Characterization of cyclodextrin-modified infrared chemical sensors: Part I. Modeling the mechanisms of interaction

To explore the properties of cyclodextrins (CDs) as an optical sensing phase, the behavior of immobilized CD in interaction with analytes was studied in this work. CDs having different cavity sizes were immobilized onto the surface of infrared (IR) internal reflection-sensing element (IRE) to kinetically monitor the behavior of CD in interaction with analytes. Several aromatic compounds having various molecular sizes and functional groups were used to characterize the interaction mechanism. A two-layer modification method was proposed in this work, which utilized a thin hydrophobic film (polyvinyl benzyl chloride) to stick on the IRE and to covalently bond to the CDs through an ethylene diamine linker. The synthesized CD phases exhibited high stability in aqueous solution. To analyze the behavior during the formation of complexes between the guest molecules and the CD phases, we modeled the interaction behavior and treated the kinetic data with the theoretical equations developed in this work. The results indicate that the behavior of the interaction between guest molecules and CDs was explained by considering the formation of two types of complexes: adsorbed complexes and inclusion complexes. The formation of the inclusion complexes was relatively fast, the time required to reach equilibrium could be shorter than a few minutes. The adsorbed complexes were also observed, but their rate of formation was relatively slow; equilibrium could be reached at times greater than 60 min. Based on the signals observed under equilibrium conditions, the concentration of inclusion complexes was approximately three times than that of the adsorbed complexes.     

Quarter wave plates for submillimeter wavelengths

A review is given of different types of quarter wave plates as presently used in the optical and microwave spectral range, with a view to their application in the sub-mm wave-length range. Two types of quarter wave plates have been constructed and results of measurements at 640m are given.     

基于有限元模拟的超声应力系数标定及分析*

应力系数的标定作为超声应力检测最为关键的环节,直接决定应力检测结果的准确性。传统的应力系数试验标定对于被测物的表面粗糙度、耦合剂厚度、声匹配块与被测物接触力等因素十分敏感,但缺少基本参照值。基于COMSOL建立多物理场耦合的超声应力检测模型,施加不同的拉伸载荷,计算临界折射纵波到达时间与不同应力值之间的关系,模拟标定45#钢的超声应力系数为13.7MPa/ns。单轴水平拉伸试验标定的45#钢应力系数为16.5MPa/ns。结果表明,通过两种方法标定的应力系数较为接近,试验标定的应力系数偏大,这是由于有限元方法能够消除试验过程中各种不确定因素对声时精确测量所造成的影响,能够更加纯粹的反映材料的声弹性效应,因此具有作为基础数据的参考价值。有限元方法作为传统试验方法的补充,可以减小试验标定数据的离散性,提高超声应力检测结果的可信度。     

基于四水听器的充水弹性管声速测量方法*

实验室中水声材料声学参数的测量主要在水声声管中进行。管内平面波声速是正确测量这些参数的基础。该文提出一种基于四水听器结合不同边界的测量充水弹性管中声速的新方法。该方法利用4个固定位置处的水听器,采用最小二乘的方法,使得两组水听器分别得到的声管末端入射波声压差值的平方最小的声速即为管内平面波声速。该方法利用单频信号,在每一频率点均可测得声速,可以在任一种声管末端边界下进行测量,同时无需知道各水听器到边界的精确距离,在文中的3种边界下声速测量结果具有很好的一致性,实验操作简单、误差很小。该方法的仿真结果与管内声速的理论值吻合得很好,同时实验测量结果与仿真值之间的误差很小,证明了方法的准确性以及鲁棒性,为声管声速测量提供一个很好的思路。     

左手材料设计及透明现象研究进展

左手材料具有负的介电常数, 磁导率和折射率,它与电磁波相互作用的规律与传统材料有本质的区别.首先讨论了金属线点阵结构实现负介电常数和开口谐振环点阵结构实现负磁导率的内在机理,综述了目前实现左手材料的设计与制备方法,讨论了左手材料研究中能量如何定义以满足守恒律, 左手材料的宏观等效参数的确定,以及影响左手材料负折射相对频带带宽的因素。最后对左手材料在光子隧道效应和电磁波透明方面的应用进行了介绍,重点讨论了利用力学中的``中性夹杂'概念对电磁波透明的设计.论文还探讨了声波左手材料的概念和物理意义,介绍了用声波左手材料实现声波透明的方法.      

A New Trial Equation Method and Its Applications

As an improved version of trial equation method, a new trial equation method is proposed. Using this method, abundant new exact traveling wave solutions to a high-order KdV-type equation are obtained.     

孔梯度陶瓷纤维复合膜管的制备及特性

陶瓷过滤管具有孔隙率高、耐腐蚀、耐高温、机械强度高、便于清洗、使用寿命长等优点,是高温烟尘处理用的高效过滤元件.本文研制了一种具有梯度孔结构堇青石陶瓷纤维复合膜过滤元件,该过滤元件是由多孔支撑体、过渡层和分离膜层组成.其中支撑体、过渡层和分离层的气孔率分别为35～40;、50～60;和60～70;.文中主要分析了孔梯度陶瓷纤维复合膜管的材料结构和抗热震性能,同时对复合膜管进行含尘气体过滤的冷态模拟试验.对于烟气中粒径大于或等于0.1μm的颗粒,复合膜管的截留率达到99.8;以上.     

辐射在CH泡沫中传输的数值模拟

利用一维多群辐射输运程序对辐射在CH泡沫中的传输过程进行了数值模拟,给出一些细致的物理图像和定量结果。在一定的入射辐射流条件下,密度变化对辐射传输特征、辐射加热介质的热力学平衡弛豫过程有重要影响。随着密度下降,辐射由亚声速传输转变为超声速传输,辐射在传输过程中的能谱形状也不同。     

利用“神光-Ⅱ”激光装置多路光束叠加直接驱动下的冲击波平面性及稳定性

利用“神光-Ⅱ”的3路基频光输出及小透镜列阵束匀滑技术,通过优化设计和合理地选择光路组合,实现了多路叠加斜入射的驱动激光, 在靶材料中产生一个650~750μm范围内平面性良好的冲击波,有效地提高了“神光-Ⅱ”输出光束的利用率。同时,利用斜面靶进行的冲击稳定性实验表明,在靶面功率密度分别为3.26×1014及2.56×1014W/cm2时,冲击波至少在28.38~55.82和22.13~35.07μm的Al样品厚度内是稳定传播的。     

过模慢波结构频率反射特性及谐振腔的影响

利用有限元方法求解:S-参数矩阵,研究了过模慢波结构对圆波导TM01,TM02模的反射特性,分析了在慢波结构末端加入谐振腔后,由于两端口的不对称性而造成的对反射特性影响。结果表明,在TM01的π模频率附近,慢波结构和谐振腔组成的系统对无谐振腔一侧端口入射TM01模的反射增大,而对有谐振腔一侧端口入射TM01模的反射减小。根据计算结果,解释了普通多波切伦柯夫振荡器所用慢波结构周期数较多的原因,说明了在多波切伦柯夫振荡器中引入谐振腔后,不但可以减少所用慢波结构周期数,而且有利于提高微波输出效率。