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11.
Jin Hu Gang Liu Jixiu Zhang Lingchao Kong Weidong Fei 《Applied Surface Science》2006,253(5):2792-2795
The microstructure of a laser treated Al18B4O33w/2024Al composite has been investigated using transmission electron microscope (TEM), low-angle (glancing angle) X-ray diffraction (XRD) techniques. Various surface microstructures were observed in the laser treated composite. The Al18B4O33 whisker on the surface of the composite was decomposed during laser surface melting, various decomposition products were studied in the laser treated composite. Eutectic phases and the precipitation in the matrix of the composite with laser-treated were observed. The main phases detected in the molten zone were aluminum and decomposition products Al2O3. The effect of laser treatment on the hardness of the composite was also examined. A surface hardness of 400 Hv was noted. 相似文献
12.
The effect of the cation concentration, hydrolysis temperature, and composition in the CeO2–ZrO2 system on the direct precipitation of ceria–zirconia solid solutions and the structure of the precipitates from acidic aqueous solutions of (NH4)2Ce(NO3)6 and ZrOCl2 by hydrolysis under hydrothermal conditions were investigated. Nanometer-sized (8–10 nm) ceria–zirconia solid solution particles in a composition range of 0 to 60 mol% ZrO2 were directly precipitated from the solutions with total metal cation concentration less than 0.2 mol/dm3 by simultaneous thermal hydrolysis at 150–240°C. The crystalline phase of the precipitates gradually changed from cubic and/or tetragonal to monoclinic with increasing the cation concentration of the solution from 0.2 to 0.8 mol/dm3 at the starting composition of 50 mol% ZrO2 under hydrolysis condition of 150°C for 48 h, which was attributed to decrease in the supply of hydrolyzed Ce component caused by decrease in the hydrolysis ratio of (NH4)2Ce(NO3)6. Ceria–zirconia solid solutions containing large amount of ZrO2 maintained high specific surface area and small-sized crystallite after heat-treatment at 900–1000°C for 1 h. 相似文献
13.
14.
Transport of surface-modified iron nanoparticle in porous media and application to arsenic(III) remediation 总被引:1,自引:0,他引:1
Sushil Raj Kanel Dhriti Nepal Bruce Manning Heechul Choi 《Journal of nanoparticle research》2007,9(5):725-735
The surface-modified iron nanoparticles (S-INP) were synthesized, characterized and tested for the remediation of arsenite
(As(III)), a well known toxic groundwater contaminant of concern. The S-INP material was fully dispersed in the aqueous phase
with a particle size distribution of 2–10 nm estimated from high-resolution transmission electron microscopy (HR-TEM). X-ray
photoelectron spectroscopy (XPS) revealed that an Fe(III) oxide surface film was present on S-INP in addition to the bulk
zero-valent Fe0 oxidation state. Transport of S-INP through porous media packed in 10 cm length column showed particle breakthroughs of 22.1,
47.4 and 60 pore volumes in glass beads, unbaked sand, and baked sand, respectively. Un-modified INP was immobile and aggregated
on porous media surfaces in the column inlet area. Results using S-INP pretreated 10 cm sand-packed columns containing ∼2 g
of S-INP showed that 100 % of As(III) was removed from influent solutions (flow rate 1.8 mL min−1) containing 0.2, 0.5 and 1.0 mg L−1 As(III) for 9, 7 and 4 days providing 23.3, 20.7 and 10.4 L of arsenic free water, respectively. In addition, it was found
that 100% of As(III) in 0.5 mg/L solution (flow rate 1.8 mL min−1) was removed by S-INP pretreated 50 cm sand packed column containing 12 g of S-INP for more than 2.5 months providing 194.4
L of arsenic free water. Field emission scanning electron microscopy (FE-SEM) showed S-INP had transformed to elongated, rod-like
shaped corrosion product particles after reaction with As(III) in the presence of sand. These results suggest that S-INP has
great potential to be used as a mobile, injectable reactive material for in-situ sandy groundwater aquifer treatment of As(III). 相似文献
15.
本文论述应用光学薄膜技术对汽车窗口玻璃和塑料的若干性能进行改进的技术发展水平,这些性能包括塑料表面的硬化,红外区的反射,紫外区的吸收,偏振化作用,双折射,憎水性以及光学角度选择性等,评论等离子体处理和物理蒸汽淀积薄膜工艺近来应用的一些例子。对于物理蒸汽淀积薄膜所提供的异常功能连同实际使用中它们的耐久性作了特殊的强调。 相似文献
16.
