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121.
《高分子科学杂志,A辑:纯化学与应用化学》2013,50(12):1253-1262
Abstract This article describes the synthesis and application of poly(1,4‐phenylene‐2,6‐pyridylurea) (MCPU) as a charge transporting and rare earth metal chelating host matrix for organic light emitting diodes (OLEDs). The chelation between MCPU and Terbium (Tb3+) (the rare earth metal used in this study), is facile in nature and persists in thin films obtained by spin coating onto various substrates. Multiple polymer chelating moieties at each Tb ion site may derive from MCPU repeat units from a single polymer chain or two polymer chains, and their respective structures are proposed. The emissive properties of these films in the presence and absence of Terbium (Tb3+) were characterized by steady state UV‐VIS absorption spectroscopy and photoluminescence (PL) spectroscopy. The PL emission from Tb(MCPU) films indicate contribution from both the host MCPU and the Tb ions. The incorporation of these films in OLEDs employing different device architectures yields electroluminescence spectra, which show the characteristic emission of the Tb ions but no emission from the host polymer matrix. Although these devices are not optimized, they exhibit an order of magnitude higher external quantum efficiency as compared to that of conventional aluminum tris 8‐hydroxyquinoline (Alq3) based OLEDs, at low current densities. 相似文献
122.
《高分子科学杂志,A辑:纯化学与应用化学》2013,50(12):1401-1410
Abstract Electrostatically layered aluminosilicate nanocomposites have been prepared by the sequential deposition of poly(allylamine hydrochloride)/poly(acrylic acid)/poly(allylamine hydrochloride)/saponite (PAH/PAA/PAH/saponite)10 on poly(ethylene terephtalate) (PET) film. Exfoliated saponite nanoplatelets were obtained by extensive shaking, sonication, and centrifugation of a water suspension. To minimize permeability and improve the mechanical integrity, cross‐linking of composite films was carried out at different temperatures. The formation of amide linkage induced through heating was observed by Fourier Transform Infrared (FT‐IR) and x‐ray photoelectron spectroscopy (XPS). The cross‐linking of nanocomposites (PAH/PAA/PAH/saponite)10 showed 60% decrease in permeability of oxygen when compared with the pristine PET substrate film. In contrast, water permeability of the nanocomposite membrane was not affected by heating temperature and deposition cycles. 相似文献
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125.
Dhirendra Kumar Dr. K. R. Justin Thomas Ching‐Chiao Lin Prof. Jwo‐Huei Jou 《化学:亚洲杂志》2013,8(9):2111-2124
A series of pyrenoimidazoles that contained various functional chromophores, such as anthracene, pyrene, triphenylamine, carbazole, and fluorene, were synthesized and characterized by optical, electrochemical, and theoretical studies. The absorption spectra of the dyes are dominated by electronic transitions that arise from the pyrenoimidazole core and the additional chromophore. All of the dyes exhibited blue‐light photoluminescence with moderate‐to‐high quantum efficiencies. They also displayed high thermal stability and their thermal‐decomposition temperatures fell within the range 462–512 °C; the highest decomposition temperature was recorded for a carbazole‐containing dye. The oxidation propensity of the dyes increased on the introduction of electron‐rich chromophores, such as triphenylamine or carbazole. The application of selected dyes that featured additional chromophores such as pyrene, carbazole, and triphenylamine as blue‐emissive dopants into multilayered organic light‐emitting diodes with a 4,4′‐bis(9H‐carbazol‐9‐yl)biphenyl (CBP) host was investigated. Devices that were based on triphenylamine‐ and carbazole‐containing dyes exhibited deep‐blue emission (CIE 0.157, 0.054 and 0.163, 0.041), whereas a device that was based on a pyrene‐containing dye showed a bright‐blue emission (CIE 0.156, 0.135). 相似文献
126.
利用MPTC型气泡压力张仪研究了十二烷基硫酸钠(SDS)溶液在不同NaCl 浓度下的动态表面吸附性质, 分析了离子型表面活性剂在表面吸附层和胶束中形成双电层结构产生表面电荷对动态表面扩散过程和胶束性质的影响. 结果表明, SDS在表面吸附过程中, 表面电荷的存在会产生5.5 kJ·mol-1的吸附势垒(Ea), 显著降低十二烷基硫酸根离子(DS-)的有效扩散系数(Deff). 十二烷基硫酸根离子的有效扩散系数与自扩散系数(D)的比值(Deff/D)仅为0.013, 这表明SDS与非离子型表面活性剂不同, 在吸附初期为混合动力控制吸附机制. 加入NaCl可以降低吸附势垒. 当加入不小于80 mmol·L-1 NaCl后, Ea小于0.3 kJ·mol-1, Deff/D在0.8-1.2之间, 表现出与非离子型表面活性剂相同的扩散控制吸附机制. 同时, 通过分析SDS胶束溶液的动态表面张力获得了表征胶束解体速度的常数(k2). 发现随着NaCl 浓度的增大, k2减小, 表明SDS胶束表面电荷的存在会增加十二烷基硫酸根离子间的排斥力, 促进胶束解体. 相似文献
127.
