The solubility of bosentan in aqueous-2-propanol mixtures at several temperatures,measurement and data correlation

ABSTRACT

The solubilities of bosentan (BST) in binary aqueous mixtures of 2-propanol at temperatures ranging from 293.15 to 313.15 K were determined using a shake-flask method. The produced data were modelled with the Jouyban-Acree-van’t Hoff model and difference between the predicted data and experimental ones were illustrated by percent average relative deviations (%ARD). Moreover, the thermodynamic functions of dissolution for BST in the aqueous 2-propanol solutions were computed which suggest that the dissolution process is endothermic and not spontaneous.     

UHF机械调谐器调谐电容片形的程序设计

采用传输线理论可以计算机械式UHF调谐器对应不同频率点的调谐电容量。在进行满足直线频率关系的调谐电容片形设计时,应当求出调谐电容量C_Τ与旋转角θ的显式函数关系。但对于分布参数的电路,这有一定的困难。本文采用数值计算方法完成了具有良好直线频率跟踪特性的调谐电容片形的设计,并由计算机自动绘出了片形。     

An efficient Fréchet differentiable high breakdown multivariate location and dispersion estimator

A good robust functional should, if possible, be efficient at the model, smooth, and have a high breakdown point. M-estimators can be made efficient and Fréchet differentiable by choosing appropriate ψ-functions but they have a breakdown point of at most 1/(p + 1) in p dimensions. On the other hand, the local smoothness of known high breakdown functionals has not been investigated. It is known that Rousseeuw's minimum volume ellipsoid estimator is not differentiable and that S-estimators based on smooth functions force a trade-off between efficiency and breakdown point. However, by using a two-step M-estimator based on the minimum volume ellipsoid we show that it is possible to obtain a highly efficient, Fréchet differentiable estimator whilst still retaining the breakdown point. This result is extended to smooth S-estimators.     

Hyperbolic -spheres with conical singularities, accessory parameters and Kähler metrics on

We show that the real-valued function on the moduli space of pointed rational curves, defined as the critical value of the Liouville action functional on a hyperbolic -sphere with conical singularities of arbitrary orders , generates accessory parameters of the associated Fuchsian differential equation as their common antiderivative. We introduce a family of Kähler metrics on parameterized by the set of orders , explicitly relate accessory parameters to these metrics, and prove that the functions are their Kähler potentials.

     

General criterion to discern between coherent and incoherent synthesis of broadband coherent anti‐Stokes Raman spectra

Recently, the ordinary qualitative criterion on how to distinguish between coherent and incoherent convolutions of broadband coherent anti‐Stokes Raman (CARS) signals generated by degenerate pump lasers has been revised in view of a quantitative analysis. The revision has established that incoherent CARS approach can be justified as unitary limit of the function ] erfc(Γ/σ₁)/σ₁, where Γ and σ₁ are respectively the spectral widths of the Raman line and the degenerate pump lasers. The result was, however, limited to nonoverlapping Raman lines. In this work, the extension to a more common situation of closely spaced Raman transitions is considered. For large overlap between adjacent Raman lines, the new analysis suggests significant deviations from the previous result. Weak line mixing is also taken into consideration. Nonetheless, all types of deviations are characterized by a common tendency toward the incoherent limit. Copyright © 2007 John Wiley & Sons, Ltd.     

Improved Ligand-Field Theory with Effect of Electron-Phonon Interaction

Traditional ligand-field theory has to be improved by taking into account both “pure electronic” contribution and electron-phonon interaction one (including lattice-vibrational relaxation energy). By means of improved ligand-field theory, R₁, R₂, R₃', R₂', and R₁' lines, U band, ground-state zero-field-splitting (GSZFS), and ground-state g factors of ruby and/or GSGG:Cr³⁺ as well as thermal shifts of GSZFS, R₁ line and R₂ line of ruby have been calculated. The results are in very good agreement with the experimental data. Moreover, it is found that the value of cubic-field parameter given by traditional ligand-field theory is inappropriately large. For thermal shifts of GSZFS, R₁ line and R₂ line of ruby, several conclusions have also been obtained.     

人颅骨结构的动力参数

为了深入探讨人头部受撞击时颅脑损伤的力学计算模型,本文对颅骨结构的功力参数连行了测试和有限元分析。结果表明,人颅骨结构属于小阻尼结构,进行动力分析时可以抽象成弹性阻尼薄壳结构。     

氮化硅陶瓷平板振动模态参数的研究

本文采用压电陶瓷片测振技术,试验分析了氮化硅陶瓷平板的固有频率及模态阻尼比,试验结果与有限元计算结果比较吻合。本文还对氮化硅陶瓷平板与普通钢平板做了对比试验,结果表明氮化硅陶瓷平板的固有频率及模态阻尼比都较高。     

静态傅里叶变换超光谱全偏振成像技术

光谱偏振成像技术是成像光谱技术与偏振成像技术的有机融合, 是当前空间光学遥感技术研究的热点和前沿. 针对目前光谱偏振成像技术受测量原理、探测模式的限制, 普遍需要运动、电控调制等部件, 导致体积大, 结构复杂, 加工装调困难, 抗振能力差等问题, 我们于2010年在国际上首先提出了一种多信息融合的静态傅里叶变换超光谱全偏振成像方法. 本文在此基础上, 阐述了新方法的基本原理, 给出了具体实现方案. 新方案无需运动、电控调制部件, 可实现目标图像、光谱、全偏振信息的一体获取. 推导出了新方案的调制干涉强度数据表达式及Stokes矢量解调公式, 分析了新方法实现光谱、全偏振探测的物理过程. 对新方案进行了计算机数值模拟验证, 研制了原理验证样机开展了室内、室外验证实验, 首次获得了室外推扫光谱图像数据立方体和全色全偏振度图像, 模拟及实验结果均表明新方案原理正确, 技术可行. 上述研究为新型空间遥感器的开发提供了基础理论及实践支持. 关键词： 成像光谱 偏振成像 Stokes矢量     

色散补偿光子晶体光纤结构参数对其色散的影响

光子晶体光纤由于其灵活可调的色散特性用作色散补偿具有极大的应用潜力. 设计了一种色散补偿光子晶体光纤, 并运用频域有限差分法模拟了其色散特性,从理论上分析了其结构参数孔间距Λ和空气占空比d/Λ对该光子晶体光纤的色散系数的影响, 并且实际制备出了3种不同结构参数的光子晶体光纤. 通过对其色散曲线对比分析表明: 当光子晶体光纤孔间距在1 μm附近时, 其色散系数随着孔间距Λ和占空比d/Λ的增大而增加, 但对于孔间距Λ的变化比占空比d/Λ更为敏感, 并且随着孔间距Λ的增加,其对色散系数的影响能力逐渐减小. 设计并制备的光子晶体光纤在1550 nm处的色散系数为-241.5 ps·nm^-1·km^-1, 相对色散斜率为0.0018, 具有较好的色散补偿能力. 关键词： 色散 色散补偿 光子晶体光纤 结构参数