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11.
12.
We study the optimal conditions for nanoisland growth in ion beam assisted deposition (IBAD). This situation occurs when adatom islands remain small enough to prevent the onset of three-dimensional growth, while at the same time preventing ion-induced surface erosion. To this end, we develop a rate equation model of IBAD, which embodies continuous deposition of adatoms and creation of vacancies, recombination of vacancies at adatom island edges, as well as recombination of adatoms at vacancy island edges. These rate equations are solved by numerical simulations based on the particle coalescence method. To determine the optimal growth condition, we find the largest mean size of the vacancy islands leading to their survival. We show that at this onset between the rough and smooth layer-by-layer growth regimes there is a simple exponential relation between the largest size of the vacancy islands and the external control parameters of the growth. 相似文献
13.
J.S. Wettlaufer 《Interface Science》2001,9(1-2):117-129
The dynamics of faceted and partially faceted single crystal and polycrystalline ice are reviewed with an emphasis on the manner in which microscopic effects produce macroscopic shapes. Our understanding of the former is rooted in the basic kinetics common to all materials and our pursuit of the latter is largely motivated by the striking patterns exhibited in the natural environment when water changes phase to become ice. 相似文献
14.
The roughening of interfaces as a function of layer thickness and magneto transport properties have been investigated on sputter-deposited Fe/Ni75B25 multilayer films. X-ray reflectivity data were recorded for Ni75B25(72 nm) film and for [Fe(2 nm)/Ni75B25(2 nm)]16 and [Fe(4 nm)/Ni75B25(4 nm)]8 multilayer films. A power law dependence of the interfacial width of growing Fe/Ni75B25 interfaces was observed. The resulting growth exponents β were found to be in the range of 0.55–0.58 in the initial growth stage of the multilayer with lower Fe/Ni75B25 repetition thickness and at approximately 0.34 for multilayer with higher repetition thickness. The growth exponents were compared with theoretical calculations. High resolution electron microscopy revealed the columnar growth of the Fe/Ni75B25 multilayer. Additionally, an increase of magnetoresistance was observed by the multilayering of Ni75B25 films with Fe interlayers. 相似文献
15.
This paper presents a modified descent method for solving co-coercive variational inequalities. Incorporating with the techniques of identifying descent directions and optimal step sizes along these directions, the new method improves the efficiencies of some existing projection methods. Some numerical results for an economic equilibrium problem are reported. 相似文献
16.
Tin oxalate as a precursor of tin dioxide and electrode materials for lithium-ion batteries 总被引:2,自引:0,他引:2
R. Alcántara Fernández F. Madrigal P. Lavela C. Pérez-Vicente J. Tirado 《Journal of Solid State Electrochemistry》2001,6(1):55-62
Tin(II) oxalate was studied as a novel precursor for active electrode materials in lithium-ion batteries. The discharge of
lithium cells using tin oxalate electrodes takes place by three irreversible steps: tin reduction, forming a lithium oxalate
matrix; solvent decomposition to form a passivating layer; and oxalate reduction in a two-electron process. These are followed
by reversible alloying of tin with lithium, leading to a maximum discharge of 11 F/mol. Cycling of the cells showed reversible
capacities higher than 600 mAh/g during the first five cycles and ca. 200 mAh/g after 50 cycles. Tin oxalate was converted
to tin dioxide by thermal decomposition at 450 °C and also by a chemical method by dissolving tin oxalate powder in 33% v/v
hydrogen peroxide at room temperature. The ultrafine nature of the tin dioxide powders obtained by this procedure allow their
use as electrodes in lithium cells. The best capacity retention during the first five cycles was achieved for a sample heat
treated to 250 °C to eliminate surface water.
Electronic Publication 相似文献
17.
18.
J. Ledieu R. McGrath Q. Chen T.A. Lograsso K.J. Caspersen B. Unal P.A. Thiel 《Surface science》2005,583(1):4-15
We compare step morphologies on surfaces of Al-rich metallic alloys, both quasicrystalline and crystalline. We present evidence that the large-scale step structure observed on Al-rich quasicrystals after quenching to room temperature reflects equilibrium structure at an elevated temperature. These steps are relatively rough, i.e., have high diffusivity, compared to those on crystalline surfaces. For the fivefold quasicrystal surface, step diffusivity increases as step height decreases, but this trend is not obeyed in a broader comparison between quasicrystals and crystals. On a shorter scale, the steps on Al-rich alloys tend to exhibit local facets (short linear segments), with different facet lengths, a feature which could develop during quenching to room temperature. Facets are shortest and most difficult to identify for the fivefold quasicrystal surface. 相似文献
19.
The influence on thermal roughening of interactions beyond nearest neighbor sites on a surface is examined. In addition to the classical gradient term a novel dependence upon curvature appears in the surface energy. For interactions oscillatory with distance the curvature term can be dominant. The short range correlation function is then linear, it crosses over to the usual logarithmic behavior at large distances. This formalism can explain experimental results in disagreement with existing models. The non-trivial influence of finite size effects in anisotropic systems is also studied. 相似文献
20.
For electrical double layers, the presence of a Helmholtz layer could lead to electrode roughness attenuation. The latter is assumed of self-affine type which is characterized by the roughness amplitude w, the correlation length ξ, and the roughness exponent H. For sufficiently rough metal electrode surfaces (H1 and/or ratios w/ξ0.1) the diffuse/Helmholtz layer interface would not have the same roughness parameters with the metal electrode surface. If the latter is smoothened at lateral length scales smaller than a healing length Λ (ξ), the diffuse charge capacitance decreases and approaches values close to that of the Gouy–Chapman theory for flat electrodes. 相似文献