M. Chandra Sekhar N. Nanda Kumar Reddy B. Venkata Rao G. Mohan Rao S. Uthanna 《Surface and interface analysis : SIA》2014,46(7):465-471
Titanium dioxide (TiO2) thin films were deposited onto p‐Si substrates held at room temperature by reactive Direct Current (DC) magnetron sputtering at various sputter powers in the range 80–200 W. The as‐deposited TiO2 films were annealed at a temperature of 1023 K. The post‐annealed films were characterized for crystallographic structure, chemical binding configuration, surface morphology and optical absorption. The electrical and dielectric properties of Al/TiO2/p‐Si structure were determined from the capacitance–voltage and current–voltage characteristics. X‐ray diffraction studies confirmed that the as‐deposited films were amorphous in nature. After post‐annealing at 1023 K, the films formed at lower powers exhibited anatase phase, where as those deposited at sputter powers > 160 W showed the mixed anatase and rutile phases of TiO2. The surface morphology of the films varied significantly with the increase of sputter power. The electrical and dielectric properties on the air‐annealed Al/TiO2/p‐Si structures were studied. The effect of sputter power on the electrical and dielectric characteristics of the structure of Al/TiO2/p‐Si (metal‐insulator‐semiconductor) was systematically investigated. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
128.
Four D–π–A bipolar molecules with n-butyl-1,8-naphthalimide (BNI) fragments as acceptors, acetylenes as π-spacers, and different aromatic groups as donors have been designed to explore their optical, electronic, and charge transport properties as charge transport and luminescent materials for organic light-emitting diodes (OLEDs). The frontier molecular orbitals (FMOs) and local density of states analysis have turned out that the vertical electronic transitions of absorption and emission are characterized as intramolecular charge transfer (ICT). The calculated results show that their optical and electronic properties are affected by the different donors of the bipolar molecules. Our results suggest that D–π–A 1,8-naphthalimide derivatives with donors triphenylamine (1), 1-nitrobenzene (2), anisole (3), and 4-phenylbenzo[c][1,2,5]thiadiazole (4) fragments are expected to be promising luminescent materials. Furthermore, 2–4 are expected to be promising candidates for both electron and hole transport materials as well as potential ambipolar charge transport material, whereas BNI and 1 can serve as hole transfer materials only. We have also predicted the mobility of 4 with better performance in three different space groups. On the basis of investigated results, we proposed a rational way for the design of charge transport and/or luminescent materials simultaneously. 相似文献
129.
Phosphorescent Cyclometalated Iridium(III) Complexes That Contain Substituted 2‐Acetylbenzo[b]thiophen‐3‐olate Ligand for Red Organic Light‐Emitting Devices 下载免费PDF全文
Chen Yang Dr. Shiu‐Lun Lai Dr. Sharon Lai‐Fung Chan Dr. Kam‐Hung Low Dr. Gang Cheng Kwan‐Ting Yeung Dr. Chi‐Chung Kwok Prof. Dr. Chi‐Ming Che 《化学:亚洲杂志》2014,9(12):3572-3585
We report the synthesis of a new class of thermally stable and strongly luminescent cyclometalated iridium(III) complexes 1 – 6 , which contain the 2‐acetylbenzo[b]thiophene‐3‐olate (bt) ligand, and their application in organic light‐emitting diodes (OLEDs). These heteroleptic iridium(III) complexes with bt as the ancillary ligand have a decomposition temperature that is 10–20 % higher and lower emission self‐quenching constants than those of their corresponding complexes with acetylacetonate (acac). The luminescent color of these iridium(III) complexes could be fine‐tuned from orange (e.g., 2‐phenyl‐6‐(trifluoromethyl)benzo[d]thiazole (cf3bta) for 4 ) to pure red (e.g., lpt (Hlpt=4‐methyl‐2‐(thiophen‐2‐yl)quinolone) for 6 ) by varying the cyclometalating ligands (C‐deprotonated C^N). In particular, highly efficient OLEDs based on 6 as dopant (emitter) and 1,3‐bis(carbazol‐9‐yl)benzene (mCP) as host that exhibit stable red emission over a wide range of brightness with CIE chromaticity coordinates of (0.67, 0.33) well matched to the National Television System Committee (NTSC) standard have been fabricated along with an external quantum efficiency (EQE) and current efficiency of 9 % and 10 cd A?1, respectively. A further 50 % increase in EQE (>13 %) by replacing mCP with bis[4‐(6H‐indolo[2,3‐b]quinoxalin‐6‐yl)phenyl]diphenylsilane (BIQS) as host for 6 in the red OLED is demonstrated. The performance of OLEDs fabricated with 6 (i.e., [(lpt)2Ir(bt)]) was comparable to that of the analogous iridium(III) complex that bore acac (i.e., [(lpt)2Ir(acac)]; 6 a in this work) [Adv. Mater. 2011 , 23, 2981] fabricated under similar conditions. By using ntt (Hnnt=3‐hydroxynaphtho[2,3‐b]thiophen‐2‐yl)(thiophen‐2‐yl)methanone) ligand, a substituted derivative of bt, the [(cf3bta)2Ir(ntt)] was prepared and found to display deep red emission at around 700 nm with a quantum yield of 12 % in mCP thin film. 相似文献
130.
Jiang Zhao Meng Lian Yue Yu Xiaogang Yan Xianbin Xu Xiaolong Yang Guijiang Zhou Zhaoxin Wu 《Macromolecular rapid communications》2015,36(1):71-78
A series of novel red phosphorescent polymers is successfully developed through Suzuki cross‐coupling among ambipolar units, functionalized IrIII phosphorescent blocks, and fluorene‐based silane moieties. The photophysical and electrochemical investigations indicate not only highly efficient energy‐transfer from the organic segments to the phosphorescent units in the polymer backbone but also the ambipolar character of the copolymers. Benefiting from all these merits, the phosphorescent polymers can furnish organic light‐emitting diodes (OLEDs) with exceptional high electroluminescent (EL) efficiencies with a current efficiency (η L) of 8.31 cd A−1, external quantum efficiency (η ext) of 16.07%, and power efficiency (η P) of 2.95 lm W−1, representing the state‐of‐the‐art electroluminescent performances ever achieved by red phosphorescent polymers. This work here might represent a new pathway to design and synthesize highly efficient phosphorescent polymers.