新型傅里叶变换光谱仪反射镜倾斜容限分析及实验

采用微机电系统微镜阵列和倾斜反射镜替代传统傅里叶变换光谱仪的动镜系统,提出一种基于微机电系统微镜阵列的新型傅里叶变换光谱仪.介绍了该光谱仪的工作原理,分析了倾斜反射镜倾斜角度的容限范围,并搭建了实验系统,进行了实验验证.理论推导表明:在近红外区域,反射镜倾角理论最大值为0.52°,光谱分辨率达到8 nm;在可见光区域,反射镜倾角理论最大值0.183°,光谱分辨率达到3 nm.选取可见光源488 nm激光器进行的实验验证结果表明:在倾角容限范围之内,光谱能准确还原;反之,光谱严重失真.最终,采用复色光源进一步实验验证了理论分析的正确性.     

一系列酞菁红外谱图的性质

因为酞菁在信息、医疗、化工等众多领域有很广泛的应用,所以近百年来一直是科学家研究的热点课题.本文首次对一系列氮杂金属酞菁谱图性质研究,这些酞菁是氮杂酞菁铜、氮杂酞菁锌、氮杂酞菁钴、氮杂酞菁镍和氮杂酞菁汞,这5种氮杂金属酞菁的红外光谱图性质进行研究与比较.这些原因主要和中心配位为金属原子不同引起的.     

头孢噻肟钠与牛血清蛋白相互作用的光谱特征

用光谱法研究头孢噻肟钠（CS）和牛血清蛋白（BSA）在模拟生命体生理条件下相互作用的特征.结果表明CS主要以静态猝灭方式使BSA的荧光强度显著降低;利用同步荧光法研究了CS和BSA作用后牛血清蛋白的构象发生了变化;求得不同温度下二者的结合常数和结合位点数,探讨了微量金属离子对实验体系结合常数的影响,并根据热力学参数确定了CS和BSA之间主要依靠静电力结合.根据Froester非辐射能量转移机理,测定了CS与BSA相互结合时的作用距离2.56nm,表明BSA与CS之间发生了非辐射能量转移.     

芬布芬-铜（Ⅱ）-牛血清白蛋白相互作用的光谱法研究

模拟生理条件下,应用荧光光谱法研究了芬布芬对牛血清白蛋白,铜（Ⅱ）对牛血清白蛋白以及铜（Ⅱ）对芬布芬和牛血清白蛋白荧光光谱特性的影响.实验表明：铜（Ⅱ）和芬布芬均可使牛血清白蛋白的荧光强度发生静态猝灭,并且在铜（Ⅱ）存在下,芬布芬对牛血清白蛋白的荧光猝灭作用显著增强.根据荧光猝灭双倒数图计算芬布芬和牛血清白蛋白的结合常数为8.44×104,结合位点数为0.97.荧光猝灭双倒数图计算的结果表明,芬布芬和牛血清白蛋白之间的结合常数和结合位点数均随铜（Ⅱ）浓度的增大而增大.很据三者结合反应的研究,进一步探讨了芬布芬、铜（Ⅱ）在生物体内与蛋白质相互作用的机理.     

Slowing down approximations to the boltzmann equation: I. Applications to energy deposition and ion implantation

An approximale method for solving the Boltzmann equation for fast particles slowing down in homogeneous media is described. The Boltzmann equation is used in its straight ahead form and the method of Goertzel and Greuling, developed for neutron transport calculations, is extended to cover the problem of ion slowing down and energy deposition. Solutions are obtained in a simple analytical form and compared with exact calculations. We observe that the error passes through a maximum as the index of anisotropy, m, goes from zero to unity. The limitations of simple áge theory are discussed and it is shown how these solutions become exact in the Coulomb limit. The additional problem of electronic stopping is included and its effect on the solution is assessed. Numerical examples are given to support the general conclusions; namely that the Goertzel-Greuling method provides a convenient way to obtain useful estimates of ion implantation profiles and energy deposition.     

Pointfree Aspects of the Td Axiom of Classical Topology

Abstract

Abstraction from the condition defining To-spaces leads to the following notion in an arbitrary frame L: a filter F in L is called slicing if it is prime and there exist a, b e L such that a £ F, b e F, and a is covered by 6. This paper deals with various aspects of these slicing filters. As a first step, we present several results about the original td condition. Next, concerning slicing filters, we show they are completely prime and characterize them in various ways. In addition, we prove for the frames £>X of open subsets of a space X that every slicing filter is an open neighbourhood filter U(x) and X is td iff every U(x) is slicing. Further, for Top_D and Prm_D the categories of td spaces and their continuous maps, and all frames and those homomorphisms whose associated spectral maps preserve the completely prime elements, respectively, we show that the usual contravariant functors between Top and Frm induce analogous functors here, providing a dual equivalence between Top_D and the subcategory of Prm_D given by the To-spatial frames (not coinciding with the spatial ones). In addition, we show that Top_D is mono-coreflective in a suitable subcategory of Top. Finally, we provide a comparison between Jo-separation and sobriety showing they may be viewed, in some sense, as mirror images of each other.     

Optogalvanic Indication of Small Continuous Spectrum Distribution Shift

An optogalvanic method based on the shift of the continuous spectrum frequency distribution is proposed. The accuracy of the shift indication depends on the frequency distribution of the absorbing transitions in the optogalvanic detector spectrum. The absorption in Ne/Cu hollow cathode discharge lamp is analysed in order to investigate the behaviour of the spectrum emitted by a red AC EL panel.