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991.
W. Wojnowski J. Pikies K. Peters E.-M. Peters D. Thiery H. G. Von Schnering 《无机化学与普通化学杂志》1994,620(2):377-384
Formation and Structures of N-(tri-t-butoxysilyl)aniline Compounds Para-substituted N-(tri-t-butoxysilyl)anilines (t-BuO)3SiNRC4H4X-p, R = H, CH3, with substituents of high electron affinity (X = CN, NO2) were prepared by a one-pot reaction of tri-t-butoxychlorsilane, potassium t-butanolate and substituted anilines. Corresponding compounds with substituents of low electron affinity (X = OMe, H) preferably were prepared by metalation of anilines with sodium amide. Four crystal structures were determined. N-(tri-t-butoxysilyl)-p-nitro-aniline, N-methyl-(N-tri-t-butoxysilyl)-p-nitroaniline and N-(tri-t-butoxysilyl)-p-cyanoaniline crystallize at 298 K monoclinically, N-(tri-t-butoxysilyl)aniline crystallizes orthorhombically. 相似文献
992.
Thiocarbonylchloride reacts with -nitroalcohols yielding symmetrical thionocarbonates. Transesterification of bis(2-fluoro-2,2-dinitroethyl)thioncarbonate affords alkyl 2-fluoro-2,2-dinitroethylthionocarbonates. Fluorination of these thionocarbonates yields the corresponding difluoroformals.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 375–376, February, 1993. 相似文献
993.
G. Stringari Ivo Pancheri Frank Möller Osvaldo Failla 《Accreditation and quality assurance》1998,3(3):122-126
Chemical analyses of trace elements are affected by relatively high analytical errors due to the different steps of the laboratory
procedures: samples grinding, mineralisation and instrumental measurements. In the present communication, the influence of
the grinding phase on the global uncertainty of Pb, Cd, Ni and Cr determinations in plant samples by the classical method
of atomic absorption spectrometry/electrothermal atomisation (AAS-ETA) after dry ashing is quantified. Two grinding machines,
a planetary mill with balls and jars of agate versus a stainless steel grinder were compared by analysing leaf samples of
cucumber, strawberry, kiwivines, apple trees and grapevines from agricultural experimental plots under controlled conditions.
Variance components due to the difference between grinding methods and experimental plots were estimated. Further, the simultaneous
effects of the grinding methods on all considered metals have been evaluated by analysis of variance. With the stainless steel
grinder, on average, higher levels of the considered heavy metals were obtained (up to 67% of the mean values). On average,
the increments were similar for metals contained in steel (Ni and Cr) and those not contained (Pb and Cd). The true causes
of these differences need further investigation to determine whether the higher metal detection is due to possible contamination,
to a different grinding quality or to other reasons. Finally, the grinding methods did not seem to affect the combined uncertainty
of the analyses.
Received: 3 November 1997 · Accepted: 29 November 1997 相似文献
994.
Conversion ofn-hexane has been applied as a test reaction to study differences between the series of Pt−Sn/γ-Al2O3 catalysts obtainedvia different methods of preparation. Preliminary results of catalytic experiments have been compared with some changes occurring
on the catalysts surfaces as the results of the preparation technique applied. It has been found that catalysts with the second
metal (Sn) introduced to the support by the coprecipitation technique were much more stable in comparison to the catalysts
where the tin component has been added by the impregnation method, however, we have not observed large differences in catalytic
activity. 相似文献
995.
The oxime of the hitherto unknown 3-amino-5-nitrobenzaldehyde was synthesized by the reaction of 3-amino-5-nitrobenzaldehyde
phenylhydrazone with excess of (NH2OH)2·H2SO4. The oxime obtained was used as the starting compound for the synthesis of novel diaryl- and arylnitrofuroxans.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2232–2235, December, 1997. 相似文献
996.
G. Glöckner 《Chromatographia》1987,23(7):517-524
Summary Prerequisite of quantitative evaluation in chromatography is equivalence of sample composition and detector signal. This includes
complete retention and proper elution of all sample constituents. In polymer HPLC, complete retention requires a poor starting
eluent, a sufficiently active column, and a low ratio of injection volume to column volume. On small pore columns, insufficient
retention caused the polymer to elute either in the interstitial volume (sample exclusion), together with the sample solvent,
or immediately after the solvent plug.Stat-copoly(styrene/ethyl methacrylate) samples are more difficultly retained thanstat-copoly(styrene/acrylonitrile) specimes. With the former copolymer it could be shown that incomplete retention did not cause
sample demixing. In order to gain complete retention, non-exclusion HPLC of polymers should be performed with columns whose
solvent volume is at least 50 times as large as the injection volume. This consequence is of practical importance in chromatographic
cross-fractionation where rather large volumes of SEC eluate are injected into the apparatus for gradient HPLC. 相似文献
997.
乳液体系中的RAFT可控/活性自由基聚合研究进展 总被引:2,自引:1,他引:2
可逆加成-断裂链转移聚合(RAFT)是新近发展起来的可控/活性自由基聚合方法。由于该方法具有适用单体范围广、反应条件温和、可采用多种聚合实施方法等优点,已成为一种有效的分子设计手段。本文总结了近几年文献报道的在乳液和细乳液体系中实施RAFT聚合反应的研究进展,对非均相体系的稳定性、聚合反应过程中的动力学特点、以及聚合产物的分子量及其分布等方面的研究进行了综述。 相似文献
998.
Kai Yang Xuan Zhang Enqin Fu Jingui Qin Minoru Kinoshita 《Journal of solid state chemistry》2004,177(11):4300-4304
Two new intercalation compounds were prepared by the reactions of Ni(II) cyclopolyamine complex cations with a preintercalate Mn1−xPS3K2x(H2O)y, respectively, through “ion exchange” process. Their structures were characterized by elemental analysis, X-ray powder diffraction and infrared spectroscopy. The lattice spacing increased 0.567 and 1.093 nm with respect to the pristine MnPS3. Ferrimagnetism of the intercalates was confirmed by SQUID experiment with Tc at 40 and 33 K, respectively. 相似文献
999.
《Tetrahedron letters》2004,45(11):2377-2380
The β-substituted captodative olefins methyl 2-aryloxy-3-dimethylaminopropenoates 4a-h were synthesized, via aminomethylenation of the corresponding 2-phenoxyacetic esters 9a-h. Lewis acid promoted intramolecular cyclization of alkenes 4 led to benzofurans 7a-h, in an efficient synthetic approach to the benzofuran frame. 相似文献
1000.
Ilaria AdamoFabio Benedetti Federico BertiGiorgio Nardin Stefano Norbedo 《Tetrahedron letters》2003,44(51):9095-9097
4-Acyl-1H-1,2,3-triazoles are formed from diethylaluminum azide and α′-(N,N-dibenzylamino)-α,β-unsaturated ketones by [3+2] cycloaddition of azide, followed by 1,5 hydride transfer to the β carbon of the triazoline side chain and fragmentation of the tertiary amino group promoted by coordination of the latter to the Lewis acid. The structure of a triazole product is confirmed by X-ray crystallography. 相似文献