Crystal Structure of Dimeric Units Cd2（ncpo）2（phen）2（H2O）2 Constructed by Flexible Dicarboxylic Acid with Fluorescent Emission

A dimeric coordination complex Cd2（ncpo）2（phen）2（H2O）2 was constructed by a flexible dicarboxylic acid, 2-nitro-4-carboxylphenoxyacetic acid. Its crystal structure was determined by X-ray single-crystal diffraction analysis. The crystal is of monoclinic system, space group P21/n with a = 17.2616（3）, b = 12.7460（2）, c = 18.4041（3） A^°, β= 94.432（1）°, C42H30Cd2N6O16, Mr = 1099.52, V = 4037.09（12）A^°^3 Dc = 1.809 g/cm^3, F（000） = 2192, μ = 1.139 cm^-1 and Z = 4. The final R = 0.0218 and wR = 0.0703 for 8288 observed reflections with I 〉 2σ（I）. There are two crystallographically independent but structurally very similar molecules in the unit cell of the title complex. It is noticeable that the ligand ncpo^2- displays a good flexibility, demonstrating different modes from the rigid ligands. The luminescence property has been investigated, which shows photoluminescence at 465, 490 and 574 nm upon excitation at 320 nm in the solid state at room temperature.     

配位聚合物[Zn(PDA)(obix)]的合成、晶体结构和荧光性质

Hydrothermal reaction between 1,4-phenylenediacetic acid (H₂PDA) and Zn(NO₃)₂·6H₂O at the presence of the second ligand of 1,2-bis((1H-imidazol-1-yl) methyl)benzene (obix) yields a new 2D metal-organic coordination polymer [Zn(PDA)(obix)] (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermal analysis. Complex 1 presents a two-dimensional (2D) sheet structure and displays strong luminescent emission at room temperature. CCDC: 716984.     

基于柔性硫醚与Cu2Br2单元二维配位聚合物的合成、结构和荧光性质

A complex [Cu₂Br₂(L)₂]_n(1) (L=bis(2-pyrimidinylthio)methane) has been synthesized and structurally characterized. Complex 1 contains dinuclear Cu₂Br₂ units, which are linked by ditopic L to form a 2D layer structure with a 36-membered macrometallocycle. The adjacent layers are further connected through interpyrimidyl rings C-H…N and π-π interactions to give rise to a three-dimensional supramolecular structure. Complex 1 also displays strong green solid-state photoluminescence, due to metal-to-ligand charge-transfer (MLCT) at room temperature. CCDC: 711434.     

A novel electromagnetism‐assisted imprinting technology to replicate microstructures onto a large‐area curved surface using a flexible magnetic mold

Replication of microstructures from a mold onto a curved surface is difficult. The conformal contact between the mold and the substrate has to be ensured. The present study proposes an innovative mechanism, which employs an electromagnetic disk to provide magnetic force and a PDMS flexible mold with a layer compounded magnetic powder. This mechanism provides not only the gradual contact from center to edge to avoid air entrapment but also conformal contact between the mold and the substrate during the imprinting operation. A system based on this electromagnetic soft imprinting technology has been implemented, and imprinting to replicate microstructures from the mold onto a curved surface has been carried out. The results reveal that the PDMS magnetic mold and the electromagnetic disk‐controlled magnetic force can successfully perform the imprinting and accurately replicate the microstructures onto the large‐area, curved surface glass. The PDMS flexible magnetic mold incorporated with the magnetic disk can be employed to achieve the conformal contact between the mold and the substrate. In addition, due to the low surface free energy of the PDMS, the de‐molding without sticking can be easily accomplished. Copyright © 2008 John Wiley & Sons, Ltd.     

