甲烷分子基频谱带谱线强度的计算

此文用代数张量法导出甲烷分子两个基频谱带的转动跃迁矩阵元，对这两个谱带的谱线强度进行了计算和比较，给出满意的结果。     

Cr^4＋：YAG在对撞脉冲锁模的Nd：YAG激光器中实现被动锁模的研究

在理论上提出了Ｃｒ＾４＋：ＹＡＧ作为可饱和吸收体在Ｎｄ：ＹＡＧ激光器中实现被动锁模的可能性，运用速率方程组导出在强激光脉冲作用下Ｃｒ＾４＋：ＹＡＧ激发态吸收的恢复时间和饱和光强。实验上在带有抗共振环结构的接近于介稳腔的脉冲式Ｎｄ：ＹＡＧ激光器中用Ｃｒ＾４＋：ＹＡＧ作为可饱和吸收体实现被动锁模运转，得到能量１３．５ｍＪ、平均脉宽１８０ｐｓ的锁模脉冲序列。     

Laser Raman spectroscopic study of ferroelastic LiCsSO4

Lithium caesium sulphate has been reported to undergo a phase transition from the room temperature orthorhombic phase with space groupP cmn to a final phase with space groupP 2₂/n. Though a sharp anomaly in its physical properties has been found at 202.0;K, it was found that there was a need for careful investigations in the vicinity of 240 and 210.0;K. Since the changes in the crystal structure involve primarily a rotation of the SO₄ tetrahedron about thec-axis and as this may be reflected both in the intensity and polarisation of the internal as well as external phonon modes, the laser Raman spectra of oriented single crystals of LiCsSO₄ at different temperatures were investigated. For correlation and definite identification of the spectral features, its infrared absorption spectrum was also studied. An analysis of the intensities and polarizations of the internal modes of the sulphate ions reveals the change in symmetry of the crystal. The integrated intensity and peak height of thev ₁ line, plotted against temperature show anomalous peaks in the region of the phase transition. Differential scanning calorimetric study gives the enthalpy change ΔH across the phase transition to be 0.213 kJ/mol.     

Calculation of the Band Intensities of the IR Spectra of Oriented Polymers

An attempt has been made to extend the theory of IR spectra of polymers to oriented polymers. Formulas for the absorption-band intensities in polarization IR spectra of oriented polymers reflecting the dependence of the polarized absorption-band intensity on the structural and orientation characteristics of polymers have been obtained. These formulas permit calculating the intensity of polarized absorption bands at different degrees of orientation of the polymer.     

角毛藻光衰减特性及其在光生物反应器培养中的应用

对角毛藻光衰减特性及其在光生物反应器培养中的应用进行了研究和讨论 .结果表明 :(1)角毛藻 (Chaetocerossp .)藻液中的光衰减方程 :I =I0 exp[- (0 .4 0 89·OD4 36 - 0 .1975 )L];(2 )本实验室研制的 10L光生物反应器的平均光强计算公式 :Iavg=2I0 [αr0 + 2exp(-αr0 ) - 1-αr0exp(α - 2r0 ) -exp(- 2αr0 ) ]/ (α2 r20 ) ,α =- (0 .4 0 89·OD4 36 - 0 .1975 )L .结合光生物反应器的结构特点 ,光衰减方程及平均光强的计算公式在光生物反应器中的应用 :(1)生产培养过程中入射光强的确定 ;(2 )半连续培养密度的确定 ;(3)进行反应器几何结构设计的改进 .     

负载型复合半导体MoO3-TiO2/SiO2的结构与吸光性能

采用表面改性法制备了负载型复合半导体材料MoO3TiO2/SiO2,用X射线衍射、比表面测定、透射电子显微镜、红外光谱、拉曼光谱、紫外可见漫反射等技术对固体材料的结构进行了表征,并从固体材料的光响应性能和化学吸附性能方面进行了评价.结果表明,MoO3TiO2/SiO2表面存在着高度分散的MoO3和TiO2微晶,它们之间有一定的复合和键联作用,形成了Mo-O-Ti键;MoO3TiO2/SiO2复合材料表面对丙烷分子有化学吸附性能,Mo=O键上的端氧是C3H8的活性吸附位;与本体MoO3和TiO2相比,复合后MoO3TiO2/SiO2的能隙值有所增加,在紫外光区的吸光强度也明显加强,使得光生载流子的复合效率得到抑制,并产生了一定的量子尺度效应.     

足球分子的电子结构和UV谱的研究

用INDO/2和INDO/CI方法研究了足球分子的电子结构和UV谱。几何构型优化后得到2种键长:R_(5-6)=1.4507,R_(6-6)=1.3979,相应的键序为1.1356和1.4385。SCF计算得到120个成键轨道和120个反键轨道,符合我们建议的结构规则。足球分子的光谱计算结果是振子强度不为零的跃迁只有一个,其值为386.0 nm,和实测的UV谱符合得较好。     

Scattering of elastic waves by a periodic array of cracks in 3-D space

The problem of scattering of normal incident time harmonic plane elastic waves by a co-planar periodic array of cracks in 3-D space is investigated. The scattered waves consist of a superposition of an infinite number of wave modes [M, N]^T and [M, N]^L,M. N=0, 1, 2, , but only a finite number of them are propagating wave modes. The numerical calculation has been made for rectangular cracks and P wave incidence. The reflection coefficient of [O, O] order,R ₀ ³ , has been studied in detail for various wave numbers and parameters of the geometry for the problem. The reliability of the numerical calculation has been checked by an application of the balance of rates of energies. For an elongated rectangular crack,R ₀ ³ in the corresponding 2-D problem in [2] is recovered. The dynamic stress intensity factors around the crack edge have been obtained. The results as the wave number goes to zero have been compared with those in the correspoding static case. Good agreement is observed.     

圆形界面裂纹反平面问题的基本奇异解

本文研究反平面集中力作用下,不同弹性材料的圆形界面上有多条裂纹的问题。运用复变函数的解析延拓技术与奇性主部分析方法,首次获得该问题的一般解答,求出了几种典型情况的封闭解;算出了应力强度因子,并由此导出一系列特殊结果,其中几个与已有文献完全吻合。     

红外光谱等方法在电机易烧毁事故分析中的应用

本文应用红外光谱,气相色谱等方法对１０３２三聚氰胺醇酸绝缘漆的稀释剂“二甲苯”进行了成份分析,结论是该稀释剂根本不是二甲苯,而是以苯,甲苯,卤代烃,二甲苯,和甲醇组成的混合液,找出了电机易烧毁的原因。