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71.
Langli Luo Yao Nian Shuangbao Wang Zejian Dong Yang He You Han Chongmin Wang 《Angewandte Chemie (International ed. in English)》2020,59(6):2505-2509
By using in situ aberration‐corrected environmental transmission electron microscopy, for the first time at atomic level, the dynamic evolution of the Cu surface is captured during CO oxidation. Under reaction conditions, the Cu surface is activated, typically involving 2–3 atomic layers with the formation of a reversible metastable phase that only exists during catalytic reactions. The distinctive role of CO and O2 in the surface activation is revealed, which features CO exposure to lead to surface roughening and consequently formation of low‐coordinated Cu atoms, while O2 exposure induces a quasi‐crystalline CuOx phase. Supported by DFT calculations, it is shown that crystalline CuOx reversibly transforms into the amorphous phase, acting as an active species to facilitate the interaction of gas reactants and catalyzing CO oxidation. 相似文献
72.
Biwei Xiao Hanshuo Liu Ning Chen Mohammad Norouzi Banis Haijun Yu Jianwen Liang Qian Sun Tsun‐Kong Sham Ruying Li Mei Cai Gianluigi A. Botton Xueliang Sun 《Angewandte Chemie (International ed. in English)》2020,59(34):14313-14320
Li‐ and Mn‐rich layered oxides are among the most promising cathode materials for Li‐ion batteries with high theoretical energy density. Its practical application is, however, hampered by the capacity and voltage fade after long cycling. Herein, a finite difference method for near‐edge structure (FDMNES) code was combined with in situ X‐ray absorption spectroscopy (XAS) and transmission electron microscopy/electron energy loss spectroscopy (TEM/EELS) to investigate the evolution of transition metals (TMs) in fresh and heavily cycled electrodes. Theoretical modeling reveals a recurring partially reversible LiMn2O4‐like sub‐nanodomain formation/dissolution process during each charge/discharge, which accumulates gradually and accounts for the Mn phase transition. From the modeling of spectra and maps of the valence state over large regions of the cathodes, it was found that the phase change is size‐dependent. After prolonged cycling, the TMs displayed different levels of inactivity. 相似文献
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75.
提出了一款具有高隔离度的双陷波超宽带多入多出(UWB MIMO)天线。该天线由两个相同的半切超宽带天线单元倒置构成。通过在天线底板刻蚀栅栏型缺陷地解耦结构,使该MIMO天线的隔离度提高至25 dB。此外,在天线半圆形辐射贴片上刻蚀两个方向相反的"L"型缝隙,实现了双陷波的功能,分别抑制了802.16无线城域网WiMAX(3.2~3.7 GHz)和WLAN(5.15~5.85 GHz)信号对天线系统的干扰。实验结果表明,该天线在3~11 GHz工作带宽内的隔离度大于25 dB,包络相关系数(ECC)小于0.004;第一个陷波频段为3.0~3.7 GHz,第二个陷波频段为5.1~5.85 GHz,有效抑制了WiMAX和WLAN的信号干扰。 相似文献
76.
Delignification of sawdust was studied using ultrasound assisted alkali peroxide approach using longitudinal horn for the first time and the efficacy compared with more commonly used configurations of ultrasonic reactors. Comparison with the conventional approach based on stirring has also been presented to establish the process intensification benefits. Effect of different operating parameters such as sodium carbonate concentration (0.1, 0.15, 0.2, 0.25 M), hydrogen peroxide concentration (0.2, 0.4, 0.6, 0.8, 1 M) and biomass loading (2, 4, 6, 8, 10 wt%), on the efficacy of lignin extraction has been investigated for different ultrasonic reactors. The optimum conditions for probe type ultrasonic horn were established as 150 W, 50% duty cycle and 80% amplitude with optimum process conditions as Na2CO3 concentration as 0.2 M, H2O2 concentration as 1 M, biomass loading of 10 wt% and operating time of 70 min. Longitudinal horn resulted in best efficacy (both in terms of yield and energy requirements) followed by ultrasonic horn and ultrasonic bath whereas the conventional approach was least effective. The obtained lignin was also analyzed using different characterization techniques. The presence of peaks at wavelength range of 875–817, 1123–1110, and at 1599 cm−1 for the extracted sample confirmed the presence of lignin. Increase in the crystallinity index of the processed sample (maximum for longitudinal horn) also confirmed the lignin removal as lignin is amorphous in nature. Overall it has been concluded that ultrasound can be effectively used for delignification with longitudinal horn as best configuration. 相似文献
77.
A technique for production of nanocrystalline cellulose with a narrow size distribution 总被引:3,自引:0,他引:3
Nanocrystalline cellulose (NCC) was prepared by sulfuric acid hydrolysis of microcrystalline cellulose. A differential centrifugation
technique was studied to obtain NCC whiskers with a narrow size distribution. It was shown that the volume of NCC in different
fractions had an inverse relationship with relative centrifugal force (RCF). The length of NCC whiskers was also fractionized
by differential RCF. The aspect ratio of NCC in different fractions had a relatively narrow range. This technique provides
an easy way of producing NCC whiskers with a narrow size distribution. 相似文献
78.
悬浮床加氢裂化水溶性催化剂的筛选与表征 总被引:14,自引:3,他引:14
催化加氢作用, 当金属组分A和组分B浓度分别为 15 μg/g ~ 25 μg/g 和 1100 μg/g~1300 μg/g时催化剂具有较好的催化加氢活性。两元水溶性催化剂硫化后的XPS、XRD和TEM分析结果表明:活性组分经硫化反应后生成了金属硫化物,但组分A硫化率不足50%;组分B易硫化结晶,其晶粒成为组分A的硫化物晶粒或颗粒分散的“载体”,使组分A的硫化物具有较高的分散度,提高了催化剂的加氢活性;A-B双金属水溶性催化剂经硫化反应后所形成的颗粒尺寸在100 nm左右,说明两元金属催化剂在硫化结晶过程中确实存在相互分散和抑制晶粒增长的作用。 相似文献
79.
Nanosized surface-enhanced Raman scattering (SERS) substrates fabricated by the controlled growth of metal nanostructures on water-dispersed two-dimensional nanomaterials can open a new avenue for SERS analysis of liquid samples in biological fields. In this work, regular and uniform Ag nanostructures were grown on the surface of graphene oxide (GO) through a microwave-assisted hydrothermal method. Polyamidoamine (PAMAM) dendrimers were assembled on the surface of GO to form GO/PAMAM templates for growing Ag nanostructures, which are primarily comprised of Ag dimers and trimers. The prepared Ag/GO nanocomposites are highly dispersed and stable in aqueous solution and may be used as substrates for enhanced Raman detection of rhodamine 6?G (R6G) in aqueous solution. This special substrate provides high-performance SERS and suppresses R6G fluorescence in aqueous solution and is promising as a nanosized material for the enhanced Raman detection of liquid samples in biological diagnostics. 相似文献
80.
Guoxin Chen Huanming Lu Junfeng Cui Haitao Yu Bo Wang Yan Liu He Li Nan Jiang 《中国化学快报》2019,30(7):1401-1404
The real time analysis structure evolution of BNNT with compression showed that the formation of V-shape in the post-buckling before BNNT fracture was reversible. 相似文献