Study on the Adsorption Characteristics of Inorganic Activated Charcoal Gel on Formaldehyde

In this paper, the powdered activated carbon is taken as the main raw material to develop a new material of inorganic activated charcoal gel by using silicate cement as the gelling agent. The micro-structure of this material is characterized by XRD, BET, SEM, EDS and so on; and the adsorption and cyclic regeneration characteristics of formaldehyde on the material are primarily studied. The experimental results show that this material is an adsorbent on the basis of micropores distributed between 0.60-1.12 nm, with specific surface area of 452.86 m2/g, average pore size of 2.62 nm and total pore space of 0.30 m3/g. The samples have excellent formaldehyde adsorption ability with saturation adsorption of 268.00 mg/g; after 20 times of cyclic adsorption and desorption, the formaldehyde adsorption rate of the samples can remain 49% of the original value, showing good cyclic regeneration of the samples.     

Synthesis and Characterization of Diethyl Fumarate‐1,4‐Cyclohexanedimethanol Polyesters for Use in Bioresorbable Bone Cement Composites

Unsaturated polyesters are prepared by transesterification polymerization of diethyl fumarate and 1,4‐cyclohexanedimethanol. The structure of the polyesters was characterized by FT‐IR and ¹H‐ and ¹³C‐NMR spectroscopy. Semicrystalline morphology of the polymers is suggested by DSC analysis with T_g at 21°C and melting at 140°C. The thermogravimetric analysis indicated that the onset of degradation takes place at 300°C. The polyester's structure has significant impact on the properties of the composites prepared by crosslinking the fumarate double bonds with N‐vinyl pyrrolidone in the presence of an inorganic filler, calcium sulfate dihydrate, with the addition of a radical initiator, benzoyl peroxide, at ambient temperatures. The compressive strength and hydrolytic stability of the cement compositions was correlated with structure of the polyesters.     

重金属污泥高温处理磨细粉对改性硫氧镁水泥基材料性能的影响

为探究重金属污泥高值资源化利用途径, 研究了含重金属污泥高温处理渣料磨细粉(简称磨细粉)对改性硫氧镁(MMOS)水泥基材料的工作性能、力学性能、早期自由收缩变形及其重金属浸出行为的影响. 结果表明: 随着磨细粉掺量的增加, MMOS水泥基材料的净浆流动度呈现逐渐增大趋势; 早期(3d)力学性能则呈现明显的降低趋势, 90d后磨细粉掺量对MMOS水泥基材料的力学性能的影响程度降低; 磨细粉可以显著降低MMOS水泥基材料早期的自由收缩变形值, 其中含10%磨细粉的MMOS水泥基材料早期的自由收缩变形比未掺加磨细粉MMOS水泥基材料的自由收缩变形值降低了57.1%. 微观分析结果表明: 掺加30%磨细粉后MMOS水泥基材料中水化产物5Mg(OH)2?MgSO4?7H2O(517相)的相对含量降低, MMOS水泥基材料硬化体的平均孔径提高了31.0%, 表明磨细粉降低了MMOS水泥基材料的力学性能. 当磨细粉掺量增加至40%时MMOS水泥基材料硬化体中重金属Ni、Cr、Zn和Cu的浸出浓度指标均能满足GB 30760-2014的浸出要求.     

水泥砂浆抗弹性能研究

对于水泥砂浆的抗弹性能研究,目前很少考虑靶体所处的应力状态,为此基于自研的真三轴静载混凝土侵彻实验装置和水泥砂浆抗弹性能实验结果,讨论了水泥砂浆在不同应力状态下的开坑深度和开坑阻力。应用侵彻深度的经验公式和基于HJC模型的有限元数值计算方法,对比分析了水泥砂浆侵彻实验,结果表明,对于低速冲击过程,采用UMIST公式和HJC模型的数值分析对开坑深度的预测较为有效。应力状态对开坑深度有明显的影响,即随着侧限增加,水泥砂浆的三轴强度提高,弹丸的开坑深度减小。应用基于HJC模型的数值分析方法,研究了弹丸开坑过程中弹体内的加速度波形和y轴支撑杆上的波形,结果表明:弹丸开坑过程对两种波形都有影响,其中y轴支撑杆上的波形可以更好地反映开坑过程。虽然数值模拟结果与实验波形的趋势基本一致,但是应力幅值有一定的差异,说明基于HJC模型的数值分析对开坑阻力的计算能力尚待提高。     

A Study on the Structure and Behavior of Sinter-free Material for Phosphorous Removal from Waste Water

Oyster shell and cement were taken as the major raw materials to fabricate hollow, tubular and recoverable material for phosphorous removal (P removal) from waste water without sintering. In this paper, the effects of different affecting factors on the sample P removal ratio were discussed to select optimal P removal process conditions. SEM and XRD were used to characterize the microscopic structures and composition of samples, and molybdenum blue spectrophotometry was applied to determine the P content in waste water. Results showed that at 30 ℃ for 2 d, the P removal ratio reached 93.3% when the cement content was 10 wt% and oyster shell powder was 90 wt%. SEM analysis revealed a flaky structure consisting of phosphorus-containing compound in the samples after P removal, and it piled on and maintained the porous structure. In addition, the results also suggested that raising the ambient temperature was benefit to the P removal. The P removal ratio of the material was optimal under neutral and alkali conditions.     

介孔硅酸镁改性硫酸钙骨水泥的降解及成骨性

将介孔硅酸镁(m-MS)掺杂到硫酸钙(CS)中,制备了一种新型复合骨水泥(m-MSC)。结果显示:掺入m-MS,延长了m-MSC的固化时间;提高了其降解速率;掺入m-MS可中和CS降解产生的酸性物质,缓解pH值下降。体外细胞实验显示:m-MSC能促进MC3T3-E1细胞增殖和分化;动物体内植入实验显示:m-MSC的成骨量和Ⅰ型胶原阳性表达率都显著高于CS。