N. S. Oliveira J. Dorgan J. A. P. Coutinho A. Ferreira J. L. Daridon I. M. Marrucho 《Journal of Polymer Science.Polymer Physics》2007,45(5):616-625
The sorption of carbon dioxide in glassy Poly(lactic acid) (PLA) films was studied by quartz crystal microbalance (QCM) at high pressures. Two thermal treatments, melted and quenched, were performed in PLA with two different L:D contents, 80:20 and 98:2, films and compared with a third thermal protocol, annealed, and used in a previous work. The results obtained show that for pressures higher than 2 MPa, the carbon dioxide solubility is larger in PLA 80:20 than in PLA 98:2, indicating that the L:D plays a dominant role on this property. The thermal treatments only affect the gas solubility in PLA 98:2. Sorption isotherms at temperatures 303, 313, and 323 K, below the glass transition temperature of the polymer, and pressures up to 5 MPa were measured and analyzed with three different models, the dual‐mode sorption model, the Flory–Huggins equation, and a modified dual‐mode sorption model where the Henry's law term was substituted by the Flory–Huggins equation. This last model performs especially well for CO2 in PLA 80:20, due to the convex upward curvature of the solubility isotherms for that system. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 616–625, 2007 相似文献
17.
重离子治疗计划系统的构想 总被引:2,自引:1,他引:1
对重离子柬治癌的优势进行简要的回顾,并着重介绍了用于重离子放射治疗的治疗计划系统。治疗计划系统是一套软件系统,不同的硬件设施应有与其相匹配的软件系统,即治疗计划系统。在此基础上,针对兰州重离子加速器的特点提出一些关于治疗计划系统方面的构想。After a brief review concerning the advantages of heavy ions in radiotherapy, more interests are concentrated on treatment planning system (TPS) for heavy ion radiotherapy. Compared to the hardware devices such as accelerator and beam delivery system, the TPS is a set of software system, and different therapy facilities require their corresponding TPSs. Based on the specialities of the Heavy Ion Research Facility in Lanzhou (HIIRFL), some suggestions on the TPS for tumor therapy at HIRFL finally are given. 相似文献
18.
Sonya V. Roberson Albert J. Fahey Amit Sehgal Alamgir Karim 《Applied Surface Science》2002,200(1-4):150-164
We present a simple method for chemical modification of chlorosilane self-assembled monolayers (SAMs) on Si surfaces by exposure to a gradient of UV-ozone radiation to create stable substrates with a range of contact angles (θH2O≈5–95°) and surface energies on a single substrate. These gradient energy substrates are developed to potentially generate libraries for combinatorial studies of thin film phenomenology, where a systematic variation of interfacial surface energy represents one of the significant parameters along one axis. The graded oxidation process presents a systematic variation of surface chemical composition. We have utilized contact angle measurements and time-of-flight secondary ion mass spectrometry (ToF-SIMS) to investigate this variation for a series of ions, among which are SiCH3+, SiOH+ and COOH−. We show that the macroscopic measurements of surface free energy/contact angle correlate with the detailed analysis of surface chemistry (as assessed by ToF-SIMS) on these test substrates. 相似文献
19.
Wieczorek-Ciurowa K. Gamrat K. Paryło M. Shirokov Ju. G. 《Journal of Thermal Analysis and Calorimetry》2002,70(1):165-172
The physical mixtures of hydroxocarbonates of Cu and Ni with aluminium were activated using a laboratory planetary mill. The
chemical reactions and alloy formations as the effects of grinding were followed by the phase analysis of solid products based
on the thermogravimetry and X-ray diffractometry. Experimental evidence indicates that the nature of reactions and products
of mechanical activation was dependent on the amount of aluminium and time of grinding.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
20.
Reduced charge montmorillonites (RCM) were prepared by the thermal treatment of lithiumsaturated montmorillonite. Samples prepared by mild thermal treatment with lithium contained more water sorbed than the original montmorrilonite. When RCMs were prepared, part of the lithium cations reacted with hydroxyl groups in the octahedral sheet and released protons, which reacted with the structure. Acid treatment probably enhanced the surface area. which was reflected in the amount of water sorbed. Deprotonation of hydroxyl groups was proved by the measurements of the ignition loss. The heating of lithium saturated montmorillonite at higher temperatures brough about the collapse of the interlayers and a decrease in the amount of water sorbed. 相似文献