Luminescence of dense, octahedral structured crystalline silicon dioxide (stishovite)

It is obtained that, as grown, non-irradiated stishovite single crystals possess a luminescence center. Three excimer pulsed lasers (KrF, 248 nm; ArF, 193 nm; F₂, 157 nm) were used for photoluminescence (PL) excitation. Two PL bands were observed. One, in UV range with the maximum at 4.7±0.1 eV with FWHM equal to 0.95±0.1 eV, mainly is seen under ArF laser. Another, in blue range with the maximum at 3±0.2 eV with FWHM equal to 0.8±0.2 eV, is seen under all three lasers. The UV band main fast component of decay is with time constant τ=1.2±0.1 ns for the range of temperatures 16-150 K. The blue band decay possesses fast and slow components. The fast component of the blue band decay is about 1.2 ns. The slow component of the blue band well corresponds to exponent with time constant equal to 17±1 μs within the temperature range 16-200 K. deviations from exponential decay were observed as well and explained by influence of nearest interstitial OH groups on the luminescence center. The UV band was not detected for F₂ laser excitation. For the case of KrF laser only a structure less tail up to 4.6 eV was detected. Both the UV and the blue bands were also found in recombination process with two components having characteristic time about 1 and 60 μs. For blue band recombination luminescence decay is lasting to ms range of time with power law decay ∼t⁻¹.For the case of X-ray excitation the luminescence intensity exhibits strong drop down above 100 K. such an effect does not take place in the case of photoexcitation with lasers. The activation energies for both cases are different as well. Average value of that is 0.03±0.01 eV for the case of X-ray luminescence and it is 0.15±0.05 eV for the case of PL. So, the processes of thermal quenching are different for these kinds of excitation and, probably, are related to interaction of the luminescence center with OH groups.Stishovite crystal irradiated with pulses of electron beam (270 kV, 200 A, 10 ns) demonstrates a decrease of luminescence intensity excited with X-ray. So, irradiation with electron beam shows on destruction of luminescent defects.The nature of luminescence excited in the transparency range of stishovite is ascribed to a defect existing in the crystal after growth. Similarity of the stishovite luminescence with that of oxygen deficient silica glass and induced by radiation luminescence of α-quartz crystal presumes similar nature of centers in those materials.     

Optical spectroscopy, 1.5 μm emission and up-conversion properties of Er-doped Li3Ba2Gd3(MoO4)8 crystal

Er³⁺:Li₃Ba₂Gd₃(MoO₄)₈ crystal has been grown from a melt of Li₂MoO₄ by the top seeded solution growth method (TSSG). The polarized spectral properties of Er³⁺:Li₃Ba₂Gd₃(MoO₄)₈ crystal were investigated and the spectroscopic parameters were calculated and analyzed based on the Judd-Ofelt (J-O) theory. The emission cross-sections were calculated by the Fuchtbauer-Ladenburg (F-L) equation and the peak values of the emission band at 1535 nm were 9.7×10⁻²¹, 7.9×10⁻²¹ and 8.4×10⁻²¹ cm² for E∥b, E∥D1 and E∥D2, respectively. Under 977 nm excitation five up-conversion fluorescence bands around 490, 530, 550, 660 and 800 nm were observed, and the possible up-conversion mechanisms were proposed.     

Infrared photoluminescence of erbium-tris(8-hydroxyquinoline) in a distributed feedback cavity

A distributed feedback (DFB) waveguide cavity with erbium-tris(8-hydroxyquinoline) has been fabricated by X-ray interference lithography in a laboratory-scale apparatus. The DFB cavity consists of a large area () one-dimensional grating of polymethylmethacrylate on Si (1 0 0). Structural, morphological and optical properties of the device have been studied. On-grating narrowing of the photoluminescence emission has been observed for the 492 nm grating period in correspondence to the 4f-4f Er band peak (at 1530 nm), indicating the possibility of optical gain for applications in the telecommunications.     

High-resolution spectroscopy of the ν8 band of methylene bromide using a quantum cascade laser

A continuous wave cavity ringdown spectrometer with a Fabry-Perot quantum cascade laser has been used to collect a rotationally-resolved infrared spectrum of the ν₈ vibrational band of methylene bromide in a slit nozzle expansion. In our laboratory, previous observations of the vibrational band were limited by spectral coverage to only the P and Q-branches and by the 24 MHz step-size of the laser [1]. The issue of limited spectral coverage has been resolved using a Fresnel rhomb and a wire grid polarizer to protect the laser from the destabilizing effects of back-reflection from the ringdown cavity. The frequency step-size of the spectrometer has been reduced from 24 MHz to 2 MHz. With both of these instrument enhancements, we have been able to record the R-branch of the vibrational band, and can resolve many lines that were previously blended in spectra acquired using a pinhole expansion nozzle. Significant hyperfine splitting was observed for the low-J transitions in the P and R-branches. It was possible to neglect the effects of hyperfine splitting for transitions involving J″ > 2 in the spectral assignment, and simulations using the constants obtained by fitting to Watson’s S-reduced Hamiltonian for CH₂⁷⁹Br⁸¹Br, and the A-reduced form for CH₂⁷⁹Br₂ and CH₂⁸¹Br₂, provide a good match to experimental spectra. A total of 297 transitions have been assigned for all three isotopologues, with a standard deviation of 0.00024 cm⁻¹(∼7 MHz).     

