全文获取类型
收费全文 | 32834篇 |
免费 | 3738篇 |
国内免费 | 6098篇 |
专业分类
化学 | 29069篇 |
晶体学 | 1317篇 |
力学 | 767篇 |
综合类 | 235篇 |
数学 | 2079篇 |
物理学 | 9203篇 |
出版年
2024年 | 51篇 |
2023年 | 351篇 |
2022年 | 702篇 |
2021年 | 882篇 |
2020年 | 1116篇 |
2019年 | 1100篇 |
2018年 | 913篇 |
2017年 | 1253篇 |
2016年 | 1280篇 |
2015年 | 1165篇 |
2014年 | 1539篇 |
2013年 | 2827篇 |
2012年 | 1935篇 |
2011年 | 2383篇 |
2010年 | 1993篇 |
2009年 | 2279篇 |
2008年 | 2338篇 |
2007年 | 2290篇 |
2006年 | 2142篇 |
2005年 | 2008篇 |
2004年 | 1780篇 |
2003年 | 1462篇 |
2002年 | 1265篇 |
2001年 | 1063篇 |
2000年 | 1005篇 |
1999年 | 810篇 |
1998年 | 689篇 |
1997年 | 606篇 |
1996年 | 523篇 |
1995年 | 533篇 |
1994年 | 471篇 |
1993年 | 398篇 |
1992年 | 308篇 |
1991年 | 219篇 |
1990年 | 139篇 |
1989年 | 136篇 |
1988年 | 119篇 |
1987年 | 72篇 |
1986年 | 75篇 |
1985年 | 67篇 |
1984年 | 52篇 |
1983年 | 34篇 |
1982年 | 43篇 |
1981年 | 47篇 |
1980年 | 49篇 |
1979年 | 44篇 |
1978年 | 32篇 |
1977年 | 27篇 |
1976年 | 14篇 |
1973年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
92.
研究了基于级联二阶非线性的铌酸锂波导全光波长变换器的特性.首先从耦合模方程出发,比较了数值分析结果与小信号近似分析的结果.其次在数值分析基础上,分析了铌酸锂晶体的温度变化导致相应基频光波波长与极化反转光栅周期的变化关系.最后分析了在不同相互作用长度下,转换的光波功率与有效基频光波波长带宽、温度调谐带宽、极化反转光栅周期带宽等关系,以对全光波长变换器件进行优化设计
关键词:
级联二阶非线性
波长变换
准位相匹配
铌酸锂光波导 相似文献
93.
The nanocrystal samples of titanium dioxide doped with europium ion (Eu3+/TiO2 nanocrystal) are synthesized by the sol-gel method with hydrothermal treatment. The Eu3+ contents (molar ratio) in the samples are 0, 0.5%, 1%, 2%, 3% and 4%. The X-ray diffraction, UV-Vis spectroscopy data and scanning electron microscope image show that crystallite size is reduced by the doping of Eu3+ into TiO2. Comparing the Raman spectra of TiO2 with Eu3+/TiO2 (molar ratio Eu3+/TiO2=1%, 2% and 4%) nanocrystals at different annealing temperatures indicates that the anatase-to-rutile phase transformation temperatures of Eu3+/TiO2 nanocrystals are higher than that of TiO2. This is due to the formation of Eu-O-Ti bonds on the surface of the TiO2 crystallite, as characterized by the X-ray photoelectron spectroscopy. The photoluminescence spectra of TiO2 in Eu3+/TiO2 nanocrystals are interpreted by the surface self-trapped and defect-trapped exciton relaxation. The photoluminescence of Eu3+ in Eu3+/TiO2 nanocrystals has the strongest emission intensity at 2% of Eu3+ concentration. 相似文献
94.
Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献
95.
Tatsuo Nakagawa Satoshi Fukura Munenori Nakai Kazumasa Sugiyama Ryohei Kokawa Hiroyuki Kagi 《Optical Review》2006,13(4):269-275
We constructed a scanning near-field optical microscope (SNOM) on a commercially available atomic force microscopy (AFM) apparatus
(SPM-9500J2; Shimadzu Corp.) to measure the stress distribution in ceramic composite materials. Features of our SNOM system
are: (1) a compact SNOM head substituted for the original AFM head; (2) a wide scanning range (125 × 125 μm2) inherited from the original scanner; (3) use of conventional shear-force regulation; (4) an optical system for the illumination-collection
(I-C) mode; (5) excitation by a 488 nm line of an Ar-ion laser, and (6) light detection by photon counting or a polychromator
equipped with an electronically cooled charge coupled device (CCD). This SNOM system was used to measure the surface structure
and stress distribution of an Al2O3/ZrO2 eutectic composite. We simultaneously measured topographic images and fluorescence spectra of an Al2O3/ZrO2 eutectic composite. We estimated its peak intensity, peak position, and peak width from the fluorescence spectrum during
scanning, which respectively correspond to the abundance of Al2O3, stress in the grain, and the anisotropy of that stress. Mapping images showed that the stress and its anisotropy were weaker
in the center of the Al2O3 grain than its boundary between Al2O3 and ZrO2. That observation suggests that Al2O3 underwent intense anisotropic stress induced by volume expansion in the phase transition of ZrO2 from the cubic phase to the monoclinic phase during preparation. 相似文献
96.
