ChemInform Abstract: Trends in Gas-Phase Fluoride Ion Affinities of Main-Group Oxyfluorides and Fluoride Sulfides. Generation and Characterization of the Fluoride Adducts of FAsO,FPO, FPO2, F2SiO,F4SO,FBO, F2SiS,FPS, FAsS,F2S2, and S2O by Ion Cyclotron Resonance Addition-Elimination Reactions.

Novel oxyfluoride and fluoride sulfide anions are generated by the isoelectronic replacement of F in a main-group polyfluoride by O- or S- via the reaction of either tBuO- or RS- (R: H, Me) with the polyfluorides.     

ChemInform Abstract: Molecular Structure of Chromium Tetrafluoride in the Gas Phase

is determined by electron diffraction at 195-220 °C. The diffraction patterns are completely consistent with a molecule of tetrahedral (Td) symmetry.     

F-P滤波器对啁啾光脉冲脉宽的扩展和压缩

导出了啁啾光脉冲通过F P滤波器后输出脉冲光强的解析表达式。在此基础上 ,对啁啾光脉冲通过F P滤波器后其脉冲宽度的变化进行了研究。结果表明 ,对于一确定的滤波器 ,其对输入脉冲脉宽的影响与输出脉冲的宽度及啁啾因子的大小有关     

On Shellsort and the frobenius problem

A boundO(N ^1+1/k ) for the running time of Shellsort, withO(logN) passes, is proved very simply by application of a Frobenius basis withk elements.     

X-ray coherence and ultra small angle resolution at grazing incidence and exit angles

We measure the nonspecular x-ray scattering at grazing incidence and exit angles from a GaAs surface, modulated by an one-dimensional lateral grating of effectively variable periodicity 1 md60 m. Due to the projection onto the sample surface, the lateral coherence length is enlarged by a factor of more than 100. The line broadening of the diffraction maxima is used to deduce the number of periods that add up coherently for a given periodd and given angle of incidence. We demonstrate that the scattering geometry used allows for large coherently illuminated lengths on the sample and ultra small angle resolution of one- or two-dimensional objects. Thus structures of m size and larger will be accessible by coherent x-ray scattering.     

Dynamic spin-orbit interaction of heavy ions in semiclassical calculations of elastic scattering

Experimental results of the 1st rank analyzing power for elastic scattering of⁶Li and⁷Li could be only understood when including coupling to inelastic channels in the calculations. This finding — established for some time — yet presents some open questions regarding the energy dependence of the spin and polarization effects. Semiclassical calculations presented here might clarify the relevant physical background of the earlier quantummechanically exact results.     

The structure of Valdivia compact lines

We study linearly ordered spaces which are Valdivia compact in their order topology. We find an internal characterization of these spaces and we present a counter-example disproving a conjecture posed earlier by the first author. The conjecture asserted that a compact line is Valdivia compact if its weight does not exceed ℵ₁, every point of uncountable character is isolated from one side and every closed first countable subspace is metrizable. It turns out that the last condition is not sufficient. On the other hand, we show that the conjecture is valid if the closure of the set of points of uncountable character is scattered. This improves an earlier result of the first author.     

Periodic points of solvable group actions on 1-arcwise connected continua

It is shown that every continuous action of a solvable group on a 1-arcwise connected continuum must have a fixed point or have a 2-periodic point.     

On the Gerber-Shiu function and change of measure

We consider several models for the surplus of an insurance company mainly under some light-tail assumptions. We are interested in the expected discounted penalty at ruin. By a change of measure we remove the discounting, which simplifies the expression. This leads to (defective) renewal equations as they had been found by different methods in the literature. If we use the change of measure such that ruin becomes certain, the renewal equations simplify to ordinary renewal equations. This helps to discuss the asymptotics as the initial capital goes to infinity. For phase-type claim sizes, explicit formulae can be derived.