Tunable microwave generation based on a Brillouin fiber ring laser and reflected pump

A simple approach for photonic generation of a tunable microwave signal is proposed and successfully demonstrated. By mixing the output from a single-longitudinal-mode Brillouin fiber ring laser with the reflected laser pump at photodetector, a microwave signal at the Brillouin shift can be obtained. Since the Brillouin shift can be changed by tuning the pump wavelength, tunable microwave can be generated. As a result a microwave signal tunable from 10.39 to 10.67 GHz has been achieved, with linewidth less than 600 KHz.     

Thermal effects in high-power Nd:YAG disk-type solid state laser

An investigation of thermal effects in a high-power Nd:YAG disk-type solid state laser pumped with different pump beam transverse profiles is carried out by numerical simulation based on the finite element method (FEM). Impact of the heat sink on the thermal effects is included in the simulation. The distribution of first principle stress, thermally induced birefringence, including the distribution and variation of the birefringence loss, are studied. The characteristics of the phase variation are analyzed with consideration of the temperature gradient, deformation, strain and thermal stress. Thermal lensing is explored as a function of pump power and of the radius pumped with different pump beam transverse profiles. The non-parabolic part of optical phase distortion is simulated. Furthermore, the characteristics of the bi-focus of the disk laser are also studied. Experiments on the maximum tensile stress distribution and depolarization loss are carried out. The presented calculations are in qualitative agreement with the experimental observations.     

Propagation characteristics of annular laser beams passing through the reflection Bragg grating with deformation

When high-power annular laser beams produced by the unstable resonator pass through the volume Bragg grating (VBG), absorption of light in the VBG will induce a temperature increment, resulting in changes in surface distortion. Considering that the surface distortion of the grating induces index and period differences, the scalar wave equations for the annular laser beams propagating in the VBG have been solved numerically and iteratively using finite-difference and sparse matrix methods. The variation in intensity distributions, the total power reflection coefficient, and the power in the bucket (PIB) for the annular laser beams passing through the reflection VBG with deformation have been analyzed quantitatively. It can be shown that the surface distortion of the VBG and the beam orders of the annular beams affect evidently the intensity distributions, the power reflection coefficient, and the PIB of the output beam. The peak intensity decreases as the deformation of the VBG increases. The total power reflection efficiency decreases significantly with the increase in deformations of the VBG. The PIB of the output beam decreases as the obscuration ratio β and the deformation of the VBG increase. For the given obscuration ratio β, the influence of deformation of reflection VBG on the PIB of the annular beams is more sensitive with increase in distortion of the VBG and decrease in beam order.     

Emission properties of femtosecond (fs) laser fabricated microstructures in Polystyrene (PS)

We fabricated microstructures and micro craters in thin films and bulk of PS. To the best of our knowledge, this is the first report of the emission from fs laser modified regions of PS when excited at 337, 400, 458, 488 and 514 nm wavelengths with different emission peaks. We systematically studied the emission in context of formation of optical centers and analyzed the spectra of irradiated PS. Change in the excitation wavelength leads to a shift in the emission peak, whereby, we infer that the emission should be due to a myriad of optical centers. Interestingly these optical centers have a similar excitation spectrum. Diphenylbutadiene (DPBD) is probably the main optical center among other optical centers thus formed in the process of fs laser irradiation of PS.     

Full L-band coverage of multiwavelength erbium-doped fiber laser

We propose and experimentally demonstrate a dual-pass unbalanced in-line Sagnac interferometer as a novel comb filter for implements in erbium-doped fiber lasers to obtain wide wavebands of multiwavelength radiations with enhancements of signal-to-noise ratios (SNRs). The hybrid combinations of the comb filter with the two schemes of nonlinear polarization rotation and intensity dependent loss have successfully not only enlarged the lasing bandwidth up to 47 nm but also enhanced the SNR up to 40 dB. The simultaneous lasing-wavelengths of 117 channels are also obtained. The multiwavelength lasing spectra with free spectral range of 0.4 nm covering the full L-band are useful for the applications of DWDM and WDM-PON systems.     

Effects of angle of probe laser and pinhole diameter on the time-resolved optical inspection system

A real-time in-situ time-resolved optical inspection system comprising two He-Ne probe lasers, a digital oscilloscope, and three fast photodetectors is developed. The effects of angle of probe laser and pinhole diameter on the time-resolved optical inspection system are investigated during excimer laser crystallization. The longest melt duration and ablation excimer laser fluence are independent of pinhole size. The pinhole with a diameter of 0.3 mm is recommended to use in the time-resolved optical inspection system. Determination of melt duration and observation of explosive crystallization oscillation are independent of angle of probe laser, but four criteria for the relationship between probe lasers and photodetectors should be followed.