An unbreakable on-line approach towards sol-gel capillary microextraction

In this work a novel unbreakable sol-gel-based in-tube device for on-line solid phase microextraction (SPME) was developed. The inner surface of a copper tube, intended to be used as a high performance liquid chromatography (HPLC) loop, was electrodeposited by metallic Cu followed by the self assembled monolayers (SAM) of 3-(mercaptopropyl) trimethoxysilane (3MPTMOS). Then, poly (ethyleneglycol) (PEG) was chemically bonded to the -OH sites of the SAM already covering the inner surface of the copper loop using sol-gel technology. The homogeneity and the porous surface structure of the SAM and sol-gel coatings were examined using the scanning electron microscopy (SEM) and adsorption/desorption porosimetry (BET). The prepared loop was used for online in-tube SPME (capillary microextraction) of some selected polycyclic aromatic hydrocarbons (PAHs), as model compounds, from the aquatic media. After extraction, the HPLC mobile phase was used for on-line desorption and elution of the extracted analytes from the loop to the HPLC column. Major parameters affecting the extraction efficiency including the sample flow rate through the copper tube, loading time, desorption time and sample volume were optimized. For investigating the sorbent efficiency, four loops based on the copper tube itself, the copper tube after electrodeposition with Cu and the tubes with the SAMs and SAMs-sol-gel coating were made and compared. The SAMs-sol-gel coated loop clearly shows a prominently lead of at least 20-100 times of higher efficiency. The linearity for the analytes was in the range of 0.01-500 μg L(-1). Limit of detection (LOD) was in the range of 0.005-0.5 μg L(-1) and the RSD% values (n=5) were all below 8.3% at the 5 μg L(-1) level. The developed method was successfully applied to real water samples while the relative recovery percentages obtained for the spiked water samples were from 90 to 104%. The prepared loop exhibited long life time due to its remarkable solvent and mechanical stability. Different solvents such as methanol, acetonitrile and acetone were passed through the loop for many days and it was also used for more than 100 extractions/desorption of the selected analytes and no decrease in the peak areas was observed.     

Advanced Materials in Cultural Heritage Conservation

Cultural Heritage is a crucial socioeconomic resource; yet, recurring degradation processes endanger its preservation. Serendipitous approaches in restoration practice need to be replaced by systematically addressing conservation issues through the development of advanced materials for the preservation of the artifacts. In the last few decades, materials and colloid science have provided valid solutions to counteract degradation, and we report here the main highlights in the formulation and application of materials and methodologies for the cleaning, protection and consolidation of works of art. Several types of artifacts are addressed, from murals to canvas paintings, metal objects, and paper artworks, comprising both classic and modern/contemporary art. Systems, such as nanoparticles, gels, nanostructured cleaning fluids, composites, and other functional materials, are reviewed. Future perspectives are also commented, outlining open issues and trends in this challenging and exciting field.     

Meissner Anisotropy in Deuterated (TMTSF)2Clo4

Both the Meissner-signal (flux expulsion on cooling through T_c) and the shielding signal (obtained by turning on a field in the superconducting state) have been observed in deuterated single crystals for fields oriented both along and normal to the chain axis. A possible isotope effect on T_c is discussed. We find complete diamagnetism in normal fields and incomplete (～ 40 %) diamagnetism in parallel fields. A dramatic drop of the Meissner-effect in parallel fields well below H_c1 is observed and not yet well explained.     

Poly(N,N-dimethylacrylamide)-grafted polyacrylamide: a self-coating copolymer for sieving separation of native proteins by CE

The potential of a series of newly synthesized poly(N,N-dimethylacrylamide) (PDMA) grafted polyacrylamide (PAM) copolymers (P(AM-PDMA)) as a replaceable separation medium for protein analysis was studied. A comparative study with and without copolymers was performed; the separation efficiency, analysis reproducibility and protein recovery proved that the P(AM-PDMA) copolymers were efficient in suppressing the adsorption of basic proteins onto the silica capillary wall. Furthermore, the size-dependent retardation of native proteins in a representative P(AM-PDMA) copolymer was demonstrated by Ferguson analysis. The results showed that the P(AM-PDMA) copolymers combine the good coating property of PDMA and the sieving property of PAM and could be applied as a sieving matrix for the analysis of native proteins.     

傅里叶自函数的维格纳分布及应用

傅里叶变换是现代光学发展的重要理论工具。自1991年Caola首次定义傅里叶自函数以来1,它在光学领域的应用研究日趋活跃。本文首先对傅里叶自函数定义进行扩展,再讨论其维格纳分布函数及其矩,研究它们在光学中的应用。最后推导出傅里叶自函数应用于光学变换器成象时的变换矩阵。     

Classical and quantum self amplified spontaneous emission in a high gain free electron laser

We describe the quantum theory and the photon statistics of self amplified spontaneous emission (SASE) in a high gain free electron laser (FEL) using Glauber's quantum theory of coherence. We generalize a previous theory by taking into account many-mode effects and the initiation process resulting from classical shot noise, quantum noise, an injected coherent field and coherent bunching. In particular, we define the concept of quantum SASE which is appropriate when the initial quantum fluctuations dominate over the classical shot noise. We also discuss the conditions for the observation. Quantum SASE is a new quantum phenomenon in which the single electron uncertainty fluctuations of the conjugate variables position and momentum produce exponential amplification of the vacuum field.     

NEA GaAs光电阴极激活工艺研究

本文报道了 GaAs 反射式光电阴极的激活工艺过程和结果.通过实验确定了 GaAs表面的热清洁温度,利用钼丝热辐射加热方法达到了比较理想的清洁效果,采用铯分子源和高纯氧作氧源获得了高于1000μA/1m 的激活积分灵敏度.     

Self polarization in GaAs–(Ga, Al)As quantum well wires: electric field and geometrical effects

The response of an electron to an external electric field in different shapes of infinite quantum well wires has been investigated. The self-polarization effect which can be defined as the influence of the barrier potential on the impurity electron is studied for the quantum well wire of square, rectangular and cylindrical cross-sections. An external electric field vanishes due to the self-polarization effect has been calculated. It is shown that the self-polarization effect outside of the center depends on both the geometrical form of the wire and the impurity position in the same structure.     

Ab initio and density functional theory studies of the gas-phase hydrogen fluoride addition to ethylene. An example of catalytic effect from a second molecule of the reagent

The accuracy of three popular DFr methods (hybrid, gradient-corrected, and local) has been evaluated on the HF-assisted addition of HF to ethylene. The possibility of forming trimolecular (two HF and one ethylene) and dimolecular (one HF and one ethylene) complexes and transition state structures during the transformation of HF and ethylene in fluoroethane is discussed. An energetically favorable pathway was selected on the basis of the computed potential energy surface for these two reactions.     

Tape Casting of Graphite Material: A New Electrochemical Sensor

Tape casting is a feasible method for preparing ceramic tapes with different electrical and magnetic properties for multilayer ceramic devices. This paper describes the tape casting process for the preparation of a new kind of self‐standing carbon electrodes (SSCE) using different ratios of graphite and the organic additives generally used in the non‐aqueous tape casting process.