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181.
Patrick Cancouët Elodie Daudet Grard Hlary Michel Moreau Georges Sauvet 《Journal of polymer science. Part A, Polymer chemistry》2000,38(5):826-836
Poly(hydrogenmethylsiloxane‐co‐dimethylsiloxane)s of various compositions have been prepared by cationic ring‐opening polymerization of octamethylcyclotetrasiloxane (D4) and 1,3,5,7‐tetramethylcyclotetrasiloxane (D) in the presence of hexamethyldisiloxane as end‐blocker or by rearrangement of poly(hydrogenmethylsiloxane) in the presence of D4. These copolymers were examined by high resolution 1H NMR (500.13 MHz) and 29Si NMR (99.37 MHz) spectroscopies. Triad effects were observed by 1H and up to heptad effects by 29Si NMR. The chemical shifts were assigned for these stereosequences. The intensities of the triad signals were used to calculate the quantitative parameters describing the microstructure of the copolymer chains: number‐average block length (L̄) and persistence ratio (η). The values of these parameters for copolymers prepared in various experimental conditions show that the time necessary for redistribution reactions (backbiting) is much larger than the time required to establish the equilibrium between linear polymer and cyclic oligomers. However, redistribution is fast enough to prevent the formation of block copolymers even in the case of the rearrangement of poly(hydrogenmethylsiloxane) in the presence of D4. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 826–836, 2000 相似文献
182.
183.
为了进一步提高小尺寸金属氧化物半导体(MOSFET)的性能,在应变硅器件的基础上, 提出了一种新型的异质栅MOSFET器件结构.通过求解二维Poisson方程,结合应变硅技术的物理原理,建立了表面势、表面电场以及阈值电压的物理模型,研究了栅金属长度、功函数以及双轴应变对其的影响. 通过仿真软件ISE TCAD进行模拟仿真,模型计算与数值模拟的结果基本符合. 研究表明:与传统器件相比,本文提出的异质栅应变硅新器件结构的载流子输运效率进一步提高, 可以很好地抑制小尺寸器件的短沟道效应、漏极感应势垒降低效应和热载流子效应, 使器件性能得到了很大的提升.
关键词:
应变硅
异质栅
阈值电压
解析模型 相似文献
184.
分子筛膜的合成和应用是近年来的研究热点, 特别是具有独特孔道结构的MFI 型分子筛膜. 但由于膜内有机模板剂在高温脱除时会导致膜产生缺陷, 进而影响分子筛膜的应用. 所以分子筛膜及分子筛晶体中有机模板剂的低温脱除工艺一直是研究者们致力解决的问题之一. 本文系统考察了高硅ZSM-5分子筛晶体内有机模板剂(四丙基氢氧化铵, TPAOH)在H2/N2气氛下的低温裂解脱除规律, 采用低温加氢裂解工艺, 在350 ℃以下可有效脱除分子筛晶体孔道内的有机模板剂. 通过对裂解后分子筛晶体的比表面积(BET)、热失重(TG)、傅里叶变换红外(FTIR)光谱和拉曼光谱表征证实, 相比于空气和氮气气氛, 含氢还原性气氛更有利于模板剂的低温脱除, 脱除率随温度的升高而增加; 280 ℃时, 加氢裂解后晶体的BET比表面积已达到252 m2·g-1, 仍有少量有机残余物; 350 ℃时, 加氢裂解后晶体的BET比表面积可达到399 m2·g-1, 仅有微量无机碳残余物. 此外, 低温加氢裂解后的分子筛表面相对洁净, 且氨气程序升温脱附(NH3-TPD)结果表明低温加氢裂解后的ZSM-5 分子筛晶体具有相对较多的酸性位. 相似文献
185.
通过经济有效的方法制备得到一种具有长循环寿命的高效稳定性硅/硅氧碳/无定形碳的复合负极材料结构. 在这种结构中,以具有稳定化学性能的硅氧碳结构作为骨架,来支撑和隔离硅纳米颗粒结构. 材料中包含的无定形碳组分可提高硅/硅氧碳结构的电导性能. 这种复合负极结构在0.3C电流充放电情况下,不仅能发挥出637.3 mAh·g-1的比容量,而且在经过100 周的充放电循环后,其容量保持率也达到86%. 这种新型硅基负极材料的设计为其他功能材料的设计提供了一种潜在可能的方法. 相似文献
186.
Zhong Ren Li Xiao Gongwei Wang Juntao Lu Lin Zhuang 《天然气化学杂志》2014,(3):265-268
Although most transition metals have been tested as the promoter to Pt for electrocatalysis toward fuel cell reactions,semi-conductor elements,such as Si,have hitherto not been examined.Here we report a simple synthesis of intermetallic Pt2Si electrode using magnetron sputtering and the electrocatalysis toward ethanol oxidation reaction(EOR).In comparison to Pt,the intermetallic Pt2Si surface turns out to be much more active in catalyzing the EOR:the onset potential shifts negatively by 150 mV,and the current density at 0.6 V increases by a magnitude of one order.Such an enormous enhancement in EOR catalysis is ascribed to the promotion effects of Si,which can not only provide active surface oxygenated species to accelerate the removal of COads,but also strongly alter the electronic property of Pt,as clearly indicated by the core-level shift in XPS spectrum. 相似文献
187.
188.
Highly hydrolytic and thermally stable sandwich-type polyoxometallates of [(A-β-SiW9O34)2(MOH2)3CO3]13− (M = Y3+ and Yb3+) have been synthesized at room temperature by stoichiometric reactions of the trilacunary ligand with M3+ in 0.1 M carbonate solution. The new complexes were isolated as sodium and mixed sodium/potassium salts and were characterized by elemental analysis, IR, 13C and 29Si NMR, UV–Vis spectroscopy, TGA, DSC and single crystal structure analysis. The crystal structure of the complexes consist of two lacunary Keggin moieties which are linked by a (H2OMO)3C belt into an assembly of virtual C2 symmetry. Each M3+ ion adopts a mono-capped trigonal-prismatic coordination. The C2 axis of the complexes and the local 3-fold axis of the MO6 group lies in the (H2OMO)3C belt plane. The trigonal prismatic geometry is achieved by the two terminal oxygen atoms of an edge shared pair of WO6 octahedra from each moiety and two oxygen from the belt, and the cap by one external water ligand. The hydrolytic and thermal stabilities of the complexes and the reasons that prove the retention of the isomeric form of the trilacunary ligand upon complexation are discussed. 相似文献
189.
Functionalization of Silicon Nanoparticles via Silanization: Alkyl, Halide and Ester 总被引:2,自引:0,他引:2
The feasibility of using silanization as a general tool to functionalize the surface of silicon nanoparticles (NPs) has been
investigated in detail. Silicon NPs were prepared from reduction of silicon tetrachloride with sodium naphthalide. The terminal
chloride on the surface of as-synthesized particles was substituted by methanol and water, in sequence. The particles were
then silanized by octyltrichlorosilane, 11-bromoundecyltrichlorosilane, or 2-(carbomethoxy)ethyltrichlorosilane. These treatments
yielded alkyl-, bromo-, or ester-termini on NP surfaces, respectively. The NPs were characterized by TEM, NMR, FTIR, UV–Vis,
and PL spectroscopy. Changes of termination groups brought various functionalities to the NPs, without loss of the photophysics
of the original NPs. 相似文献
190.