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本文应用醋酸铬(Ⅱ)在吡啶溶液中置换[Fe~2MO(CH~3CO~2)~6(H~2O)~3]·nH~2O(M=Mn,Co,Ni)中三价铁离子的反应,制备了三个标题化合物.从测定的晶胞参数可以确定它们为异质同晶,进而测定其中[FeCrCoO(CH~3CO~2)~6Py~3]·Py三核物的晶体结构.晶体属三方晶系,a=1.7516,c=1.1027nm,V=2.9297nm^3,Z=3,空间群R32.同时还研究了三个标题化合物吡啶溶液的民电子光谱,应用配位场理论对有关金属离子的d-d跃迁谱带进行归属和配位场参数的计算. 相似文献
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We consider the dynamical stability of a class of static, spherically symmetric solutions of the nonsymmetric gravitational theory. We numerically reproduce the Wyman solution and generate new solutions for the case where the theory has a nontrivial fundamental length scale -1. By considering spherically symmetric perturbations of these solutions we show that the Wyman solutions are generically unstable. 相似文献
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A Brief Guide to Variations in Teleparallel Gauge Theories of Gravity and the Kaniel-Itin Model 总被引:1,自引:0,他引:1
Recently Kaniel and Itin proposed a gravitational model with the wave type equation
as vacuum field equation, where
denotes the coframe of spacetime. They found that the viable Yilmaz-Rosen metric is an exact solution of the tracefree part of their field equation. This model belongs to the teleparallelism class of gravitational gauge theories. Of decisive importance for the evaluation of the Kaniel-Itin model is the question whether the variation of the coframe commutes with the Hodge star. We find a master formula for this commutator and rectify some corresponding mistakes in the literature. Then we turn to a detailed discussion of the Kaniel-Itin model. 相似文献
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采用DFT(B3LYP)方法,分别在6-311g(d,p),6-311++g(d,p)和自洽相关基组cc-pVIZ水平上优化了基态硝基甲烷和自由基H,OH,CH3,CH2[^3B1]以及O[^3P]等发生吸氢反应时的过渡态结构,并计算了反应的位垒。研究表明,对同一反应,不同基组下优化得到的过渡态几何结构基本一致;反应位垒数值的大小也基本接近,经校正,硝基甲烷同自由基反应位垒的理论计算值同实验结果基本吻合。 相似文献
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