柔性曲梁多体系统的研究现状和展望

本文对近几年来柔性多体系统建模理论的研究进展进行了评述, 详细阐述了曲梁结构多体系统动力学研究的理论背景和工程意义. 结合连续介质力学和多体系统动力学理论, 介绍了平面曲梁、空间曲梁应变位移场的描述以及几何非线性问题研究现状. 通过国内外文献及已有的研究, 综述了现有曲梁的离散化方法, 以及这些方法对于定曲率、变曲率曲梁的适用性. 然后, 总结了曲梁刚柔耦合动力学建模和数值计算中的难点问题, 介绍了平面曲梁、空间曲梁实验研究的现状. 最后, 综合全文, 提出了目前研究存在的难点问题, 以及计划解决这些难点问题的方法.      

柔性多体碰撞问题的多变量方法

针对柔性多体系统碰撞问题的特点, 提出了柔性多体系统碰撞问题的多变量方法. 在未碰撞阶段和分离后的阶段, 多变量方法考虑了物体大范围运动与变形的耦合.在碰撞阶段, 考虑非碰撞区域的变形, 对非碰撞区域用浮动参考系方法求解, 对发生碰撞的局部区域用非线性有限元方法求解. 非碰撞区域采用浮动基位形坐标和柔性体相对浮动基的变形模态坐标描述, 大大减缩了变量的维数,提高了计算效率. 碰撞局部区域采用非线性有限元节点坐标描述, 可以得到碰撞局部区域高精度的应力、应变响应, 而且可以反映碰撞局部区域的大变形、塑性等非线性响应. 该方法既能体现碰撞对系统大范围运动和长期动力学仿真的影响, 又能精确反映出碰撞发生的微小时间段内物体碰撞局部区域的应力、应变响应, 表现出碰撞过程中物体接触区域的演化历程.介绍了两杆正碰撞与铅垂面内双摆撞击自由圆盘的算例, 设计了两柔性杆正碰撞实验,多变量方法的数值仿真结果与实验测量结果很好地吻合.      

A HIGH-ORDER RIGID-FLEXIBLE COUPLING MODEL OF A ROTATING FLEXIBLE BEAM UNDER LARGE DEFORMATION

对在平面内做大范围转动的中心刚体-柔性梁系统的刚柔耦合建模理论进行了深入研究,建立了系统的高次耦合动力学模型. 该动力学模型考虑了柔性梁横向弯曲变形和纵向伸长变形,且在纵向位移中计及由于横向变形而引起的纵向缩短项,即非线性耦合变形项,并保留了与非线性耦合项相关的一些高阶项,最终得到了系统的高次刚柔耦合动力学方程. 由此得到的动力学方程不仅能适用于柔性梁的小变形问题,也同样适用于大变形问题,弥补了一次近似耦合模型在处理柔性梁大变形问题上的不足. 通过与绝对节点坐标法以及一次近似耦合模型的对比验证了高次耦合模型的正确性.     

DYNAMIC SUBSTRUCTURE METHOD FOR PROPAGATION OF ELASTIC-PLASTIC WAVE INDUCED BY IMPACT

通过建立弹塑性碰撞动态子结构模型,推导了模态坐标下的控制方程,提出了模拟柔性结构碰撞激发弹塑性波传播的动态子结构方法,并对其中的主模态的存在性和主模态截断的收敛性进行了证明.通过对柔性杆纵向碰撞和柔性梁横向碰撞两个算例的计算,并将计算结果与理论解和三维动力有限方法计算结果进行了对比,验证了该方法的数值收敛性和计算碰撞弹塑性波传播的有效性.     

Review of flexible and transparent thin-film transistors based on zinc oxide and related materials

Flexible and transparent electronics enters into a new era of electronic technologies.Ubiquitous applications involve wearable electronics,biosensors,flexible transparent displays,radio-frequency identifications(RFIDs),etc.Zinc oxide(ZnO) and relevant materials are the most commonly used inorganic semiconductors in flexible and transparent devices,owing to their high electrical performances,together with low processing temperatures and good optical transparencies.In this paper,we review recent advances in flexible and transparent thin-film transistors(TFTs) based on ZnO and relevant materials.After a brief introduction,the main progress of the preparation of each component(substrate,electrodes,channel and dielectrics) is summarized and discussed.Then,the effect of mechanical bending on electrical performance is highlighted.Finally,we suggest the challenges and opportunities in future investigations.