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71.
M. Gutowski I. Dabkowska J. Rak S. Xu J.M. Nilles D. Radisic K.H. Bowen Jr 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(3):431-439
The photoelectron spectra (PES) of anions of uracil-glycine and uracil-phenylalanine complexes reveal broad features with
maxima at 1.8 and 2.0 eV. The results of ab initio density functional B3LYP and second order M?ller-Plesset theory calculations indicate that the excess electron occupies a
π* orbital localized on uracil. The excess electron attachment to the complex can induce a barrier-free proton transfer (BFPT)
from the carboxylic group of glycine to the O8 atom of uracil. As a result, the four most stable structures of the anion of
uracil-glycine complex can be characterized as the neutral radical of hydrogenated uracil solvated by the anion of deprotonated
glycine. The similarity between the PES spectra for the uracil complexes with glycine and phenylalanine suggests that the
BFPT is also operative in the case of the latter anionic species. The BFPT to the O8 atom of uracil may be related to the
damage of nucleic acid bases by low energy electrons because the O8 atom is involved in a hydrogen bond with adenine in the
standard Watson-Crick pairing scheme.
Received 6 April 2002 Published online 13 September 2002 相似文献
72.
T.M. Mishonov N. Chéenne D. Robbes J.O. Indekeu 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(3):291-296
The generation of harmonics of the voltage response is considered when an AC current is applied through a superconducting
film above Tc. It is shown that almost at all temperatures the mechanism of the temperature oscillations created by the AC current and
the temperature dependence of the resistance dominates over the isothermal nonlinear electric conductivity. Only in a narrow
critical region close to Tc the latter is essential for the generation of the harmonics. A detailed investigation of harmonics generation provides an
accurate method for measuring the thermal boundary conductance between the film and the insulating substrate. The critical
behaviour of the third harmonic will give a new method for the determination of the lifetime of metastable Cooper pairs above
Tc. The comparison of the calculated fifth harmonics of the voltage with the experiment is proposed as an important test for
the applicability of the employed theoretical models.
Received 8 September 2001 相似文献
73.
Necessary and sufficient conditions in constrained optimization 总被引:22,自引:0,他引:22
Additional conditions are attached to the Kuhn-Tucker conditions giving a set of conditions which are both necessary and sufficient
for optimality in constrained optimization, under appropriate constraint qualifications. Necessary and sufficient conditions
are also given for optimality of the dual problem. Duality and converse duality are treated accordingly. 相似文献
74.
In this paper, we first reduce the problem of finding a minimum parity (g,f)-factor of a graph G into the problem of finding a minimum perfect matching in a weighted simple graph G*. Using the structure of G*, a necessary and sufficient condition for the existence of an even factor is derived.
This paper was accomplished while the second author was visiting the Center for Combinatorics, Nankai University.
The research is supported by NSFC 相似文献
75.
76.
Changbing Hu 《Journal of Differential Equations》2007,236(1):133-163
In this article we study the 3D Navier-Stokes equations with Navier friction boundary condition in thin domains. We prove the global existence of strong solutions to the 3D Navier-Stokes equations when the initial data and external forces are in large sets as the thickness of the domain is small. We generalize the techniques developed to study the 3D Navier-Stokes equations in thin domains, see [G. Raugel, G. Sell, Navier-Stokes equations on thin 3D domains I: Global attractors and global regularity of solutions, J. Amer. Math. Soc. 6 (1993) 503-568; G. Raugel, G. Sell, Navier-Stokes equations on thin 3D domains II: Global regularity of spatially periodic conditions, in: Nonlinear Partial Differential Equations and Their Application, College de France Seminar, vol. XI, Longman, Harlow, 1994, pp. 205-247; R. Temam, M. Ziane, Navier-Stokes equations in three-dimensional thin domains with various boundary conditions, Adv. Differential Equations 1 (1996) 499-546; R. Temam, M. Ziane, Navier-Stokes equations in thin spherical shells, in: Optimization Methods in Partial Differential Equations, in: Contemp. Math., vol. 209, Amer. Math. Soc., Providence, RI, 1996, pp. 281-314], to the Navier friction boundary condition by introducing a new average operator Mε in the thin direction according to the spectral decomposition of the Stokes operator Aε. Our analysis hinges on the refined investigation of the eigenvalue problem corresponding to the Stokes operator Aε with Navier friction boundary condition. 相似文献
77.
A new sample business survey for agriculture, the REA survey, and a project of integration with the FADN network (RICA in
Italy) have significantly changed the production of statistical information nowadays available with reference to the agricultural
sector. On the basis of this relevant information, new economic analyses are being developed on farms’ performance, agricultural
households’ income and the Common Agricultural Policy (CAP). In this paper the authors estimate the relationship between the
levels of variables of interest and their sampling errors using models in order to improve the accessibility of the information
on estimates accuracy to the final users (agricultural analysts, policy makers).
The paper is the result of a joint research of the three authors. Sections 1–3 and 6 by Pizzoli, Sects. 4 and 5 by Rondinelli,
Sect. 7 by Filiberti, conclusions joint to the three authors. 相似文献
78.
Jan P. Boroński 《Topology and its Applications》2007,154(18):3156-3166
A set (or a collection of sets) contained in the Euclidean space Rm is symmetric if it is invariant under the antipodal map. Given a symmetric unicoherent polyhedron X (like an n-dimensional cube or a sphere) and an odd real function f defined on vertices of a certain symmetric triangulation of X, we algorithmically construct a connected symmetric separator of X by choosing a subcollection of the triangulation. Each element of the subcollection contains the vertices v and u such that f(v)f(u)?0. 相似文献
79.
We investigate separability questions for the mapping class group of a surface. While this group is not subgroup separable in general, we prove a large family of interesting subgroups are separable. This includes many classically studied subgroups such as solvable subgroups, Heegaard and Handlebody groups, geometric subgroups, and all the terms in the Johnson filtration. 相似文献
80.
New criteria are provided for determining whether an integral representation of a stable process is minimal. These criteria are based on various nonminimal sets and their projections, and have several advantages over and shed light on already available criteria. In particular, they naturally lead from a nonminimal representation to the one which is minimal. Several known examples are considered to illustrate the main results. The general approach is also adapted to show that the so-called mixed moving averages have a minimal integral representation of the mixed moving average type. 相似文献