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21.
§ 1 IntroductionA triple system of order v and indexλ,denoted by TS(v,λ) ,is a collection of3- ele-mentsubsets Aof a v- set X,so thatevery 2 - subsetof X appears in preciselyλ subsets of A.L etλ≥ 2 and (X,A) be a TS(v,λ) .If Acan be partitioned into t(≥ 2 ) parts A1,A2 ,...,Atsuch that each (X,Ai) is a TS(v,λi) for 1≤ i≤ t,then (X,A) is called de-composable.Otherwise it is indecomposable.If t=λ,λi=1for 1≤ i≤ t,the TS(v,λ) (X,A) is called completely decomposable.It … 相似文献
22.
Hui Zhang 《Journal of solid state chemistry》2004,177(3):772-780
A nano-scale magnetic solid base catalyst MgAl-OH-LDH/MgFe2O4 (where LDH denotes layered double hydroxide) composed of MgAl-OH-LDH Brønsted base catalytic layers coated on MgFe2O4 spinel cores has been prepared. A magnetic precursor MgAl-CO3-LDH/MgFe2O4 was prepared by a method involving separate nucleation and aging steps, and subsequently calcined to give a mixed metal oxide composite MgAl(O)/MgFe2O4 which was rehydrated to give MgAl-OH-LDH/MgFe2O4. The structure and magnetic properties of the nano-scale magnetic solid base MgAl-OH-LDH/MgFe2O4, together with those of the magnetic precursor MgAl-CO3-LDH/MgFe2O4 and MgFe2O4 were characterized by XRD, XPS, low temperature N2 adsorption and vibrating sample magnetometry (VSM). The MgAl-OH-LDH/MgFe2O4 composite possesses a mesoporous structure with pore size ranging from 2 to 20 nm with particle size mainly in the range 35-130 nm. The catalytic properties of MgAl-OH-LDH/MgFe2O4 were evaluated using the self-condensation of acetone at 273 K as a probe reaction. The results showed that the conversion of acetone to diacetone alcohol reached the thermodynamic equilibrium value of 23% at 273 K. The catalyst was easily recovered through application of an external magnetic field, and when the reclaimed catalyst was used in a second run for the same reaction, the reactivity remained unchanged. 相似文献
23.
Peter J. Cameron 《组合设计杂志》2005,13(6):466-470
It is shown that there is a function g on the natural numbers such that a partial Steiner triple system U on u points can be embedded in a Steiner triple system V on ν points, in such a way that all automorphisms of U can be extended to V, for every admissible ν satisfying ν > g(u). We find exponential upper and lower bounds for g. © 2005 Wiley Periodicals, Inc. J Combin Designs. 相似文献
24.
《Magnetic resonance in chemistry : MRC》2003,41(1):61-64
Palladium(II) dichloride reacts with 1,10‐bis(2‐pyrrolyl)‐2,5,9‐triaza‐1,9‐decadiene to give a [Pd(C15H20N5)]Cl complex in which the ligand is four‐coordinated, leaving one pyrrole group dangling. By using COSY, gHSQC, gHMBC connectivities and NOE experiments it has been concluded that one linkage isomer exists in DMSO solution, in spite of the fact that different sets of N atoms of potentially pentadentate ligand might be involved in coordination, and that the three chelate rings in the complex cation are arranged in a sequence: five‐membered, six‐membered, five‐membered which is different from that (5–5–6) found by x‐ray studies on the related [Ni(C15H20N5)]Cl compound. NMR studies allowed an unambiguous assignment of all 1H and 13C NMR resonances for the complex. Results of x‐ray structural analysis of [Pd(C15H20N5)](CH3COO)H2O supported the five‐membered, six‐membered, five‐membered ring sequence in the [Pd(C15H20N5)]+ complex cation and show an E (trans) orientation of the dangling pyrrole group with respect to the metal center. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
25.
A. Filarowski A. Koll A. Kochel J. Kalenik P. E. Hansen 《Journal of Molecular Structure》2004,700(1-3):67-72
The crystal structures of two ortho-hydroxy ketones (5-chloro-2-hydroxyacetophenone (I K) and 3,5-dichloro-2-hydroxyacetophenone (II K)) have been determined with X-ray diffraction at 100 K. A comparison of steric effects on properties of pseudoaromatic hydrogen bonds in ortho-hydroxy acetophenone and ortho-hydroxy ketimines have been carried out with the application of crystallographic data.
Nuclear quadrupole resonance (NQR) spectra have been measured and interpreted. 相似文献
26.
27.
The authors derive a formula for the volume of a compact domain in a symmetric space from normal sections through a special submanifold in the symmetric space.This formula generalizes the volume of classical domains as tubes or domains given as motions along the submanifold.Finally,some stereological considerations regarding this formula are provided. 相似文献
28.
Yuichiro Fujiwara 《组合设计杂志》2006,14(3):237-250
In this paper, we present three constructions for anti‐mitre Steiner triple systems and a construction for 5‐sparse ones. The first construction for anti‐mitre STSs settles two of the four unsettled admissible residue classes modulo 18 and the second construction covers such a class modulo 36. The third construction generates many infinite classes of anti‐mitre STSs in the remaining possible orders. As a consequence of these three constructions we can construct anti‐mitre systems for at least 13/14 of the admissible orders. For 5‐sparse STS(υ), we give a construction for υ ≡ 1, 19 (mod 54) and υ ≠ 109. © 2005 Wiley Periodicals, Inc. J Combin Designs 14: 237–250, 2006 相似文献
29.
In this paper we describe the general forms of all (nonlinear) continuous functionals on the sets of positive definite, positive semi-definite and Hermitian matrices which are multiplicative on the commuting elements. As a consequence, we obtain some new characterizations of the determinant on those classes of matrices.
30.
A simple and rapid method is developed to determine the high acidity and the basicity of solutions by chronopotentiometry with a platinum working electrode. The acidity range from 5.0 mol/l H+ to 1.0 mol/l OH− can be measured by the adjustment of deposition potential and time. The response mechanism to acidity and basicity has been explored. The transition potential plateau in chronopotentiograms is caused from the oxidation of hydrogen adsorbed on electrode surface. 相似文献