving the major setbacks of the system.