全文获取类型
收费全文 | 3275篇 |
免费 | 83篇 |
国内免费 | 488篇 |
专业分类
化学 | 2023篇 |
晶体学 | 38篇 |
力学 | 35篇 |
综合类 | 4篇 |
数学 | 1352篇 |
物理学 | 394篇 |
出版年
2023年 | 11篇 |
2022年 | 25篇 |
2021年 | 19篇 |
2020年 | 31篇 |
2019年 | 61篇 |
2018年 | 69篇 |
2017年 | 41篇 |
2016年 | 65篇 |
2015年 | 64篇 |
2014年 | 99篇 |
2013年 | 215篇 |
2012年 | 116篇 |
2011年 | 206篇 |
2010年 | 201篇 |
2009年 | 281篇 |
2008年 | 295篇 |
2007年 | 270篇 |
2006年 | 218篇 |
2005年 | 165篇 |
2004年 | 151篇 |
2003年 | 92篇 |
2002年 | 105篇 |
2001年 | 104篇 |
2000年 | 112篇 |
1999年 | 127篇 |
1998年 | 97篇 |
1997年 | 76篇 |
1996年 | 52篇 |
1995年 | 51篇 |
1994年 | 45篇 |
1993年 | 29篇 |
1992年 | 45篇 |
1991年 | 34篇 |
1990年 | 27篇 |
1989年 | 31篇 |
1988年 | 26篇 |
1987年 | 17篇 |
1986年 | 16篇 |
1985年 | 16篇 |
1984年 | 21篇 |
1983年 | 9篇 |
1982年 | 22篇 |
1981年 | 12篇 |
1980年 | 15篇 |
1979年 | 20篇 |
1978年 | 21篇 |
1977年 | 11篇 |
1976年 | 6篇 |
1975年 | 2篇 |
1973年 | 1篇 |
排序方式: 共有3846条查询结果,搜索用时 15 毫秒
31.
In this paper the distribution of the zeros of the error function for bestL
1-approximation by rational functions fromR
n,m
is considered. It is shown that the maximal distance between such zeros isO(1/(n–m)), ifn > m.Communicated by Edward B. Saff. 相似文献
32.
LetW
(x) be a function nonnegative inR, positive on a set of positive measure, and such that all power moments ofW
2(x) are finite. Let {p
n
(W
2;x)}
0
denote the sequence of orthonormal polynomials with respect to the weightW
2(x), and let {A
n
}
1
and {B
n
}
1
denote the coefficients in the recurrence relation
相似文献
33.
晶化温度对中孔分子筛(M41S)结构转变的影响 总被引:11,自引:6,他引:11
在低表面活性剂浓度及低表面活性剂与氧化硅比的条件下,研究了十六烷基三甲基溴化铵-硅酸钠体系中晶化温度对中孔分子筛M41S材料结构转变的影响。结果有,晶化温度提高至135℃改变了原六方晶相MCM-41的结构,晶化温度提高到150℃后,中孔结构六方MCM-41晶格转变为变不稳定的层状相, 相似文献
34.
J. Goworek W. Stefaniak Agnieszka Kierys Mariola Iwan 《Journal of Thermal Analysis and Calorimetry》2007,87(1):217-222
Mesoporous silica material of MCM-41 type was synthesized by co-condensation
of highly concentrated octyltriethoxysilane (OTEOS), octadecyltriethoxysilane
(ODTEOS) and tetraethoxysilane (TEOS). The obtained hybrid materials were
characterized using XRD, TG-DSC and low temperature adsorption/desorption
of nitrogen. It was shown that the applied method of synthesis allows to obtain
silica of MCM-41 type with a high degree of hydrocarbon saturation. 相似文献
35.
对国产GYQG球形硅胶施加高压水热处理并进行扩孔,制备了用于高效液相色谱法的大孔硅胶填料,考察了扩孔压力,扩孔温度和扩孔时间对平均孔径和比表面积的影响。并将产品日本SIL-3003×10^-8m硅胶进行了物理性质和孔分布的对比实验,结果表明GYQG硅胶扩孔后平均孔径为20~30nm接近日本SIL-3003×10^-8m硅前平平均孔径25nm。display structure 相似文献
36.
