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71.
Benjamin ZeebMonika Gibis Lutz FischerJochen Weiss 《Journal of colloid and interface science》2012,387(1):65-73
The influence of interfacial crosslinking, layer thickness and layer density on the kinetics of Ostwald ripening in multilayered emulsions at different temperatures was investigated. Growth rates of droplets were measured by monitoring changes in the droplet size distributions of 0.5% (w/w) n-octane, n-decane, and n-dodecane oil-in-water emulsions using static light scattering. Lifshitz-Slyozov-Wagner theory was used to calculate Ostwald ripening rates. A sequential two step process, based on electrostatic deposition of sugar beet pectin onto fish gelatin or whey protein isolate (WPI) interfacial membranes, was used to manipulate the interfacial properties of the oil droplets. Laccase was added to the fish gelatin-beet pectin emulsions to promote crosslinking of adsorbed pectin molecules via ferulic acid groups, whereas heat was induced to promote crosslinking of WPI and helix coil transitions of fish gelatin. Ripening rates of single-layered, double-layered and crosslinked emulsions increased as the chain length of the n-alkanes decreased. Emulsions containing crosslinked fish gelatin-beet pectin coated droplets had lower droplet growth rates (3.1 ± 0.3 × 10−26 m3/s) than fish gelatin-stabilized droplets (7.3 ± 0.2 × 10−26 m3/s), which was attributed to the formation of a protective network. Results suggest that physical or enzymatic biopolymer-crosslinking of interfaces may reduce the molecular transport of alkanes between the droplets in the continuous phase. 相似文献
72.
73.
R. Vetter 《Isotopes in environmental and health studies》2013,49(11):380-383
Die Bestimmung dünner Auftragsschichten auf bewegten Trāgermaterialien mit der β-Rūckstreumethode hängt wesentlich von der Empfindlichkeit der Messung und der Dynamik des Prozesses ab. In diesem Beitrag wird für spezielle Stoffe der Einfluβ der Trāgermaterialien bei Mehrschichtproblemen auf die Empfindlichkeit untersucht. 相似文献
74.
《Physics and Chemistry of Liquids》2012,50(3):209-219
Abstract The system of hard rods in an external, uniform gravitational field is studied and exact expressions obtained for the partition functions, and the one- and two-particle distributions. In principle all higher order distributions can be exactly expressed as finite sums and the Laplace transforms of the one-particle density and pressure for a semi-infinite system are reducible to single integrals. Limiting cases of weak field and small rod diameters are examined. In the former case, these results agree with Percus and Lebowitz's local density expansion. In the latter case, corrections to the barometric pressure and density laws are obtained. Finally some mathematical difficulties involved in the calculation of the virial expansion and distribution of roots of the grand partition function are mentioned. 相似文献
75.
La0.45Ce0.45F3:Tb (10 mol% Tb) nanoparticles was synthesized via sonochemical method and then coated with silica (SiO2) shells through a microemulsion process, resulting in the formation of core/shell structured LaCeF3:Tb/SiO2 nanoparticles. The obtained core/shell LaCeF3:Tb/SiO2 nanoparticles are spherical and uniform in size (average size about 60 nm), strongly fluorescent, and long fluorescence lifetime
(1.87 ms). This kind of nanoparticles was water-soluble, which could be applied in biological labeling and other fields. 相似文献
76.
J. Gaca M. Wójcik A. Jasik K. Pierściński M. Kosmala A. Turos A. M. Abdul-Kaderd 《Opto-Electronics Review》2008,16(1):12-17
GaAs/AlAs Bragg mirrors on GaAs with varied number of layer pairs were grown, by molecular beam epitaxy (MBE), to be applied
for semiconductor saturable absorber mirrors (SESAMs) and intensity modulators. Due to the random variation of the growth
rate, substrate surface roughness, and interdiffusion at the interfaces, precise control of the growth conditions of deposited
layers poses a serious problem. Usually, thickness variations and composition grading at the heterointefaces result in variations
of the mirror reflectivity. In this paper, the high resolution X-ray diffraction (HRXRD), optical reflectance, Rutherford
backscattering/channelling (RBS), supported by numerical evaluation methods were employed to determine both the exact thickness
of each layer and the composition grading at the interface between succeeding layers of GaAs/AlAs-based mirrors. To reduce
ambiguity and to speed up the analysis, the rocking curves and RBS spectra were simulated concurrently, using results of one
simulation to verify the others. This process was carried out until the best fit between experimental and calculated curves
was achieved. The complementary use of both methods results in improved sensitivity and makes the whole process of evaluation
of the thickness variation of each layer and the size of the composition grading at the interfaces less time consuming. 相似文献
77.
The relationships between the morphological characteristics and the vulnerability of atherosclerotic plaque were analyzed
theoretically and several suggestions were proposed to evaluate the plaque vulnerability. Validated by animal experiments
and clinical studies, the theoretical results were confirmed.
Supported by the National Natural Science Foundation of China (Grant Nos. 10302016 and 60402023), the National Basic Research
Program of China (973 Program)(Grant No. 2006CB503803), and the National Hi-Tech Research and Development Program of China
(863 Program) (Grant No. 2007AA02Z448) 相似文献
78.
79.
C. Andreoiu M. Axiotis G. de Angelis J. Ekman C. Fahlander E. Farnea A. Gadea T. Kröll S.M. Lenzi N. Mărginean T. Martinez M.N. Mineva C. Rossi Alvarez D. Rudolph C.A. Ur 《The European Physical Journal A - Hadrons and Nuclei》2002,15(4):459-462
Excited states in 59Zn were observed for the first time following the fusion-evaporation reaction 24Mg + 40Ca at a beam energy of 60 MeV. The GASP array in conjunction with the ISIS Silicon ball and the NeutronRing allowed for the
detection of γ-rays in coincidence with evaporated light particles. The mirror symmetry of 59Zn and 59Cu is discussed.
Received: 28 May 2002 / Accepted: 10 July 2002 / Published online: 3 December 2002
RID="a"
ID="a"Present address: Oliver Lodge Laboratory, University of Liverpool, P.O. Box 147, Liverpool, L69 7ZE, United Kingdom; e-mail: ca@ns.ph.liv.ac.uk.
RID="b"
ID="b"Present address: Physik-Departament, Technische Universit?t München, D-85748 Garching, Germany.
Communicated by W. Henning 相似文献
80.
We study global symmetry breaking in the 2D system of scalar nonconserved order parameter following a quench to zero temperature. We show that the instant of time when the symmetry is broken and the final morphology is chosen corresponds to the saturation of the order parameter inside the domains. There are three possible final morphologies: the positive and negative order parameter final morphology, and the state of the coexisting positive and negative order parameter subsystems with a flat interface between them. We find also that each type of the final morphology constitutes about 1/3 of all cases, what agrees with the results obtained recently by Spirin et al. [Phys. Rev. E 65, 016119 (2001)]. Our results are pertinent for the two dimensional systems, but we suspect that there is also a way to apply similar arguments for the three dimensional ones. 相似文献