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61.
Considering a system ofN identical interacting particles, which obey Fermi-Dirac or Bose-Einstein statistics, we derive new formulas for correlation functions of the type
(whereB
j is diagonal in the free-particle states) in the thermodynamic limit. Thereby we apply and extend a superoperator formalism, recently developed for the derivation of long-time tails in semiclassical systems. As an illustrative application, the Boltzmann equation value of the time-integrated correlation functionC(t) is derived in a straightforward manner. Due to exchange effects, the obtained t-matrix and the resulting scattering cross section, which occurs in the Boltzmann collision operator, are now functionals of the Fermi-Dirac or Bose-Einstein distribution. 相似文献
62.
Summary We deal with two diffusion problems: Space-integrated conserved entities characterizing very fast - diffusion - controlled reactions, such as time lags, etc. are universal. They are given by relationships which do not reflect the failure of the mean field hydrodynamic equations. We present another application which does not reflect this failure, for determining the surface flux via a diffusion controlled reaction producing a colored product. Another anomalous diffusion process we considered is transport through cellular materials whose cell sizes are highly nonuniform. We have analyzed the effects of extreme nonuniformity by considering fractal-like models of cellular solids. The diffusion current through these models can exhibit anomalous time-dependencies which are not predicted by the diffusion equation. In particular, it is shown that the initial diffusion current can be characterized by a power-law dependence on the time. Furthermore, the exponent of the power law is given in terms of the distribution of cell sizes in the fractal-like cellular solid. 相似文献
63.
The service life of ABS polymer, stabilized by 2-(3,5-di-tert-butyl-4-hydroxyanilino)-4,6-bis(octylthio)-1,3,5-triazine and containing 50% of a modifying rubber component, was estimated from oxidative induction times measured by DSC in isothermal mode in the temperature interval 140–170°C. The lifetime of ABS powder at the actual temperature of drying was predicted by linear extrapolation according to Arrhenius. However, the extrapolated value was much longer than the real lifetime determined from the long-term oven aging tests at 70 and 90°C, simulating the industrial drying process. The effect of changes in the apparent activation energy of oxidation due to antioxidant consumption during polymer aging is discussed. 相似文献
64.
Min-Hsien Liu Cheng Chen Yaw-Shun Hong Chuan-Wen Liu 《Theoretical chemistry accounts》2005,113(1):35-41
Calculation methods, based on hybrid density-functional theory with the basis sets of B3LYP/ 6-311+G (2d, p)//B3LYP/6-31G(d, p)and B3LYP/6-31+G(d)//B3LYP/6-31G(d, p), were applied to determine the thermodynamic characteristics of various energetic nitro compounds. A parametric modification equation and the least-squares approach were used to identify 21 of the energetic research compounds. The atomization energies of these 21 compounds have an average relative error of 0.21–0.25% of the experimental values. The enthalpy (H f) and the Gibbs energy (G f) of formation have mean absolute errors of 10.8–11.4 kJ/ mol (2.6–2.7 kcal/mol) and 10.0–10.3 kJ/mol (2.4 kcal/ mol), respectively. The enthalpy and the Gibbs energy of formation obtained exceed those in the literature obtained by semiempirical calculations. The calibrated least-squares parameters and parametric equations were used to predict H f and G f for the five newly developed energetic nitro compounds for further applications.Acknowledgements. The authors would like to thank the National Science Council of the Republic of China for financial support of this work under grant no. NSC-91-2113-M-014-003. The National Center for High-Performance Computing providing the computation facility is also acknowledged. 相似文献
65.
病态分析体系有偏估计的研究 总被引:3,自引:0,他引:3
运用广义岭估计和Liukejian提出的有偏估计,对病态分析体系进行了数值模拟和实际光度测定,结果表明,广义岭估计显优于最小二乘估计,Liukejian法有功效,可和为解析病态分析体系的化学计量学方法。 相似文献
66.
The considered mathematical model of the decomposition of valerate presents three unknown kinetic parameters, two unknown
stoichiometric coefficients, and three unknown initial concentrations for biomass. Applying a structural identifiability study,
we concluded that it is necessary to perform simultaneous batch experiments with differenitial conditions for estimating these
parameters. Four simultaneous batch experiments were conducted at 55°C, characterized by four different initial acetate concentrations.
Product inhibition of valerate degradation by acetate was considered. Practical identification was done optimizing the sum
of the multiple determination coefficients for all measured state viariables and for all experiments simultaneously. The estimated
values of kinetic parameters and stoichiometric coefficients were characterized by the parameter correlation matrix, the confidence
interval, and the student's t-test at 9% significance level with positive results except for the saturation constant, for which more eperiments for improving
its identifiability should be conducted. In this article, we discussekinetic parameter estimation methods. 相似文献
67.
In this paper, a tumor immune model with time delay is studied. First, the stability of nonnegative equilibria is analyzed. Then the time delay τ is selected as a bifurcation parameter and the existence of Hopf bifurcation is proved. Finally, by using the canonical method and the central manifold theory, the criteria for judging the direction and stability of Hopf bifurcation are given. 相似文献
68.
In this article, a novel method is proposed for investigating the set controllability of Markov jump switching Boolean control networks (MJSBCNs). Specifically, the switching signal is described as a discrete-time homogeneous Markov chain. By resorting to the expectation and switching indicator function, an expectation system is constructed. Based on the expectation system, a novel verifiable condition is established for solving the set reachability of MJSBCNs. With the newly obtained results on set reachability, a necessary and sufficient condition is further derived for the set controllability of MJSBCNs. The obtained results are applied to Boolean control networks with Markov jump time delays. Examples are demonstrated to justify the theoretical results. 相似文献
69.
In this paper estimation of the probabilities of a multinomial distribution has been studied. The five estimators considered are: unrestricted estimator (UE), restricted estimator (RE) (under model ), preliminary test estimator (PTE) based on a test of the model , shrinkage estimator (SE) and the positive-rule shrinkage estimator (PRSE). Asymptotic distributions of these estimators are given under Pitman alternatives and the asymptotic risk under a quadratic loss has been evaluated. The relative performance of the five estimators is then studied with respect to their asymptotic distributional risks (ADR). It is seen that neither of the preliminary test and shrinkage estimators dominates the other, though each fares well relative to the other estimators. However, the positive rule estimator is recommended for use for dimension 3 or more while the PTE is recommended for dimension less than 3. 相似文献
70.
We consider a decentralized LQG measurement scheduling problem in which every measurement is costly, no communication between observers is permitted, and the observers' estimation errors are coupled quadratically. This setup, motivated by considerations from organization theory, models measurement scheduling problems in which cost, bandwidth, or security constraints necessitate that estimates be decentralized, although their errors are coupled. We show that, unlike the centralized case, in the decentralized case the problem of optimizing the time integral of the measurement cost and the quadratic estimation error is fundamentally stochastic, and we characterize the -optimal open-loop schedules as chattering solutions of a deterministic Lagrange optimal control problem. Using a numerical example, we describe also how this deterministic optimal control problem can be solved by nonlinear programming.This research was supported in part by ARPA Grant N00174-91-C-0116 and NSF Grant NCR-92-04419. 相似文献