本文采用表面活性剂十六烷基三甲基溴化铵(C16TABr,以下为1631),在(Na,K)OHSiO2C16TABrH2O体系中分别利用室温、水热及干粉法进行了纯硅MCM41中孔分子筛的合成,考察了阳离子Na+、K+对MCM41合成及稳定性的影响。通过XRD对结晶度的测定,发现NaMCM41的晶化速率明显高于KMCM41,而热稳定性和水热稳定性较差,且a0值小于后者。同时发现,就合成方法而言,室温法得到的产物具有很高的结晶度,利用水热法合成的样品的热稳定性明显较高,而干法得到的分子筛产品具有优良的水热稳定性。 相似文献
37.
中孔MCM—41分子筛在微孔沸石ZSM—5上附晶生长的研究 总被引:15,自引:2,他引:15
首次在微孔沸石ZSM5表面进行了MCM41分子筛的附晶生长,并首次提出中孔材料MCM41分子筛静电组配理论的新形式(XS+I);同时利用XRD、TEM、BET等测试手段表征了合成样品,并讨论了微孔沸石表面附晶生长中孔分子筛MCM41的合成化学,考察了F离子效应、pH值及表面活性剂CTAB(十六烷基三甲基溴化铵)的影响。 相似文献
38.
Bobonich F. M. Yaroshenko N. A. Solomakha V. N. Strelko V. V. Il'in V. G. 《Theoretical and Experimental Chemistry》2004,40(4):254-259
Under the conditions studied for the synthesis of mesophase materials with alkylpyridinium halides an increase in the density of packing of these molecules in the encapsulated micelles was observed with an increase in the length of the alkyl radicals. The difference in the density of packing of these surface active reagents (SAR) depended to a considerable extent on the perfection of the hexagonal structure and the characteristic absorption properties of the mesophase materials of MCM-41 type. 相似文献
39.
The phase analysis of cryolite (Na3AlF6) and sodium metasilicate (Na2SiO3) was performed by thermal analysis. The eutectic system with a region of two immiscible substances at a concentration of Na2SiO3 between 42.8 and 46.3 mol‐% was identified and the eutectic temperature determined to (886±2) °C. Based on the results of mass‐loss measurements, it was assumed that the introduced Na2SiO3 reacts with Na3AlF6 due to the formation of some nonvolatile stable compounds. The stable reaction products were identified by X‐ray diffraction analysis and IR spectroscopy of the spontaneously cooled samples, which established the formation of NaF and stable amorphous aluminosilicate compounds. 相似文献
40.
Mesoporous material as catalyst for the production of fine chemical: Synthesis of dimethyl phthalate assisted by hydrophobic nature MCM-41 总被引:1,自引:0,他引:1
Seshachalam Udayakumar Arumugam Pandurangan Predeep Kumar Sinha 《Journal of molecular catalysis. A, Chemical》2005,240(1-2):139-154
Aluminum, iron and zinc containing MCM-41 molecular sieves were prepared by the hydrothermal method. The catalyst was characterized by the XRD, BET (surface area), FT–IR and 29Si, 27Al MAS–NMR techniques. The catalytic activity of these molecular sieves was tested with esterification reaction used with phthalic anhydride (PAH) and methanol (MeOH) in the autoclave at 135 °C, 150 °C and 175 °C. Conversion increases with an increase in temperature and mole ratio. The activity of these catalysts followed the order: Al-MCM-41 (112) > Fe-MCM-41 (115) > Al-MCM-41 (70) > Al-MCM-41 (52) > Fe-MCM-41 (61) > Al, Zn-MCM-41 (104) > Al-MCM-41 (30). The reaction yielded both monomethyl phthalate (MMP) and dimethyl phthalate (DMP). The nature of the catalyst sites has been proposed using with water as an impurity. The selectivity of the dimethyl phthalate increases with increase in temperature and mole ratio. The weight of the catalyst was optimized at 0.07 g. The hydrophilic and hydrophobic nature of the catalyst has been explained by the influence of water and the external surface acidity also facilitates the reaction and this has been confirmed by the supporting reaction. 相似文献
|