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991.
Synthesis of Tetrahydrofuran and Tetrahydropyran Derivatives Catalyzed by Tungstophosphoric Acid in Ionic Liquid 总被引:3,自引:0,他引:3
Wen PEI Li SUN Chun Hua XIONG Chen SHEN 《中国化学快报》2005,16(9):1155-1157
Synthesis of tetrahydrofuran and tetrahydropyran derivatives catalyzed by tungstophosphoric acid (H3PW12040) were conveniently performed with high yield from the corresponding unsaturated alcohols in ionic liquid. Sufuric acid (H2SO4), trifluoromathanesulfonic acid (TfOH) and p-toluenesulfonic acid (TsOH) were also explored for preparing these products in ionic liquid. The catalysts and ionic liquid can be easily recovered and reused. 相似文献
992.
I. A. Sukhina R. P. Mamedova M. A. Agzamova M. I. Isaev 《Chemistry of Natural Compounds》2007,43(2):159-161
The two trisdesmoside cycloartane glycosides astragaloside VII and cyclotrisectoside were isolated from Astragalus dissectus (Leguminosae) and identified. The latter was 20R,25-epoxy-24S-cycloartan-3β,6α,16β,24-tetraol 3-O-β-D-xylopyranoside-6,24-di-O-β-D-glucopyranoside and was a new natural compound.
Presented at the Sixth International Symposium on the Chemistry of Natural Compounds (SCNC, Turkey, Ankara, 28–29 June 2005).
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 132–134, March–April, 2007. 相似文献
993.
The Commission Decision of August 12, 2002 on the performance of analytical methods and the interpretation of results was applied to the HPLC method for the analysis of parabens, 2-phenoxyethanol and 1-phenoxypropan-2-ol in cosmetic products. This method is published in the seventh Directive 96/45/EC of the European Commission. Non-compliant concentrations, taking into account the data distribution (CC) and the probability of false negative values (CC) were determined. The repeatability and reproducibility amount to <4% and <7%, respectively. These values were obtained with blanc samples that were fortified in the laboratory. Calibration linearity was confirmed by absence of lack of fit for all seven preservatives. Matrix effects on the determinations of the preservatives in body milk or shampoo are negligible. 相似文献
994.
A convenient and efficient preparation of Stryker's reagent, [Ph3PCuH]6, under homogeneous conditions using silanes as the reducing agent is detailed. The reaction time can be reduced to 1-2 h, and high yields of Stryker's reagent can be routinely achieved. The same method has been extended to the synthesis of [Ph3PCuD]6 using Ph2SiD2. 相似文献
995.
The acetone-butanol production by simultaneous saccharification and extractive fermentation (SSEF) was investigated. In the
SSEF employing cellulase enzymes andClostridium acetobutylicum, both glucan and xylan fractions of pretreated aspen are concurrently converted into acetone and butanol. Continuous removal
of the fermentation products from the bioreactor by extraction was an important factor that allowed long-term fed-batch operation.
The use of membrane extraction prevented the problems of phase separation and extractant loss. Increase in substrate feeding
as well as reduction of nutrient supply was found to be beneficial in suppressing the acid production, thereby improving the
solvent yield. Because of prolonged low growth conditions prevalent in the fed-batch operation, the butanol-to-acetone ratio
in the product was significantly higher at 2.6–2.8 compared to the typical value of two. 相似文献
996.
The emeraldine base form of polyaniline (PANI) can be doped by a photo-induceddoping method. In this method a copolymer of vinylidene chloride and methyl acrylate(VCMAC) was used as photo acid generator which can release proton when it is exposedto ultraviolet light (λ= 254 nm). The structure of PANI-VCMAC system before and afterirradiation was characterized by elemental analysis, IR, XPS, and SEM images. Resultsobtained indicate that the photo-induced doping characteristics, such as doping positionand type of charge carriers, are similar to that of PANI doped with HCl. The poor room-temperature conductivity (~10~(-5)S/cm) of PANI-VCMAC system after irradiation maybe due to low doping degree (~pH= 3) and the difference in morphology as compared withPANI-HCl film. 相似文献
997.
