Evolution and Operating Experiences with Different Drop‐On‐Demand Systems

Summary: We describe the development of different drop‐on‐demand systems particularly for applications for the liquid handling of biopolymers. Different designs of drop‐on‐demand systems developed by the authors are described. Experiments with these systems show the applicability for pipetting different liquids with different properties. Commercially available systems are also tested. A comparison of the different approaches leads to a discussion of the best fields of application of the different approaches or, alternatively, to the potential further development of the drop‐on‐demand technologies.

Principle setup of the print heads.     

Monte Carlo Investigation of Adsorption Stage of O on Ru（0001）：a Study of a Lattice Model

The adsorption of O on Ru(0001) is studied by means of Monte Carlo simulation of lattice gas model on a triangular lattice. A recent STM study shows that at low coverage the p(2×2) structure grows via island formation but the p(2×1) structure is abruptly formed at a critical coverage. Moreover, it also shows that there is a coexistence of the p(2×2) and p(2×1) structures. The above results seem not to coincide with the former studies of the system by both the LEED and Monte Carlo simulation. We therefore carried out the Monte Carlo study for the system again in the present paper and found that our simulation almost agrees with the results of the STM.     

X射线光谱在生命起源和全球气候变化等若干重大科学问题中的研究进展

生命起源、全球气候变化等是关系到人类未来命运的重大科学问题,X射线光谱(XRS)可原位测定物质组成与元素形态,在解决重大科学问题、揭示自然规律中发挥了重要作用:(1)在生命起源探索中,通过RNA结构和海洋热液自养体系元素形态分析,揭示了RNA形成机制和生物地球化学规律;(2)在地球早期生命研究中,通过沉积纹层、细胞组构...     

某工程地基基坑支护探讨

软土地基中的支护是基础工程的关键,在节约成本的前提下,选择合理的支护结构至关重要．通过对某公司将要开发的2个基坑支护方案的项目进行的相关分析、计算和探讨,总结出了软土地基中的基坑支护方案的选择原则及其相对应的施工措施等．     

螺旋线型脉冲形成线匝间击穿与输出波形的研究

 针对螺旋线型脉冲形成线放电过程的匝间击穿问题,采用数值模拟的方法研究了影响螺旋线上轴向电场的因素,模拟结果表明：螺旋线的螺旋角越大、开关的上升沿越小、负载的阻值越小则越容易造成匝间击穿;针对输出波形的前沿上冲和下凹问题,通过数值模拟和实验方法研究了加速器内阻抗不匹配段对输出波形的影响,结果表明: 改变螺旋线与开关之间连接段的阻抗以及开关和二极管之间过渡段的阻抗,使之接近于螺旋线阻抗,并使电长度减小,可以消除波形的前沿上冲和下凹,得到近似方波的高电压脉冲输出。     

孔梯度陶瓷纤维复合膜管的制备及特性

陶瓷过滤管具有孔隙率高、耐腐蚀、耐高温、机械强度高、便于清洗、使用寿命长等优点,是高温烟尘处理用的高效过滤元件.本文研制了一种具有梯度孔结构堇青石陶瓷纤维复合膜过滤元件,该过滤元件是由多孔支撑体、过渡层和分离膜层组成.其中支撑体、过渡层和分离层的气孔率分别为35～40;、50～60;和60～70;.文中主要分析了孔梯度陶瓷纤维复合膜管的材料结构和抗热震性能,同时对复合膜管进行含尘气体过滤的冷态模拟试验.对于烟气中粒径大于或等于0.1μm的颗粒,复合膜管的截留率达到99.8;以上.     

Kemp Elimination Reaction Catalyzed by Electric Fields

The Kemp elimination reaction is the most widely used in the de novo design of new enzymes. The effect of two different kinds of electric fields in the reactions of acetate as a base with benzisoxazole and 5-nitrobenzisoxazole as substrates have been theoretically studied. The effect of the solvent reaction field has been calculated using the SMD continuum model for several solvents; we have shown that solvents inhibit both reactions, the decrease of the reaction rate being larger as far as the dielectric constant is increased. The diminution of the reaction rate is especially remarkable between aprotic organic solvents and protic solvents as water, the electrostatic term of the hydrogen bonds being the main factor for the large inhibitory effect of water. The presence of an external electric field oriented in the direction of the charge transfer (z axis) increases it and, so, the reaction rate. In the reaction of the nitro compound, if the electric field is oriented in an orthogonal direction (x axis) the charge transfer to the NO₂ group is favored and there is a subsequent increase of the reaction rate. However, this increase is smaller than the one produced by the field in the z axis. It is worthwhile mentioning that one of the main effects of external electric fields of intermediate intensity is the reorientation of the reactants. Finally, the implications of our results in the de novo design of enzymes are discussed.     

On factor-invariant graphs

We classify trivalent vertex-transitive graphs whose edge sets have a partition into a Hamilton cycle and a 1-factor that is invariant under the action of the full automorphism group.     

政府补贴下供应链合作减排的微分博弈

借助微分博弈理论,研究政府补贴下由一个供应商和一个制造商组成的供应链长期合作减排的动态协调问题。在产品需求受减排量的影响下,构建了集中式和分散式微分博弈模型,并设计了成本分担契约协调供应链。结合算例对参数进行灵敏度分析,研究发现:政府补贴对企业减排起到有效的激励作用并且有助于供应链实现协调;成本分担契约的引入可提高供应商和制造商的减排努力水平、产品减排量及需求量,并实现了供应链协调;随着供应商、制造商减排成本系数以及减排量自衰减率的增大,引入契约后产品减排量呈下降趋势;相反,随着产品减排量对减排努力水平的敏感性以及消费者低碳意识的增强,产品减排量呈上升趋势。     

高速磁浮列车气动噪声分布规律研究

本文基于上海线高速磁浮列车现场噪声测试，结合数值仿真分析了磁浮列车行驶时的噪声特性以及气动噪声分布规律．数值仿真采用延时分离涡结合声比拟的方法，并对比现场测试噪声数据，给出了高速列车气动噪声特性以及噪声源分布规律．研究结果表明：列车行驶时噪声时程呈现很强脉冲性，频率小于100 Hz噪声主要来源于与高架桥梁结构振动相关的二次辐射噪声，特别是次声频段内，桥梁自振会产生显著的噪声．磁浮列车表面气动噪声分布规律与噪声频率相关，低频噪声与列车的车尾涡脱相关，高频噪声由车头边界层分离以及再附着、车身边界层流动等引起，而中频噪声主要产生于列车底部、抱轨与轨道梁表面相对运动作用．因此，高速磁浮列车除了要重点考虑车头、车尾的气动外形对气动噪声的影响外，还应考虑轨道间隙处气动噪声及其分布规律．