Transition metal complexes with thiosemicarbazide-based ligand – Part LV: Synthesis and X-ray structural study of novel Ni(II) complexes with pyridoxal semicarbazone and pyridoxal thiosemicarbazone

Reaction of aqueous solutions of Ni(NO₃)₂ and pyridoxal semicarbazone (PLSC) in the presence of NaN₃ afforded two complexes, viz. green, paramagnetic binuclear octahedral [Ni₂(PLSC)₂(μ_1,1-N₃)₂(N₃)₂] · 2H₂O (1) and, as admixture, red, octahedral [Ni(PLSC–H)₂] · 2H₂O (2) complex. Under the same reaction conditions, pyridoxal thiosemicarbazone (PLTSC) gave only one diamagnetic square-planar, red complex [Ni(PLTSC–H)N₃] · H₂O (3). In the absence of NaN₃, the reaction of PLTSC and Ni(NO₃)₂ yielded brown paramagnetic octahedral complex [Ni(PLTSC)₂](NO₃)₂ · H₂O (4).     

Structural modelling of icosahedral and simple cubic approximant phase in Al-Mn(Fe)-Si system

In spite of various models being available for the icosahedral quasicrystal structure in Al-Mn(Fe)-Si system, a consistent model for describing the simple cubic approximant and icosahahedral structure in terms of rational and irrational sections of the same six dimensional cubic crystal seems to be lacking. Such a model is presented and the subtle difference between the present model and the previous ones is discussed. The necessity of such considerations is spelt out while accomplishing the partitioning of the tricontahedral motif (with extension in three dimensional pseudo direct space) based on the chemistry of the alloy. An algorithm for generating the required polyhedra for partitioning is also presented.     

化学学习中记忆的7种缺陷

记忆是学生进行其他认知活动的基础,因记忆容量以及保持时间等限制具有一些缺陷,表现为分心、暗示、健忘、纠缠、空白、错认、偏颇等7种类型。记忆缺陷影响着学生的化学学习,了解化学学习中学生记忆的7种缺陷,可以精准地把握学生化学学习产生困难的原因,并采取一定的教学方法改进教学。     

固-固掺杂结构声子晶体中弹性波的缺陷模

为了研究弹性波在固-固掺杂结构声子晶体中缺陷模的特性,推导出弹性波斜入射固-固掺杂结构声子晶体的转移矩阵。利用它计算了固-固掺杂结构声子晶体中弹性波的透射系数,得到由于掺杂在禁带的中间出现了多条缺陷模透射峰带,缺陷模透射峰带随杂质厚度的变化呈周期性地出现,在同一缺陷模透射峰带上缺陷模的频率随杂质厚度增加近似呈线性减少。缺陷模的这些特征可以作为设计声子晶体滤波器的理论依据。     

Effect of structural defect on phonon transmission quantization in low-dimensional superlattices

Using the scattering-matrix cascading method, we investigate the effect of structural defect on the acoustic phonon transmission quantization in a low-dimensional superlattice quantum waveguide. In the present system, the phonon transmission exhibits rather complex resonant behaviors. It is found that a lateral defect in an otherwise periodic structure modifies the transversal phonon transmission spectra nontrivially and completely washes away the transmission quantization due to the strong additional scattering by defect. However, the appreciable quantization survives in the presence of a longitudinal defect. Our results also show that by adjusting the geometric parameters of the structural defect, one can control the phonon transport of the structure to match practical requirements in devices.     

Optimization of spot-welded structures

This paper addresses the optimization problem of a spot-welded structure under fatigue life consideration. The so-called umbrella model of spot welds and the radial stresses around a spot weld were introduced into the optimization process. The idea was to study the optimization problem using the type of analysis which is now considered to be valid for fatigue life prediction. Two formations were considered: one maximizes the stiffness of a structure under fatigue life constraints and the other seeks the maximum fatigue life of the structure. The optimization results show that the optimization process has successfully found the global minimum values of the corresponding objective functions for both the formations.     

半无限体内双圆柱亚表面热波散射问题的研究

本文基于非傅里叶导热定律,采用波函数展开法,研究了含双圆柱缺陷非透明半无限体中热传播问题,给出了基于热传导波动模型的热波散射问题的一般解．温度波由调制光束在材料表面激发,缺陷表面的边界条件为绝热,分析了各物理参数对温度分布的影响,特别是热波波长对温度变化的影响,并给出了温度变化的数值结果。     

铁基非晶稀土合金的结构转变和结构弛豫

通过对铁基非晶稀土合金结构转变和结构弛豫过程特征的研究，讨论了该材料的稳定性；认为稀土成份是影响合金品质和应用前景的关键因素。     

Perturbation of semi-Browder operators and stability of Browder's essential defect and approximate point spectrum

In the present paper we investigate the stability of closed densely defined semi-Browder operators under operator perturbations that belong to a perturbation class related to compact operators. Furthermore, we apply the obtained results to give a characterization and to study the stability of Browder's essential approximate point spectrum and Browder's essential defect spectrum.