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991.
992.
In this article, multivariate density expansions for the sample correlation matrix R are derived. The density of R is expressed through multivariate normal and through Wishart distributions. Also, an asymptotic expansion of the characteristic function of R is derived and the main terms of the first three cumulants of R are obtained in matrix form. These results make it possible to obtain asymptotic density expansions of multivariate functions of R in a direct way. 相似文献
993.
应用钛宝石可调谐脉冲激光,在波长为691nm、脉冲宽度为10ns的条件下,研究了新型富勒烯叠氮乙酰氨衍生物(N-acetamide1,2-dihydro-1,2-azafulerene[60])的光限幅特性。 相似文献
994.
Qian Rong LI* Sha YANG Structure Research Laboratory University of Science Technology of China Hefei 《中国化学快报》2003,(11)
Functionalization by cycloaddition reactions1 represents a useful strategy to modify fullerenes1,2. Stable cycloadducts are interesting in regarding to the development of new materials with unique physical properties or biological activities3. One of the typical reactions is the cycloadditions of C60 with azide compounds. Wudl and Miyata et al. reported that C60 reacted with alkyl azides4 or benzyl azides5 to give the same kind of adduct azafulleroids with an opened 6,5-ring junction by th… 相似文献
995.
Two new dibenzyltin bisditiocarbamates(PhCH2)2 Sn(S2CNEt2)2(1) and (PhCH2)2 Sn(S2CNC4H8)2(2) were synthesized by the reaction of dibenzyltin dichloride with dithiocarbamates and characterized by elemental analysis ,IR,^1H NMR and MS spectra.The crystal structures were determined by X-ray single crystal diffraction analysis.In both complexes,the tin atom is six-coordinated in a distorted octahedral configuration.In the crystals of 1,the molecular packing in unit cell reveals that the two adjacent molecules are symmetrically linked to each other in dimers by two Sn S interactions of 0.3816nm.In the crystals of 2,the molecules are packed in the unit cell in one-dimensional chain structure linked by weaker intermolecular S S conmtacts. 相似文献
996.
XiLIFENG 《高校应用数学学报(英文版)》1997,12(4):483-492
For real-valued functions defined on Cantor triadic ,set. a derivative with corresponding formula of Newton-Leihniz‘s type is given In particular, for the self-simltar functions and alter-nately jumping functions defined in this paper, their derivative and exceptional sets are studied ac-curately by using ergodic theory on Е2 and Duffin-Scbaeffer‘s theorem coneerning metric diophan-tine approximation. In addition, Haar basis of L2(Е2) is constructed and Flaar expansion of stan-drd self-similar function is given. 相似文献
997.
Baran Sándor Pap Gyula Van Zuijlen Martien C. A. 《Statistical Inference for Stochastic Processes》2004,7(3):279-304
A shifted Wiener sheet is observed above a decreasing curve Γ. By the help of a direct discrete approach and under weaker
assumptions than in the paper of Arató [Comput. Math. Appl.
33 (1997), 13–25], an explicit formula is derived for the maximum likelihood estimator of the shift parameter. This estimator
is a weighted linear combination of the values at the endpoints of the curve Γ and weighted integrals of the observed process
and its normal derivative along the curve Γ.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
998.
本文讨论拟微分算子象证的Witt乘积与C[x]▲△A.G[p]的乘积之间的关系,得到以下结果:具有Witt乘积的象证类S1.0^m。是具有普通乘积的函数类S1.0^m经过对Hopf代数的乘积量子化得到的,进一步,给出了C[x]▲△h.cC[p]上标准的辫导数的显示表示,并且证明了其上的Poisson括号与经典的具有同一形式. 相似文献
999.
The structure of (+)1-(3-allylpropyl)-(5R,8S,10R)-N,N-diethyl-N-[6-methylergolin-8-yl]urea, C22H33N4O (allyl-terguride), has been determined as part of a study on the chiral recognition mechanism of ergot alkaloids when they are used as the chiral stationary phase for the separation of racemic mixtures in liquid chromatographic methods. At the pH of the solution used for the crystallization, the molecules of allyl-terguride are protonated at N(6). All bond distances and angles are in the expected ranges. In the asymmetric unit one hydroxide ion is present. Hydrogen bonds join molecules of allyl-terguride in pairs along the b axis, connecting O(2) of the hydroxide ion to O(1) of one molecule and to N(2) and N(6) of another. 相似文献
1000.
Summary Characteristics of silica gel dynamically modified with a bile acid derivative have been investigated in liquid chromatography. 3-[(3-cholamidopropyl) dimethylamonio]-1-propane-sulfonate (CHAPS) is selected as modifier. CHAPS possesses a quaternary ammonium group which can be attached to the silica gel surface by cation exchange. The stationary phase modified with CHAPS has been applied to the separation of 1,1-binaphthyl-2,2-diyl-hydrogen phosphate enantiomers.Dedicated to Professor Leslie S. Ettre on the occasion of his 70th birthday. 相似文献