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61.
硅杂环丁烷在有机硅化学中是一类非常重要的小分子环系化合物。由于硅杂环丁烷和环丁烷的环张力相似,因而显示出较高的反应活性。例如能与某些试剂作用,生成开环产物;在光解或热解条件下,产生具有Si=C结构的高活性中间体,可用以合成多种有机硅化合物。 相似文献
62.
Simulation of aerated lagoon using artificial neural networks and multivariate regression techniques
Karla Patricia Oliveira-Esquerre Aline C. da Costa Roy Edward Bruns Milton Mori 《Applied biochemistry and biotechnology》2003,106(1-3):437-449
The aim of this study was to develop an empirical model that provides accurate predictions of the biochemical oxygen demand
of the output stream from the aerated lagoon at International Paper of Brazil, one of the major pulp and paper plants in Brazil.
Predictive models were calculated from functional link neural networks (FLNNs), multiple linear regression, principal components
regression, and partial least-squares regression (PLSR). Improvement in FLNN modeling capability was observed when the data
were preprocessed using the PLSR technique. PLSR also proved to be a powerful linear regression technique for this problem,
which presents operational data limitations. 相似文献
63.
Ritei Shibata 《Annals of the Institute of Statistical Mathematics》1986,38(1):459-474
Summary A generalized Final Prediction Error (FPEα)_ criterion is considered. Based onn observations, the numberk of regression variables is selected from a given range 0≦k≦K, so as to minimize
. It is shown that if α tends to infinity withn, the selection is consistent but the maximum of the mean squared error of estimates of parameters diverges to infinity with
the same order of divergence as that of α. A meaningful minimax choice of α exists for a regret type mean squared error, while
for simple mean squared error it is trivially 0. The minimax regret choice of α converges to a constant, approximately 3.5
forK≧8 ifn−K increases simultaneously withn, otherwise it diverges to infinity withn. 相似文献
64.
There are many organic pollutants in the environment, such as polychlorinated biphenyl, polycyclic aromatic hydrocarbons, dichlorodiphenyl-trichloroethane (DDT), and polychlorinated naphthalene. These organic pollutants are persistent,liposoluble and easily cumulated in organism; consequently, the potential toxicity will be high. Risk assessment of industrial chemicals is currently carried out using scanty experimental data, because many of these chemicals have very little or no test data. S… 相似文献
65.
Changeable size moving window partial least squares (CSMWPLS) and searching combination moving window partial least squares (SCMWPLS) are proposed to search for an optimized spectral interval and an optimized combination of spectral regions from informative regions obtained by a previously proposed spectral interval selection method, moving window partial least squares (MWPLSR) [Anal. Chem. 74 (2002) 3555]. The utilization of informative regions aims to construct better PLS models than those based on the whole spectral points. The purpose of CSMWPLS and SCMWPLS is to optimize the informative regions and their combination to further improve the prediction ability of the PLS models. The results of their application to an open-path (OP)/FT-IR spectra data set show that the proposed methods, especially SCMWPLS can find out an optimized combination, with which one can improve, often significantly, the performance of the corresponding PLS model, in terms of low prediction error, root mean square error of prediction (RMSEP) with the reasonable latent variable (LVs) number, comparing with the results obtained using whole spectra or direct combination of informative regions for a compound. Regions consisting of the combinations obtained can easily be explained by the existence of IR absorption bands in those spectral regions. 相似文献
66.
多组分体系同时定性定量测定的逐步回归分析法 总被引:2,自引:0,他引:2
阐述了逐步回归分析法用于多组分体系同时定性定量分析的原理、实验及数据处理方法。分析了硝基酚类人工样、未知样及合成样。该法可用于仅知可能含有的组分范围的样品分析。 相似文献
67.
As an adjunct to the regression analysis of differential capacitance curves, which allows refining the adsorption parameters, a program, which takes into account possible errors in volume concentrations of organic substances, is developed. Using this procedure, the earlier data on the differential capacitance of a mercury electrode in aqueous solutions of normal butanol (1-BuOH) containing either 0.1 M NaF or 0.05 and 0.5 M Na2SO4 as the supporting electrolyte are analyzed. This allows obtaining the most accurate values of adsorption parameters for the systems mentioned above within the framework of the model of two parallel capacitors and the Frumkin isotherm. It is shown that, when a linear dependence of the intermolecular interaction parameter on the electrode potential is taken into account, the standard deviation of experimental capacitance values from those calculated using the mentioned model is 6.8–8.8%, which points to very high accuracy of this phenomenological model. 相似文献
68.
The adsorption of complexes formed by sodium, potassium, and rubidium cations with macrobicyclic ligand (kryptofix 222 with C18H36N2O6 composition) is studied as a function of the ligand concentration on a stationary mercury drop in 0.1 M solutions of corresponding sulfates and chlorides by using the differential capacitance technique. Based on the model of two parallel capacitors supplemented by the Frumkin isotherm, the adsorption parameters of studied cryptates are estimated by using the regression analysis technique. Differential capacitance curves calculated with the parameters found are compared with experimental data. The comparison of the found adsorption parameters makes it possible to reveal the effects of the nature of included cations and specifically adsorbed supporting-electrolyte anions on the adsorption behavior of cryptates under study.__________Translated from Elektrokhimiya, Vol. 41, No. 4, 2005, pp. 475–481.Original Russian Text Copyright © 2005 by Stenina, Sviridova. 相似文献
69.
Simultaneous measurement of glucose and glutamine in aqueous solutions by near infrared spectroscopy 总被引:1,自引:0,他引:1
Hoeil Chung Mark A. Arnold Martin Rhiel David W. Murhammer 《Applied biochemistry and biotechnology》1995,50(2):109-125
A method is described for measuring the concentrations of both glucose and glutamine in binary mixtures from near infrared
(NIR) absorption spectra. Spectra are collected over the range from 5000–4000/cm (2.0–2.5μm) with a 1-mm optical path length.
Glucose absorbance features at 4710, 4400, and 4300/cm and glutamine features at 4700, 4580, and 4390/cm provide the analytical
information required for the measurement. Multivariate calibration models are generated by using partial least squares (PLS)
regression alone and PLS regression combined with a preprocessing digital Fourier filtering step. The ideal number of PLS
factors and spectral range are identified separately for each analyte. In addition, the optimum Fourier filter parameters
are established for both compounds. The best overall analytical performance is obtained by combining Fourier filtering and
PLS regression. Glucose measurements are established over the concentration range from 1.66–59.91 mM, with a standard error of prediction (SEP) of 0.32 mM and a mean percent error of 1.84%. Glutamine can be measured over the
concentration range from 1.10–30.65 mM with a SEP of 0.75 mM and a mean percent error of 6.67%. These results demonstrate
the analytical utility of NIR spectroscopy for monitoring glucose and glutamine levels in mammalian and insect cell cultures. 相似文献
70.
B. B. Damaskin 《Russian Journal of Electrochemistry》2006,42(9):990-994
Based on the results of the regression analysis of differential capacitance curves of a mercury electrode in solutions of cyclobutane carboxylic acid (CBCA) at 25, 50, and 75°C, the adsorption parameters that enter into both the Frumkin isotherm and the model of two parallel capacitors are estimated. The free energies of adsorption found from the analysis of the temperature dependence of these parameters are incorrect due to the partial blowing out of CBCA during the deaeration of the solutions. The corresponding adsorption parameters are corrected under the assumption that the hydrophobic effect associated with the increase in the liquid-water entropy at the removal from it of CBCA molecules is the same as for n-valeric acid. The physical meaning of the squeezing-out effect is revised. 相似文献