In this paper, we report that the phase transformation of Ni-B, Ni-P diffusion barriers deposited electrolessly on Cu, for the reason that the Ni-P layer is a more effective diffusion barrier than the Ni-B layer. The Ni3B crystallized was decomposed to Ni and B2O3 above 400 °C and the Ni3P crystallized was decomposed to Ni and P2O5 above 600 °C respectively in Ar atmosphere. Also, the Ni3B was decomposed to Ni and free B above 400 °C and the Ni3P was decomposed to Ni and free P above 600 °C respectively in H2 atmosphere. The decomposed Ni formed a solid solution with Cu. The Cu diffusion occurred above 400 °C for Ni-B layer and above 600 °C for Ni-P layer, respectively. Because the decomposition temperature of Ni-P layer is about 200 °C higher than that of Ni-B layer, the Ni-P layer is a more effective barrier for Cu than the Ni-B layer. 相似文献
97.
Ultrathin epitaxial Fe films on Cu(1 0 0) with perpendicular magnetization have been used as templates for the preparation of FCC Fe/Cu/Fe trilayers. The magnetic anisotropy and the coupling of these films have been studied by in-situ magneto optical Kerr effect measurements and Kerr microscopy. The magnetic coupling of both Fe layers is found to be dominated by magnetostatic interaction. Adsorbate-induced spin reorientation in the top layer also causes spin reorientation in the bottom layer. The governing role of the Fe-vacuum interface for the magnetism of the whole trilayer is demonstrated. 相似文献
98.
3d-metal antimonides: Fe1+x Sb, N+x Sb, Co+x Sb and the (Ni1?y Fe y )Sb solid solution have been studied by the Mössbauer effect method at 57Fe and 119Sn. It was found that the quadrupole interactions at the Fe and Sn nucleus in 3d-metal antimonides are very sensitive to the filling of different crystallographic sites with metal atoms. The metal atoms in trigonal-bipyramidal sites have a strong effect on the quadrupole splitting of 119Sn. They are nearest to anions (Sb or Sn) with the typical axial ratio of c/a = 1.25. The QS(x) dependence of 119 Sn in 3d-metal antimonides in the 0 ≤ x ≤ 0.1 concentration range can be used to determine x – the concentration of transition metal excess relative to the stoichiometric composition. 相似文献
99.
Polyvinyl alcohol (PVA)-based proton conducting polymer electrolytes have been prepared by the solution cast technique. The
conductivity is observed to increase from 10−9 to 10−4 S cm−1 as a result of orthophosphoric acid (H3PO4) addition. The plot of conductivity vs temperature shows that a phase transition occurred at 343 K in the sample PVA-33 wt%
H3PO4. The β-relaxation peak is observed at 313 K. The glass transition temperature of PVA-33 wt% H3PO4 is 343 K. Orthophosphoric acid seems to play a dual role, i.e., as a proton source and as a plasticizer. The ac conductivity
σ
ac = Aω
s was also calculated in the temperature range from 303 to 353 K. The conduction mechanism was inferred by plotting the graph
of s vs T from which the conduction mechanism for sample PVA-17 wt% H3PO4 was inferred to occur by way of the overlapping large polaron tunneling (OLPT) model and the conduction mechanism for the
sample PVA-33 wt% H3PO4 by way of the correlated barrier height (CBH) model. 相似文献
100.
Tiago Buckup Timo Lebold Alexander Weigel Wendel Wohlleben Marcus Motzkus 《Journal of photochemistry and photobiology. A, Chemistry》2006,180(3):314-321
Biomolecules very often present complex energy deactivation networks with overlapping electronic absorption bands, making their study a difficult task. This can be especially true in transient absorption spectroscopy when signals from bleach, excited state absorption and stimulated emission contribute to the signal. However, quantum control spectroscopy can be used to discriminate specific electronic states of interest by applying specifically designed laser pulses. Recently, we have shown the control of energy flow in bacterial light-harvesting using shaped pump pulses in the visible and the selective population of pathways in carotenoids using an additional depletion pulse in the transient absorption technique. Here, we apply a closed-loop optimization approach to β-carotene using a spatial light modulator to decipher the energy flow network after a multiphoton excitation with a shaped ultrashort pulse in the near-IR. After excitation, two overlapping bands were detected and identified as the S1 state and the first triplet state T1. Using the transient absorption signal at a specific probe delay as feedback, the triplet signal could be optimized over the singlet contribution. 相似文献