全文获取类型
收费全文 | 1592篇 |
免费 | 370篇 |
国内免费 | 207篇 |
专业分类
化学 | 934篇 |
晶体学 | 102篇 |
力学 | 28篇 |
综合类 | 6篇 |
数学 | 3篇 |
物理学 | 1096篇 |
出版年
2024年 | 4篇 |
2023年 | 11篇 |
2022年 | 28篇 |
2021年 | 27篇 |
2020年 | 44篇 |
2019年 | 39篇 |
2018年 | 45篇 |
2017年 | 49篇 |
2016年 | 77篇 |
2015年 | 59篇 |
2014年 | 59篇 |
2013年 | 125篇 |
2012年 | 88篇 |
2011年 | 122篇 |
2010年 | 80篇 |
2009年 | 112篇 |
2008年 | 94篇 |
2007年 | 131篇 |
2006年 | 118篇 |
2005年 | 77篇 |
2004年 | 86篇 |
2003年 | 95篇 |
2002年 | 120篇 |
2001年 | 63篇 |
2000年 | 61篇 |
1999年 | 49篇 |
1998年 | 56篇 |
1997年 | 37篇 |
1996年 | 33篇 |
1995年 | 46篇 |
1994年 | 34篇 |
1993年 | 24篇 |
1992年 | 13篇 |
1991年 | 10篇 |
1990年 | 14篇 |
1989年 | 11篇 |
1988年 | 8篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1984年 | 2篇 |
1979年 | 3篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 7篇 |
1972年 | 3篇 |
排序方式: 共有2169条查询结果,搜索用时 15 毫秒
101.
102.
A detailed singlet potential energy surface(PES) of [Si,C,O,O] system including a van der Waals (vdW) comples SiO……CO2,eight isomers,and twelve transiton states is investigated by MP2 and QCISD(T) (single-point)methods.At the final QCISD(T)/6-311 G(2df)//MP2/6-311G(d) level with zero-point energy included,the complex SiO……CO is found to be thermodynamically and kinetically the most stable species.Although eight ismoers are located as local energy minima,they are rather unstable toward isomerization to the dissociation fragments or comples.For the reaction of silocon atoms with carbon dioxide,two competitive reaction channels are found,and the primary pathway,which leads to the products of SiO and CO fragments,is the direct oxygen-abstraction process from carbon dioxide by silicon atom with a41.16 kJ/mol reaction barrier height.Our predications are in good agreement with previous experimental and theoretical studies. 相似文献
103.
104.
E. Miyoshi T. Iura Y. Sakai H. Tochihara S. Tanaka H. Mori 《Journal of Molecular Structure》2003,630(1-3):225-232
We investigated the interactions between the Si(111) surface and the Na, Mg, and Al atoms using cluster model calculations. Calculations were performed at levels of complete-active-space self-consistent-field (CASSCF) and multi-reference singly and doubly excited configuration interaction (MRSDCI) calculations using the model core potential method. Our calculations revealed that the most favorable sites of Na, Mg, and Al adsorption on Si(111) are on top (T1), bridge (B2), and 3-fold filled (T4) sites, respectively. The nature of chemical bonds between these metal atoms and the dangling bonds of the surface Si atoms are found to be essentially covalent. 相似文献
105.
Syntheses, Single-Crystal X-Ray Analyses and Solid-State 29Si NMR Studies of a Zwitterionic λ5-Spirosilicate and a Cage-like Octa(silasesquioxane) The zwitterionic λ5-spirosilicate bis[2,3-naphthalenediolato(2 ?)][2-(dimethylammonio)phenyl]silicate ( 1 ; isolated as 1 · 1/2 CH3CN) was synthesized by reaction of the [2-(dimethylamino)phenyl]dimethoxyorganosilanes 5, 6 and 7 [2-(Me2N)C6H4Si(OMe)2R: R = Ph ( 5 ), cyclo? C6H11 ( 6 ), Me ( 7 )] with 2,3-dihydroxynaphthalene in acetonitrile at room temperature. Reaction of 1 · 1/2 CH3CN or [2-(dimethylamino)phenyl]trimethoxysilane ( 3 ) with water in acetonitrile yielded the cage-like octa{[2-(dimethylamino)phenyl]silasesquioxane} ( 2 ). The crystal structures of 1 · 1/2 CH3CN and 2 were studied by X-ray diffraction. In addition, 1 · 1/2 CH3CN and 2 were characterized by solid-state (29Si CP/MAS) and solution NMR studies (1H, 13C, 29Si). 相似文献
106.
