一类单参数假设检验拒绝域的直观构造法

本文提出直观法的理论 ,举出用直观法构造单参数假设检验拒绝域的应用实例 ,并得出构造形如 ( * )式的检验拒绝域的一种方法     

Ni~(2+):CsMgCl_3的光学吸收谱和EPR的研究

应用三角晶场中d2 (d8)电子组态包括静电相互作用和自旋 轨道耦合作用的强场能量矩阵 ,采用完全对角化方法 ,精确地计算了具有D3d 对称的Ni2 + :CsMgCl3 的光学吸收谱和EPR谱。理论结果与实验值符合得很好。     

电场线的三维演示现象的机理研究

本文对电场线的三维演示新方法进行机理分析，为实验提供理论依据。     

Cross-validation and the smoothing of orthogonal series density estimators

We describe a class of smoothed orthogonal series density estimates, including the classical sequential-series introduced by [6], Soviet Math. Dokl. 3 1559–1562) and [16], Ann. Math. Statist. 38 1261–1265), and [23], Ann. Statist 9 146–156) two-parameter smoothing. The Bowman-Rudemo method of least-squares cross-validation (1982, Manchester-Sheffield School of Probability and Statistics Research Report 84/AWB/1; 1984, Biometrika 71 353–360; [14], Scand. J. Statist. 9 65–78), is suggested as a practical way of choosing smoothing parameters automatically. Using techniques of [18], Ann. Statist. 12 1285–1297), that method is shown to perform asymptotically optimally in the case of cosine and Hermite series estimators. The same argument may be used for other types of series.     

Parameter estimation of ordinary differential equations

This paper addresses the development of a new algorithm forparameter estimation of ordinary differential equations. Here,we show that (1) the simultaneous approach combined with orthogonalcyclic reduction can be used to reduce the estimation problemto an optimization problem subject to a fixed number of equalityconstraints without the need for structural information to devisea stable embedding in the case of non-trivial dichotomy and(2) the Newton approximation of the Hessian information of theLagrangian function of the estimation problem should be usedin cases where hypothesized models are incorrect or only a limitedamount of sample data is available. A new algorithm is proposedwhich includes the use of the sequential quadratic programming(SQP) Gauss–Newton approximation but also encompassesthe SQP Newton approximation along with tests of when to usethis approximation. This composite approach relaxes the restrictionson the SQP Gauss–Newton approximation that the hypothesizedmodel should be correct and the sample data set large enough.This new algorithm has been tested on two standard problems.     

Flow of viscoelastic fluids between plates rotating about distinct axes

We discuss the flow of BKZ fluids in an orthogonal rheometer. Some analytical results are proved, and numerical solutions are obtained for the Currie model. These solutions show a boundary layer behavior at high Reynolds numbers and the possibility of discontinuous solutions or nonexistence at high Weissenberg numbers.     

Mathematical Relationships Between Bond-Bending Force Fields

Molecular mechanics softwares adopt various set of force field functions. In some cases, reliable data from one set of force field parameters cannot be used in a software that adopts another set of force field. Using mathematical approach, exact relationships between parameters from three bond-bending force fields, namely the (i) harmonic cosine angle, (ii) polynomial series, and (iii) Fourier series, are herein developed. Parameters from these three potential functions are further related to the approximate form, the harmonic angle function, which is valid for small change in chemical bond angle.