镁热还原CO2气体制备介孔石墨烯及其电容特性研究

以CO_2为原料,采用金属镁热还原法,制备出富含介孔结构的石墨烯材料。分别利用X射线衍射、扫描电镜、透射电镜、拉曼光谱和N_2吸附-脱附等测试手段对材料的微观结构进行了表征。通过在镁粉中加入不同质量的MgO,可以实现对石墨烯形貌和孔结构的调控,当MgO/Mg质量比为8∶1时,产物(MRG-8)具有均一的介孔结构(4nm)。并对材料的电化学性能进行了测试,在1mol/L KOH的电解液中,MRG-8具有最高的比电容(171F/g),同时具有非常好的倍率特性,循环测试12000周,比电容保持率为94%。当采用[EMIM][BF4]离子液体作为电解液,以MRG-8为电极材料组装成的对称型超级电容器显示出超高功率密度(175k W/kg),对应的能量密度为28.1Wh/kg。因此,采用此方法制备的介孔石墨烯材料在高功率的超级电容器领域具有潜在的应用前景。     

加窗后波前功率谱密度的计算值修正

 波前功率谱密度的数值计算会由于窗函数的使用引入较大的计算误差。通过对模拟的单一频率波前加窗前后的功率谱密度的理论计算,由傅里叶变换性质推导出了修正因子,并对波前频率与修正因子的关系进行了理论研究。结果表明,在一定的波前频率及误差范围内,对加汉宁窗后1维功率谱密度的计算结果乘上一个常量8/3即可实现简单有效地修正。     

脉冲压缩系统中气体开关对功率增益的影响

 对高功率微波脉冲压缩系统中气体开关对功率增益的一些重要影响进行了较详尽的理论分析,包括气体开关在导通过程中吸收微波能量,等离子体瞬间功率损耗使得谐振腔固有品质因数的下降,开关导通后等离子体并非理想良导体等,并将这些影响用修正系数来加以体现,对原有的用微波等效电路理论推导出的功率增益公式加以修正,使得理论公式的精确度由原来的60%提高至约85%。     

P沟道和N沟道MOS场效应管的辐照实验研究

通过对P沟道MOS场效应管IRF9530和N沟道MOS场效应管IRF540N的X射线和钴源γ射线的辐照对比研究,发现两种场效应管阈值电压变化随吸收剂量近似成一阶指数衰减关系。产生这种现象的原因是场效应管氧化物中的空间俘获电荷与吸收剂量近似成线性变化,对阈值电压变化和吸收剂量有近似线性的改变;而界面态对空间电荷有补偿作用,其对阈值电压的改变与吸收剂量有近似成二次方的关系。     

等离子体断路开关和电感负载间的功率流特性

利用PIC (particle-in-cell) 方法,结合实验装置的几何结构和实验结果,采用动态开关模型,对微秒等离子体断路开关和电感负载间的功率流特性进行了研究。模拟得到了与实验结果符合较好的开关电压和负载电流波形,并给出了开关下游出现的稀薄等离子体的密度(约1012 cm-3)和速度(约1 cm/ns), 同时也得到了开关下游的空间电流分布。模拟结果表明,开关下游的结构应避免阻抗突变以减少电流损失,同时提高开关阻抗可有利于提高负载上的最大功率。     

Effect of power ultrasound on crystallization characteristics of magnesium ammonium phosphate

Magnesium ammonium phosphate (MAP) crystallization could be utilized for the recovery of phosphorus from wastewater. However, the effectiveness of the recovery is largely determined by the crystallization process, which is very hard to be directly observed. As a result, a specific ultrasonic device was designed to investigate the crystallization characteristics of MAP under various ultrasonic conditions. The results demonstrated that the metastable zone width (MZW) narrowed along with the rising of the ultrasonic power. Similarly, for the 6 mM MAP solution, with the ultrasonic power gradually enhanced from 0 W to 400 W, the induction time was shortened from 340 s to 38 s. Meanwhile, the crystallization rate was accelerated till the power reached 350 W, and then remained a constant value. It can be observed from the scanning electron microscopy (SEM), the MAP crystal became bigger in size as well as the crystal size distribution (CSD) became broad and uneven, with the increase of ultrasonic power. The results indicate that the crystallization process enhanced by power ultrasound could be used as an effective method to eliminate and recover the phosphorus from wastewater.     

Power extraction efficiency improvement of a fully-activated flapping foil: With the help of an auxiliary rotating foil

The power extraction efficiency improvement of a fully-activated flapping foil with the help of an auxiliary rotating foil is numerically examined in this work. A NACA0015 airfoil is placed in a two-dimensional laminar flow and synchronously performs the imposed pitching and plunging motions. An auxiliary smaller foil, which rotates about its center, is arranged below the flapping foil. As a consequence, the vortex interaction between the flapping foil and the rotating foil occurs. At a Reynolds number of 1100 and the position of the pitching axis at one-third chord, the effects of the distance between the flapping foil and the auxiliary foil, the phase difference between the rotating motion and the flapping motion as well as the frequency of flapping motion on the power extraction performance are systematically investigated. It is found that compared to the single flapping foil, the efficiency of power extraction for the flapping foil with an auxiliary device can be improved. Based on the numerical analysis, it is indicated that the enhanced plunging contribution, which is caused by the increased lift force owing to the vortex interaction, directly helps the efficiency improvement.     

Quantifying price fluctuations in the Brazilian stock market

This paper investigates price fluctuations in the Brazilian stock market. We employ a recently developed methodology to test whether the Brazilian stock price returns present a power law distribution and find that we cannot reject such behavior. Empirical results for sub-partitions of the time series suggests that for most of the time the power law is not rejected, but that in some cases the data set does not conform with a power law distribution.     

Non-monotonic driven vortex noise in HTSC

We present noise measurements on YBCO thin films in different conditions of magnetic field and driving current. Noise spectra for non-driven and driven cases (in the flux-creep region) evidence deep differences in vortex dynamics between these two regimes. For the driven case, the effect of applying magnetic field is a reduction in noise, which can be explained by the increase in the fraction of vortices that undergo flux-flow. For the non-driven case, magnetic field has no significative influence on noise, probably due to the absence of Lorentz force that causes coherent movement of vortices. For all magnetic fields studied in this work (0-154 mT) the effect of increasing current is an increase of noise, which is in contrast to the results from other authors. This behavior can be explained by an increase of current induced vortex-antivortex annihilation events. We propose that driven noise has a non-monotonic behavior due to the competition between annihilation events and driving force which causes opposite effects on noise.     

二维光子晶体功率分配与合成的仿真

利用平面波展开法,绘出了光子晶体的能带结构图,揭示了光子晶体能带结构的特点.在带隙结构中引入线缺陷,实现了对电磁波传播方向的控制.通过设计不同的线缺陷分布,实现了对电磁波传输能量的分配与合成.最终完成了对电磁波传播方向的控制和功率分配及合成的引导.采用Comsol Multiphysics软件对空气背景不同形状的介质光子晶体进行功率分配与合成的仿真,结果表明,在光子晶体中通过对线缺陷的设计,可实现功率的分配与合成.