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91.
For the periodicity-modulation of the Si(h h k) template between (0 0 1) and (1 1 1), it is necessary to prepare the surface with any orientation within this range, most especially for fabricating useful one-dimensional nanostructures. Especially, when there are no strong X-ray signals using the standard Cu K-α source in the vicinity of any arbitrarily chosen (H H K), it turns out that the line-profile analysis on the topographic image of scanning tunneling microscopy can be a unique way for confirming the orientation of the prepared surface. Though there are a number of small-width facets on the reconstructed surface, if any of well-defined facets, such as (1 1 1), (3 3 7), (1 1 2), and (3 3 5), are included in these facets it is possible to determine the orientation using the weighted-average method. 相似文献
92.
《Angewandte Chemie (International ed. in English)》2017,56(42):13099-13102
Multidimensional tunneling calculations are carried out for 13 reactions, to test the scope of heavy‐atom tunneling in organic chemistry, and to check the accuracy of one‐dimensional tunneling models. The reactions include pericyclic, cycloaromatization, radical cyclization and ring opening, and SN2. When compared at the temperatures that give the same effective rate constant of 3×10−5 s−1, tunneling accounts for 25–95 % of the rate in 8 of the 13 reactions. Values of transmission coefficients predicted by Bell's formula, κBell , agree well with multidimensional tunneling (canonical variational transition state theory with small curvature tunneling), κSCT. Mean unsigned deviations of κBell vs. κSCT are 0.08, 0.04, 0.02 at 250, 300 and 400 K. This suggests that κBell is a useful first choice for predicting transmission coefficients in heavy‐atom tunnelling. 相似文献
93.
We combined scanning tunneling microscopy and density functional theory to establish the structure-functionality relationship for nanometer-sized defects on TiO2(1 1 0). Three-angstrom high topographically distinct dots are ascribed to stoichiometric TiO2 nanoclusters with low coordination numbers. The under-coordinated O atoms of the nanocluster, with surface O atoms, provide exceptionally strong binding sites for Au nanoparticles. Our atomistic model elucidates a number of characteristics salient to low temperature CO oxidation by Au nanoparticles. 相似文献
94.
Hawking radiation is studied for arbitrary scalars, fermions and spin-1 bosons, using a tunneling approach, to every order in ? but ignoring back-reaction effects. It is shown that the additional quantum terms yield no new contribution to the Hawking temperature. Indeed, it is found that the limit of small ? in the standard quantum WKB approximation is replaced by the near-horizon limit in the gravitational WKB approach. 相似文献
95.
96.
Back Cover: Room‐Temperature Synthesis of Covalent Organic Frameworks with a Boronic Ester Linkage at the Liquid/Solid Interface (Chem. Eur. J. 51/2016)
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97.
Guo-Ping Guo Xiao-Jie Hao Tao Tu Zhi-Cheng Zhu Guang-Can Guo 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(2):141-146
We propose a scheme to eliminate the effect of non-nearest-neighbor
qubits in preparing cluster state with double-dot molecules. As the
interaction Hamiltonians between qubits are Ising-model and mutually
commute, we can get positive and negative effective interactions
between qubits to cancel the effect of non-nearest-neighbor qubits
by properly changing the electron charge states of each quantum dot
molecule. The total time for the present multi-step cluster state
preparation scheme is only doubled for one-dimensional qubit chain
and tripled for two-dimensional qubit array comparing with the time
of previous protocol leaving out the non-nearest-neighbor
interactions. 相似文献
98.
99.
We have studied the tunneling conductance in ferromagnet/insulator/p-wave superconductor junctions, taking into account the
rough interface scattering effect. We find that there exist zero-bias conductance peaks and single-minimum structure in tunneling
spectroscopy. As the exchange energy increases, the Andreev reflection is always suppressed and the differential conductance
decreases. The differential conductance depends on the barrier strength and the roughness at the interface.
Supported by the Natural Science Foundation of Jiangsu Higher Education Institutions, China (Grant No. 06KJB140009) 相似文献
100.
Goumri-Said S. Salomon L. Dufour J. P. De Fornel F. 《Optical and Quantum Electronics》2004,36(9):787-806
Numerical simulation of a two-dimensional probe–object system for photon scanning tunneling microscope is presented. The R-matrix propagation algorithm incorporated into the Fourier modal method was used to achieve an extended capability for modeling of a realistic system consisting of both a probe and a sample. The type of the mode guided through the dielectric probe and the coupling of the near-field to fundamental guiding mode in the probe are discussed. The influence of the probe parameters on the near-field images is investigated. Three different probe shapes were simulated in the constant height scanning mode. The transmitted flux intensity through the probe was found to be strongly dependent on the tip shape. The analysis shows a good agreement of the obtained results with the available theoretical works and confirming experimental results. The proposed numerical scheme can find applications for near-field probe characterization and provides an understanding of the degree of perturbation introduced by a probe tip in the experiment. 相似文献