Monir Uddin Antonis G. Hatzidimitriou Maria Lalia-Kantouri Chris Tsiamis 《Structural chemistry》1997,8(2):131-139
The infrared and electronic excitation spectra of a series of new nickel(II) chelates containing an-diimine (or nitrogenous base, enR) and the anion of a-dione (1,3-ketoenol or 1,3-ketoester,H) were obtained in the solid state and in solution. The composition and the overall structure of the new chelates in the solid state depends on ligand concentration, the substituents within the-dionato moiety and the counterion present. The IR and electronic excitation spectra of [Ni(enR)2
]NO3 and [Ni(enR)(O2NO)] indicate, in conjunction with other physicochemical measurements, bidentate coordination of the ligands, while the spectral shifts reveal replacement of the (O,O)nitrato group by basic solvents. The existence of the nickel(II) in an octahedral environment is confirmed by an X-ray structure analysis of [Ni(dpamH)2acac]NO3 · CH3OH (monoclinic, space groupP2l/n, a=17.296(1),b=7.462(1),c=21.604(3) å,=95.65(1),Z=4, R=0.0534,Rw=0.0600), where dpamH denotes the 2,2-dipyridylamine. 相似文献
998.
Bis-(2,4,5-triphenylimidazolyls) result from the dimerization of 2,4,5-triphenylimidazolyls and from the nucleophilic attack of 2,4,5-triphenylimidazole anions upon 2,4,5-triphenylimidazolylium cations. The isomeric bis-imidazolyls consist of imidazole and isoimidazole systems. Imidazoles undergo only anodic oxidation, isoimidazoles only cathodic reduction. Therefore the bis-imidazolyls may be analyzed from their electrochemical behaviour. Bis-(2,4,5-triphenylimidazolyl)-1,2′ and bis-(2,4,5-triphenylimidazolyl)-1,4′ undergo reductive bond cleavage in an ē.c?.ē. mechanism from which 2,4,5-triphenyl-imidazole anions result. The electrochemical properties of one of the bis-imidazolyls agree with that of 1,4,5-triphenyl-2-(2,4,5-triphenylisoimidazolyl-4)-imidazole and not with that of bis-(2,4,5-triphenylimidazolyl)-2,4′ as reported in literature. 相似文献
999.
以乙酰丙酮镍、油酸、油胺为原料,十八烯为溶剂,聚乙烯吡咯烷酮为表面活性剂,采用溶剂热法,在不同反应条件制备了纳米级氧化镍材料.通过X射线衍射(X-ray diffraction,XRD)、透射电子显微镜(Transmission electron microscope,TEM)、紫外-可见光吸收光谱(Ultraviolet-visible spectroscopy,UV-Vis)光谱分析以及塔菲尔(Tafel)测试考察了反应物比例、保温时间、表面活性剂(PVP)、油胺的量对产物微结构、粒径、形貌、光学以及电化学活性性能的影响.实验结果表明:在反应物n[Ni(acac)2]∶n(OA)=1∶2、添加剂PVP质量分数为1.66%、油胺物质的量为30 mmol、200℃下保温8 h时,可获得粒径约为30~40 nm纯相氧化镍,具有最佳电化学活性,交换电流密度为J0=1.23×10-2 mA·cm-2. 相似文献
1000.
Andrzej W. Trochimczuk Shoji AokiKazunori Yamabe Akinori Jyo 《European Polymer Journal》2002,38(5):941-945
Four porous vinylnaphthalene/divinylnaphthalene (VN/DVN) polymers having three different nominal crosslinking degrees (60, 80 and 100 wt.%) have been synthesized using the suspension polymerization method in the presence of toluene and decane.The use of various crosslinking levels and inert diluents was aimed at changing the extent of polymeric network-diluent interactions. The resultant polymers have specific surface area in the range 450-700 m2/g depending on the DVN content. Two sets of pores were detected in all resins: one with the diameter of ≈2 nm and the second one in the range of 30-40 nm. Their sorptive properties have been studied using dilute (0.5 mmol/l) solutions of phenol and its derivatives (o-chlorophenol, 2-methylphenol, o-nitrophenol, m-nitrophenol and p-nitrophenol). It has been found that sorption, at low equilibrium concentration, follows the order: o-nitrophenol > o-chlorophenol > m-nitrophenol > o-methylphenol > p-nitrophenol > phenol. Full characteristics of the porous structure of resultant polymers was obtained by nitrogen adsorption at 77 K and their surface properties analyzed using Inverse Gas Chromatography. 相似文献