机械力化学改性硅酸盐矿物的FTIR研究

利用气流磨所产生的超音速气流作为机械力，分别对层状硅酸盐矿物滑石、绢云母、高岭土和链状硅酸盐矿折硅灰石与硬脂酸进行超细粉碎－表面改性，应用FTIR法进行研究。     

Fluorine sites in glasses and transparent glass-ceramics of the system Na2O/K2O/Al2O3/SiO2/BaF2

The transparent glass-ceramics obtained in the silicate system Na₂O/K₂O/SiO₂/BaF₂ show homogeneously dispersed BaF₂ nano crystals with a narrow size distribution. The X-ray diffraction and the nuclear magnetic resonance spectroscopy were applied to glasses and the respective glass-ceramics in order to clarify the crystallization mechanism and the role of fluorine during crystallization. With an increasing annealing time, the concentration and also the number of crystals remain approximately constant. With an increasing annealing temperature, the crystalline fraction increases until a saturation limit is reached, while the number of crystals decreases and the size of the crystals increases. Fluoride in the glassy network occurs as Al-F-Ba, Al-F-Na and also as Ba-F structures. The latter are transformed into crystalline BaF₂ and fluoride is removed from the Al-F-Ba/Na bonds. However, some fluorine is still present in the glassy phase after the crystallization.     

电子探针自动连续分析硅酸盐中存在问题的研究

目前,电子探针已成为分析硅酸盐样品的一种重要仪器,新型仪器都可以自动连续分析,大大提高了工作效率,可是定量分析的准确度往往不太高,尤其SiO_2经常偏低。我们以剖析SiO_2分析存在问题出发,讨论了造成误差较大的原因并提出克服的方法     

Influence of postdeposition annealing on structural properties and electrical characteristics of thin Tm2O3 and Tm2Ti2O7 dielectrics

We describe the structural properties and electrical characteristics of thin thulium oxide (Tm₂O₃) and thulium titanium oxide (Tm₂Ti₂O₇) as gate dielectrics deposited on silicon substrates through reactive sputtering. The structural and morphological features of these films were explored by X-ray diffraction, X-ray photoelectron spectroscopy, secondary ion mass spectrometry, and atomic force microscopy, measurements. It is found that the Tm₂Ti₂O₇ film annealed at 800 °C exhibited a thinner capacitance equivalent thickness of 19.8 Å, a lower interface trap density of 8.37 × 10¹¹ eV⁻¹ cm⁻², and a smaller hysteresis voltage of ∼4 mV than the other conditions. We attribute this behavior to the Ti incorporated into the Tm₂O₃ film improving the interfacial layer and the surface roughness. This film also shows negligible degrees of charge trapping at high electric field stress.     

Optical Properties of Gamma Irradiated Soda-Lime Silicate Glasses Exchanged with Copper

The effect of copper ion exchange upon the optical absorption and room temperature gamma colouration of soda lime silicate glasses has been investigated. After ion exchange performed at 720 K, copper ions substitute mainly the alkali ions and do modify the optical absorption spectra of the specimens. It has been shown that gamma irradiation does not induce the formation of colloidal copper. Moreover, the colouration process itself is independent of the presence of copper ions. The generated colour centres are rather related to the presence of sodium and potassium ions. The optical bleaching by the UV light occurs in two stages. First disappear centres related to the Na-type defects and next those related to the K-type defects.     

Preparation and optical properties of soda-lime silicate glasses partially substituted by copper

The ion-exchange process was used to introduce copper ions into soda lime silicate glasses (SLS), the composition of which corresponds to the miscibility gape in the Na 2 O-SiO 2 system. The samples have been immersed either in a molten Cu 2 Cl 2 or CuCl 2 at various temperatures from the range 720-940 v K for different time. The observed green colour of glass is related with the 790-nm absorption band related to the cupric ions. The annealing either in air or in the hydrogen atmosphere was used for the reduction of copper. The effectiveness of these procedures was analysed on a basis of the penetration profiles monitored by roentgenographic methods (diffraction and EDAX). Transmission electron microscopy (TEM) observations of the replicated surface and common optical absorption measurements have been used to study the morphology of the dopant ions.     

Microwave enhanced alkaline digestion of silicate samples for determination of Fe2O3

A novel approach to the study of microwave enhanced alkaline digestion was developed for rapid digestion of silicate samples. By using alkali metal hydroxide solution as microwave digestion solvent, the feasibility and principle of digestion were discussed for the determination of Fe₂O₃ contents in quartz, kaolin, feldspar and soda-lime-silica glass. The results obtained from four standard samples and six real world samples are in good agreement with the certified values, and are comparable to the predicted results from traditional alkaline digestion method. All the above demonstrates that this new proposed method is precise, accurate and can provide a simple, fast and energy saving procedure for the determination of components in silicate samples.     

In-Situ Constructing A Heterogeneous Layer on Lithium Metal Anodes for Dendrite-Free Lithium Deposition and High Li-ion Flux

Constructing efficient artificial solid electrolyte interface (SEI) film is extremely vital for the practical application of lithium metal batteries. Herein, a dense artificial SEI film, in which lithiophilic Zn/Li_xZn_y are uniformly but nonconsecutively dispersed in the consecutive Li⁺-conductors of Li_xSiO_y, Li₂O and LiOH, is constructed via the in situ reaction of layered zinc silicate nanosheets and Li. The consecutive Li⁺-conductors can promote the desolvation process of solvated-Li⁺ and regulate the transfer of lithium ions. The nonconsecutive lithiophilic metals are polarized by the internal electric field to boost the transfer of lithium ions, and lower the nucleation barrier. Therefore, a low polarization of ≈50 mV for 750 h at 2.0 mA cm⁻² in symmetric cells, and a high capacity retention of 99.2 % in full cells with a high lithium iron phosphate areal loading of ≈13 mg cm⁻² are achieved. This work offers new sights to develop advanced alkali metal anodes for efficient energy storage.