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961.
The formation process of Zn/Cu surface alloys is investigated using the Bozzolo-Ferrante-Smith (BFS) method for alloys. The effects of the crystallographic orientation on the deposition process, formation of surface alloys as a function of temperature and coverage, Zn surface migration, and interdiffusion in the Cu substrate, are modeled and discussed with atom-by-atom energy analyses and large scale simulations. 相似文献
962.
Mariano Venanzi Giuseppina Pace Lorenzo Stella Manuela Scarselli Fernando Formaggio Giovanni Marletta 《Surface science》2006,600(2):409-416
A novel hexapeptide was functionalized at the N-terminus by a lipoyl group for binding to gold substrates. Owing to the high content of α-aminoisobutyric acid residues, the peptide adopts a rigid helical conformation despite the shortness of its main chain. Binding of the peptide to gold was investigated by quartz crystal microbalance, cyclic voltammetry, X-ray photoelectron spectroscopy, and scanning tunneling microscopy under ultra-high vacuum conditions. Scanning tunneling microscopy experiments revealed that the peculiar self-assembly properties of this short helical peptide determine the complex morphology of the monolayer, showing ‘stripes’, i.e. peptide aggregates horizontally layered on the gold surface, and ‘holes’, i.e. Au vacancy islands coated by the peptide monolayer. 相似文献
963.
Here we report on high-resolution photoemission of iron layers grown on a W(1 1 0) substrate. The evolution of the substrate states upon sub-monolayer adsorption of Fe atoms leads to a shift in surface state binding energy. For thicker (1 1 0) films, sharp metallic surface states are obtained. Their dispersion displays the signature of quasiparticle renormalization due to dressing with excitations. The energy scale is characteristic for the spin wave spectrum in iron, thereby giving evidence of electron-magnon coupling. Furthermore, it is found that quantum well states occur as a function of layer thickness. These modify the spin density of states at the Fermi level in the ferromagnetic film. 相似文献
964.
We study the nucleation phase of molecular beam epitaxy of (hexagonal) MnAs on (cubic) GaAs (0 0 1) using reflection high-energy electron diffraction (RHEED) azimuthal scans. The nucleation proceeds from a non-reconstructed initial stage through randomly oriented small nuclei and two orientation stages to the final single-phase epitaxial orientation. The fascinatingly complex nucleation process contains elements of both Volmer-Weber and Stranski-Krastanov growth. The measurement demonstrates the potential of high-resolution RHEED techniques to assess details of the surface structure during epitaxy. 相似文献
965.
α-Actinin has been shown to be capable of interacting with some special membrane phospholipids directly, which is important for its function. In this study, hybrid bilayer membranes composed of negatively charged lipids are constructed on the surface plasmon resonance gold substrate and on the gold electrode, respectively, and the interaction between α-actinin and negatively charged lipids membrane is investigated by surface plasmon resonance, cyclic voltammetry and electrochemical impedance spectroscopy methods. α-Actinin is proved to be able to interact with the negatively charged lipids membrane directly. It can also insert at least partly into the membrane or lead to some defect or lesion in the membrane, which increase the permeability of the membrane. This study would bring some insight on the interaction between the α-actinin and the cell membranes in vivo. 相似文献
966.
P. Galinetto M. Marinone D. Grando G. Samoggia F. Caccavale A. Morbiato M. Musolino 《Optics and Lasers in Engineering》2007,45(3):380
In this work we report on micro-Raman analysis on lithium niobate (LN) substrates in order to study the compositional homogeneity of the crystals and to clear up the effects of etching and polishing processes on the surface of wafers and crystals.The fact that the linewidth of some Raman modes scale with the composition of LN crystals, together with the use of a confocal microscope, allowed a three-dimensional determination of the sample stoichiometry and of the crystalline quality. This local tool can supply additional information, which can be complementary to the electro-optic coefficients, carefully measured as well in order to check functional parameters.Raman spectra from buried regions were obtained on as-grown, etched and polished crystals and wafers. The depth profile of the peak energy and the linewidth of the Raman mode at 872 cm−1 indicate that mechanical processing of surfaces causes, in some cases, structural modifications till a depth of 15 μm. 相似文献
967.
Reorganization of Au + Pd submonolayers on a Rh(1 1 0) surface occurring during the water formation reaction has been observed and characterized by low energy electron microscopy (LEEM) and X-ray photoemission electron microscopy (XPEEM). The results demonstrate segregation of Au + Pd and oxygen into separate surface phases, the morphology and size of the O and Au + Pd patterns being governed by the reaction parameters and adsorbate coverage. At moderate Au + Pd coverages and temperatures in the range 760-860 K, lamellar periodic Au + Pd/O micro-structures are generated. The results are interpreted in terms of kinetic and thermodynamic considerations. 相似文献
968.
969.
Experimental studies employing surface science methods indicate that kinetic oscillations, chaos, and pattern formation in heterogeneous catalytic reactions often result from the interplay of rapid chemical reaction steps and relatively slow complementary processes such as oxide formation or adsorbate-induced surface restructuring. In general, the latter processes should be analysed in terms of theory of phase transitions. Therefore, the conventional mean-field reaction–diffusion equations widely used to describe oscillations in homogeneous reactions are strictly speaking not applicable. Under such circumstances, application of the Monte Carlo method becomes almost inevitable. In this review, we discuss the advantages and limitations of employing this technique and show what can be achieved in this way. Attention is focused on Monte Carlo simulations of CO oxidation on (1 0 0) and (1 1 0) single-crystal Pt and polycrystal Pt, Pd and Ir surfaces and of NO reduction by CO and H2 on Pt(1 0 0). CO oxidation on supported nanometre-sized catalyst particles and NO reduction on composite catalysts are also discussed. The results show that with current computer facilities the MC technique has become an effective tool for analysing temporal oscillations and pattern formation on the nanometre scale in catalytic reactions occurring on both single crystals and supported particles. 相似文献
970.