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991.
DYNAMIC RHEOLOGICAL BEHAVIOR OF POLYPROPYLENE FILLED WITH ULTRA-FINE POWDERED RUBBER PARTICLES 总被引:2,自引:0,他引:2
QiangZheng Yan-xiaCao MiaoDu 《高分子科学》2004,(4):363-367
Dynamic rheological characteristics of polypropylene (PP) filled with ultra-fine full-vulcanized powdered rubber (UFPR) composed of styrene-butadiene copolymer were studied through dynamic rheological measurements on an Advanced Rheometric Expansion System (ARES). A specific viscoelastic phenomenon, i.e. “the second plateau“, appeared at low frequencies, and exhibits a certain dependence on the amount of rubber particles and the dispersion state in the matrix. This phenomenon is attributed to the formation of aggregation structure of rubber particles. The analyses of Cole-Cole diagrams of the dynamic viscoelastic functions suggest that the heterogeneity of the composites is enhanced on increasing both particle content and temperature. 相似文献
992.
Wilasinee Kongsuebchart Joongjai Panpranot Chairit Satayaprasert Piyasan Praserthdam 《Reaction Kinetics and Catalysis Letters》2007,91(1):119-126
Nanocrystalline TiO2 powders with average crystallite sizes of 9–15 nm were synthesized by the solvothermal method and employed as supports for
Co catalysts. The value of H2 chemisorption/specific surface area of Co/TiO2 increased significantly with increasing TiO2 crystallite size. It was suggested that the higher amount of Ti3+ surface defects on the larger crystalline TiO2 resulted in a stronger interaction between Co and TiO2, hence, higher dispersion of Co was obtained. 相似文献
993.
邻苯二甲酸Pb(Ⅱ)配合物纳米颗粒的合成及其燃烧催化性能研究 总被引:6,自引:0,他引:6
The nanoparticle Pb(Ⅱ)-Phtalate complex was synthesized by liquid dispersion deposition method using Pb(Ac)2·3H2O and potassium acid phthalate as the reactant. The nanoparticle complexes were characterized with TEM, XRD, TG, DSC and IR. The composition of the nanoparticle PbPht complex was determined by chemical and elemental analysis. The catalytic performance of nanoparticle complex on the combustion of RDX-CMDB propellant was investigated. The results showed the average particle size of complex were about 50 nm. The nanoparticle Pb(Ⅱ)-Phtalate complex can enhance burning-rate of propellant by 135%, and lower the pressure exponent by 74%. 相似文献
994.
Neal Tai-sheng Chung 《高分子科学》2000,(5):459-463
Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by "stepwise coupling polymerization".The molecular weight of CP-T is as high as 1.7×10~5. It is a tough, elastic reactive ladderlike polymer and has good heat-resistant and adhesive properties. CP-T can further react with many nucleophilic reagents to generate new ladderlike reactivepolysilsesquioxanes, which can be used as potential precursors in the synthesis of functional ladderlike polymers. 相似文献
995.
996.
The crystal structure of air-dried crystals of the O-monocarboxylic acid of cyanocobalamin, E2, has been solved by x-ray analysis.
The lattice constants area =14-51 A,b = 1709 A,c = 16.35A, β = 103°; space group P21. Phase angles were derived from observations on anomalous dispersion effects for 2567 of the measured 2875 pairs of reflections,hkl andhkl, and used in the solution of the structure. The intensities of reflexions were eye estimated from Weissenberg photographs.
The molecular arrangement is very different from that of other cyanocobalamins; the corrin rings of neighbouring molecules
are atca 90° to one another. It was not possible to recognise the one acid group among the amides with certainty. 相似文献
997.
用化学计量法—分光光度法测定活体叶片中叶绿素a,b的含量 总被引:2,自引:0,他引:2
本文研究了用逐步回归分析法、主成分回归法、偏最小二乘法与人工神经网络法测定活体叶片中叶绿素a、b的含量。活体叶片的光谱由PC微机采集,测定叶绿素a与b的相关系数分别达到0.927~0.958与0.873~0.908;相对标准偏差约5%~9%(叶绿素a 9.4μg/2ml,n=20)。本方法可用于农业研究。 相似文献
998.
999.
1000.
氨基酸结构描述子矢量VHSE及其在肽QSAR中的应用 总被引:8,自引:0,他引:8
从20种天然氨基酸的50个物化性质出发,按照疏水、立体和电性特征将其分类后分别进行主成分分析,并将产生的得分矢量即VHSE(principal component score vector of hydrophilicity,steric,and electronic properties)作为氨基酸结构描述子用于肽的定量构效关系研究。与已有方法相比,VHSE描述子具有物化意义明确、结果更易解释等特点。应用该描述子并结合逐步回归变量筛选和偏最小二乘建模方法,在对苦味二肽和血管舒缓激肽促进剂等体系的定量构效关系研究中,均取得了优于已有文献的结果。 相似文献