Time-domain interferometry using synchrotron radiation applied to diffusion in ordered alloys

Time-domain interferometry of synchrotron radiation (TDI) has recently been used as a tool for investigating diffusion in glasses. This work deals with an extension of this technique to ordered structures. In a TDI experiment performed on the B2 alloy CoGa at the APS the intensity scattered into Bragg directions showed no detectable quasielastic signal. Experimental lower limits of the elastic contribution are given. They are in accordance with the coherent scattering function derived in this paper. This result indicates that TDI can be applied to diffusion in crystalline solids, e.g. intermetallic alloys, by using diffuse scattering. Requirements and limitations of diffuse scattering experiments are discussed. Received 21 September 2000 and Received in final form 13 December 2000     

Defect correction on Shishkin-type meshes

We consider a defect-correction method that combines a first-order upwinded difference scheme with a second-order central difference scheme for a model singularly perturbed convection–diffusion problem in one dimension on a class of Shishkin-type meshes. The method is shown to be convergent, uniformly in the diffusion parameter , of second order in the discrete maximum norm. As a corollary we derive error bounds for the gradient approximation of the upwind scheme. Numerical experiments support our theoretical results.     

Keggin结构阳离子[AlO4Al12(OH)24(H2O)12]7+与杂多阴离子构筑的新型无机纳米簇凝胶

多金属氧酸盐（Polyoxometalates POMs）化学已成为材料科学、医学、催化及光化学等诸多领域的活跃研究课题[1～5]。     

沸石分子筛膜缺陷的形成及修复*

分子筛膜在化学传感器、膜分离和膜催化等领域有潜在的应用前景。缺陷的存在降低了分子筛膜的筛分作用和分离选择性,从而限制了其工业应用。本文综述了沸石分子筛膜缺陷形成及修复方面的研究进展,详细介绍了沸石分子筛膜缺陷形成的原因,并按照过程机理将分子筛膜修复方法划分为多次合成法、积炭结焦法、表面涂层法、化学气相沉积法以及液相化学沉积法等。在深入分析了各种修复方法优缺点的基础上,对今后分子筛膜修复技术的发展趋势进行了展望。     

9600kW六轴电力机车转向架构架的静强度分析

大功率交流传动9600kW六轴电力机车用于重载货运牵引,本文一方面参照相关规范和标准,另一方面针对特殊运营、安装等特殊载荷,数值模拟了共计四十种工况,对其转向架构架的静强度进行了分析与讨论.研究所获得的数值结论具有重要的理论意义和工程应用价值,在为该型机车的投产以及相关的设计技术提供重要参考同时,也为大功率重载机车的构架计算的工况选取提供了很好的数值依据.     

TMB·TCNQ和硬脂酸混合LB膜的制备及表征

将没有双亲性的电荷转移配合物TMB·TCNQ (TMB：3, 3′,5,5′-Tetramethylbenzidine;TCNQ：7,7,8,8-tetracyanoquinodimethane)通过与硬脂酸混合组装制备了混合LB膜。TMB·TCNQ和硬脂酸的摩尔比例在1∶1, 1∶2和1∶3的情况下都可以成功进行组装。利用紫外-可见-近红外光谱、透射和掠角反射红外光谱、X射线衍射以及原子力显微镜研究了混合LB膜中各组分的结构、分子取向和表面形貌等。研究结果表明,混合LB膜中的TMB·TCNQ是混合堆积排列的,电荷转移度ρ约为0.35。配合物中的电子给体TMB和电子受体TCNQ分子的苯环平面都垂直于基底表面。硬脂酸的碳氢长链以一定角度倾斜于基底表面。混合LB膜的小角X射线衍射图中出现了两组衍射峰。混合比例为1∶1的单层和多层LB膜中出现纳米棒和微粒,而且,纳米棒和粒子的数量随着LB膜层数的增加而增多。     

应力S(t)为复合x~2-更新过程时结构可靠度渐近正态估计

该文讨论强度为随机变量Ｘ　应力为复合ｘ２－更新过程｛Ｙ（ｔ）,ｔ ∈［０,Ｔ］｝时结构可靠度的 渐近正态性问题．获得在设计基准期［０,Ｔ］ 内结构可靠度表达式和结构可靠度渐近正态估计．     

Some Results on the Problems of Block Theory

In this paper, we obtain two results on Brauer‘s k (B) - problem about finite groups under some conditions. Furthermore, we obtain that Olsson‘s conjecture holds under the same conditions on the finite groups.     

基于亏量方程的多重网格解法

基于亏量方程提出了一种生成多重网格插值公式的新方法,新插值公式充分利用了粗网格的信息,因而具有更高的精度.对Poisson方程,各向异性方程,双调和方程,甚至三维问题的数值试验表明,新插值公式改进了多重网格法的渐近收敛速度,节省了存储空间及计算时间.     

Influence of microscopic defects on optical damage resistance of Zn:Fe:LiNbO3 crystals

Influence of defect structure on the infrared transmission spectra of OH^‐ in Zn:Fe:LiNbO₃ crystals with various ZnO concentration and different Li/Nb ratios was investigated. It indicates that above the Zn concentration threshold the OH^‐ absorptions bands successively shift from 3482cm^‐1 to 3504cm^‐1 and 3529cm^‐1. The intensity of the 3504cm^‐1 band increases with ZnO concentration increasing. The optical damage resistance of the Zn:Fe:LiNbO₃ crystals increases rapidly when the ZnO concentration exceeds a threshold value. This result contributed to the site alteration from the Li sites to Nb sites due to Zn‐doping in crystal. © 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim