基于Android的大学物理移动学习平台设计及应用研究

移动学习作为一种新型的学习模式使学习者摆脱时间和空间的束缚,实现真正意义上的自主学习.本文基于对大学物理课程教学现状和学生学习需求的分析,设计并开发了基于Android系统的大学物理移动学习平台,并应用于课程开展教学实证研究,通过测试和问卷调查评估平台的应用效果.     

基于Si3N4/SiNx/Si3N4三明治结构的偏振无关1×2多模干涉型解复用器的设计

提出一种基于Si3N4/SiNx/Si3N4三明治结构多模干涉波导的偏振无关1×2解复用器,用于分离1310和1550 nm两个波长.通过合理选择三明治结构中间层SiNx的折射率,可以调节同一波长两个正交偏振态的拍长相等,实现偏振无关;根据多模干涉原理,通过合理选择多模干涉波导的长度与宽度,可以使两个波长的输出像点分别成正像和反像,实现解复用功能.运用三维有限时域差分法进行建模仿真,对结构参数进行优化,并对器件关键结构参数的制作容差进行了分析.结果表明:该器件多模干涉波导的尺寸为4.6μm×227.7μm,插入损耗低至0.18dB,输出波导间的串扰低至–25.7dB, 3dB带宽可达60 nm.另外,本文提出的器件采用Si3N4/SiO2平台,可有效减小波导尺寸,提高集成度,不仅实现了偏振无关,而且结构紧凑、损耗低,在未来的集成光路中具有潜在的应用价值.     

冰区海洋平台的时变疲劳可靠性分析

冰区海洋平台在交变冰力作用下的管节点疲劳是影响平台安全的主要因素。本文结合现有的冰疲劳环境荷载及冰力谱函数,提出了相对于冰速、冰厚随机冰载的管节点应力幅显式近似计算公式;将海洋平台管节点的全寿命划分为裂纹萌生和扩展两个阶段,分别采用S-N曲线法和Paris公式来计算相应的寿命;并考虑了管节点抗力随时间的衰减,得到了时变疲劳可靠性计算公式;最后对渤海JZ20-2 MSW平台进行时变疲劳可靠性分析。结果表明,本文提出的疲劳应力幅近似计算方法和时变可靠性分析方法是合理有效的。     

Electrochemical Sensing Platform Integrated with Solid-state Reference Electrode Based on Indium Tin Oxide Interdigitated Array Electrodes

We present a new strategy for the fabrication of a fully integrated electrochemical platform. The three-electrode system consists of an indium tin oxide interdigitated array as working electrode, a solid-state reference electrode, and an electrodeposited Pt counter electrode that are placed in microfluidic channel. By controlling the electrodeposition conditions, such as the applied potential and time, the stability and uniformity of the films can be optimized. A solid-state reference electrode was fabricated on the nanoporous Pt via electropolymerization of poly-1,3-phenylenediamine. This system provides a simple method for the fabrication of three-electrode system and opens the possibility for an electroanalytical platform.     

Organocatalytic Upgrading of Biomass Derived Building Blocks

The depletion of finite primary fossil fuels we are facing makes necessary a deep metamorphosis in fundamental parts of the chemical industry. A progressive transition from petro-based starting materials toward renewable biomass-derived sources will have to take place in the synthesis of added-value chemicals, important for our everyday life, such as pharmaceuticals, polymers, agrochemicals etc. Moreover, greener processes, carried out under friendlier reaction conditions, must be designed to address current concerns about the climate change and the resulting pressing need to reduce the environmental footprint of chemical processes. To this end, organocatalysis could offer a valuable opportunity for upgrading biomass-derived platform molecules in line with the principles of Green Chemistry. This review presents some of recent and remarkable advancements in this emerging area. Organocatalysis has proven to be an efficient tool to transform low value bio-based renewable platform building blocks into new high value bio-based chemicals, with potential applications as synthetic intermediates, innovative materials and pharmaceutically active compounds.