分子印迹β-环糊精聚合物选择性识别水中的双酚A

以双酚A为模板分子, β-环糊精为功能单体, 六亚甲基二异氰酸酯为交联剂, 二甲基亚砜为溶剂, 采用沉淀聚合法合成了分子印迹β-环糊精聚合物. 用傅里叶变换红外光谱仪、 扫描电子显微镜对聚合物的结构进行表征. 从选择性、 吸附容量、 结合特性对吸附剂的性能进行了评价. 底物类似物的机会均等与机会不均等竞争吸附实验证明了β-CD-MIPs对底物的结合容量远大于对类似物的结合容量. 用热力学参数对实验数据进行拟合, 发现β-CD-MIPs对BPA的吸附为自发的放热过程, 温度低对吸附有利.     

电容提取的新摄动方程及小波边界元解法

提出一种解决含高电容率介质结构电容提取问题的新摄动方程,使计算时间减少一半.建立新摄动方程的快速小波Galerkin边界元解法.算例证明新摄动方程精度高且受介质电容率影响小;用小波Galerkin边界元求解的效率高,时间和内存消耗达到最优O(N)(N为未知量数目).     

Determination of the Real Surface Area of Palladium Electrode

Four methods, including voltammetric measurement of double layer capacitance, surface oxides reduction, under potential deposition of Cu and carbon monoxide (CO) stripping have been applied to evaluate the real surface area of a polycrystalline Pd (pc-Pd) electrode. The results reveal that the second and third methods lead to consistent results with deviations below 5%. And from the determined double layer capacitance and CO stripping charge, it is deduced that the double layer capacity unit area is 23.1±0.4 μF/cm² and the saturated CO adlayer should be ca. 0.66 ML in order to ensure that the real surface area as determined isconsistent with the other two techniques. The applicability as well as the attentions when applying these techniques for the determination of the real surface area of pc-Pd electrodes have been discussed.     

SEC1酶免疫电极免疫反应的AFM和电化学方法研究

将一种肠毒素抗体共价耦联于自组装的金电极表面 ,利用原子力显微镜识别抗原抗体在多种实验条件下的形貌并通过统计数据进行定量分析 .用作控制实验的是非特异性牛血清白蛋白(BSA)抗原以及低浓度的SEC1抗原 .另外 ,酸性溶液可以打破抗原与抗体之间的结合从而使得生物电极可以被重复使用 .电化学实验支持了AFM的测试结果     

Ion penetration into an ‘unfriendly medium’ and the double layer capacitance of the interface between two immiscible electrolytes

We develop a theory of the double layer at electrolyte | electrolyte interfaces with account for the finite thickness of the interfacial region. This includes the distribution of ions between the two phases and smooth variation of dielectric properties across the interface. The theory offers simple laws for the dependence of the double layer capacitance on the nature of ions, ionic concentrations and potential, which are in line with experimental observations. The theory shows which parameters reflect the nature of ions and the structure of the interface, and how these parameters can be extracted from the capacitance data.     

Heat capacity and magnetic phase transitions of rare-earth orthoferrite HoFeO3

Heat capacity of two rare-earth orthoferrites HoFeO₃ and LuFeO₃ were measured between 1.8 and 200 K. A distinctly large and two small heat capacity anomalies were detected for HoFeO₃ under zero magnetic field around 3.3, 53 and 58 K, respectively. The low-temperature anomaly with a peak at 3.3 K is due to the ordering of Ho³⁺ ions and the estimated magnetic entropy for this transition was favorably compared with the expected (R ln 2). Application of magnetic field significantly affects the positions and the magnitudes of the anomaly at 3.3 K. Energies of low-lying levels of the lowest J-term of Ho³⁺ ion were roughly estimated through analysis of the Schottky heat capacity.     

硅微机械陀螺传感器信号的检测方法

硅微机械陀螺是近几年发展起来的一种新型惯性元件。由于其巨大的军事和民用价值,各国均将研制过程中的关键技术列为高度机密。本文对硅微机械陀螺的关键技术之一 传感器信号的检测方法进行了探讨。提供了几种硅微机械陀螺传感器信号的检测方法,并对这几种检测方法进行了比较。     

An apparatus for the measurement of thermal expansion of solids at low temperatures

A dilatometer, using the three terminal capacitance technique, suitable for measurement of linear thermal expansion of solids in the temperature range 1.3–300 K is described. The dialtometer is designed such that the mounting system for the specimen does not undergo any significant changes in dimensions when the specimen is heated. The apparatus, therefore, yields in principle absolute values of α, the coefficient of linear thermal expansion. The performance of the apparatus has been checked by measurements on copper in the temperature range of 77–300 K. Some preliminary results on the behaviour of α for Y₁Ba₂Cu₃O_6.9 compound in the vicinity of superconducting transition temperature,T _c are also described. The system can detect relative changes in length Δl/l ₀ of about 10⁻⁸. Attempts are being made to improve the sensitivity.     

Solution-processed Nonstoichiometry NiOx Nanocrystal Aggregations for Supercapacitor Electrodes

Nickel oxide (NiOx) has been considered as one of the most promising electrode materials for electrochemical supercapacitors because of its exceptional redox and charge storage characteristic. Here, the nonstoichiometry NiOx nanocrystals were synthesized by a room-temperature chemical precipitation method with the following annealing process. The stoichiometric ratio and morphology of the NiOx nanocrystals were controlled by annealing Ni(OH)₂ nanoparticles under different temperatures. At 270 ^○C annealing process, the NiOx nanocrystals get together to aggregations, which not only have large specific surface area, but also have relatively long charge transfer channels. Meanwhile, with increasing temperature beyond 270 ^○C, Ni²⁺ active sites in the nonstoichiometry NiOx decrease. Furtherly, the NiOx nanocrystal aggregations show the superior electrochemical performance with a specific capacitance of 332 F · g^–1 at a current density of 1 A · g^–1. In addition, the stability of Coulombic efficiency can still retain 91.3 % after 500 cycle.     

Experimental assessment of interactions between liquid crystal 4-cyano-4’-hexylbiphenyl and magnetoferritin

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