硅锑钼杂多酸·罗丹明B缔合物的共振散射光谱研究及其应用 总被引:5,自引:0,他引:5
在0.04mol/L H2SO4介质中,SiO^2-3、Sb(Ⅲ)和MoO^2-4形成Si-Sb-Mo三元杂多酸;调节酸度至0.22mol/L H2SO4加入罗丹明B生成四元缔合物。该缔合物在600nm处产生一灵敏的共振散射峰。据此建立了一个测定2-40ng/mL Si的共振散射光谱分析新方法,用于钢样中硅的测定,结果满意。 相似文献
107.
T. Woignier C. Fernandez-Lorenzo J. L. Sauvajol J. F. Schmit J. Phalippou R. Sempere 《Journal of Sol-Gel Science and Technology》1995,5(3):167-172
The structure of the silica aerogels was studied by Raman spectroscopy. The spectra of the solid network resembles that of bulk silica with additional bands related to organic groups and a large amount of OH groups.The typical bands due to ring breathing also called defect bands D
1 and D
2 located at 490 and 610 cm–1 are present. However, the evolution of the D
2 band compared to that of OH band (980 cm–1) seems apparently, in contradiction with the results previously reported in the literature. During heat treatments between 25 and 300°C the D
2 and the OH bands increase simultaneously. Generally, in silica glass the defect band D
2 grows at the expense of the OH groups.This result is explained by the oxidation of the organic compounds which, in this temperature range, leads to the formation of the both species (OH) and those related to siloxane rings. 29Si MAS NMR results are in agreement with the Raman study. 相似文献
108.
Harry J. Whitlow Margaretha Andersson Mikael Hult Leif Persson Mohamed El Bouanani Mikael Östling Carina Zaring Nils Lundberg David D. Cohen Nick Dytlewski Peter N. Johnston Ian F. Bubb Scott R. Walker Erik Johanson Sture Hogmark P. Anders Ingemarsson 《Mikrochimica acta》1995,120(1-4):171-181
Recoil Spectrometry covers a group of techniques that are very similar to the well known Rutherford backscattering Spectrometry technique, but with the important difference that one measures the recoiling target atom rather than the projectile ion. This makes it possible to determine both the identity of the recoil and its depth of origin from its energy and velocity, using a suitable detector system. The incident ion is typically high-energy (30–100MeV)35C1,81Br or127I. Low concentrations of light elements such as C, O and N can be profiled in a heavy matrix such as Fe or GaAs. Here we present an overview of mass and energy dispersive recoil Spectrometry and illustrate its successful use in some typical applications. 相似文献
109.
磷酸铝类分子筛是近年来继Y型和ZSM七分子筛之后的第三代合成分子筛材料,其骨架由A10。和P0。四面体均匀交替地组成问.由于带负电行的A10。和带正电荷的PO。四面体数目相等,整个骨架呈电中性,所以这类分子筛本身无离子交换能力和催化活性.当用硅或某些金属离子(如Mg、Fe、Co、Zn等)对磷酸铝分子筛进行同晶取代,就会在骨架上造成电行不平衡,从而使这类分子筛具有一定的离子交换能力和酸性【习.因而对硅或金属离子在磷酸错类分子筛中取代机理的研究一直是人们感兴趣的问题问.Vpl-5是最近才合成出来的具有18圆环一维孔结构的… 相似文献
110.
有机硅化合物是半导体工业中产生硅元件的基本原料和有机合成中的重要试剂,是多年来大家研究较多的分子体系之一.本文报导了用同步辐射加速器产生的真空紫外光,电离St(CH3hCI。分子.在50-120n-m波长范围内,测量了各种离子产物与真空紫外光波长的关系,推算得它的绝热电离电势和离子中几个化学键的键能.1实验装置和方法本工作在国家同步辐射实验室光化学实验站进行.进行分子真空紫外光电离研究的实验系统已在文献山中详细描述.同步辐射加速器产生的真空紫外光波长用Ne气的电离势标定,其误差<士0-Inln.单色仪的分辨率为河凸… 相似文献