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91.
92.
Synthesis of new fluorinated tertiary malonamides (F-malonamides) was accomplished, and their liquid/liquid (L/L) extraction properties with f-elements were investigated. These molecules are fluorinated analogues of well known extractants used in several processes designed towards the treatment of nuclear wastes, and the efficient separation of lanthanides from minor actinides; however, the synthesis of F-malonamides deserved a modification of the general synthetic route commonly employed to prepare H-malonamides. Extraction of neodymium from various aqueous media into both fluorous and classical solvents was studied, which revealed an opposite trend between F-malonamides and H-malonamides: L/L extraction ability is very sensitive to the nitrogen atoms substitution pattern, and the most efficient F-malonamide is compound 3 (R1 = Me), whereas the best H-malonamide is compound 5 (R1 = Bu, DMDBTDMA). 相似文献
93.
《Arabian Journal of Chemistry》2014,7(3):312-318
The oxidation of some aliphatic alcohols by triethylammonium chlorochromate (TriEACC) in dimethyl sulfoxide leads to the formation of the corresponding carbonyl compounds. The reaction is first order with respect to TriEACC. The reaction exhibited Michaelis–Menten type kinetics with respect to alcohol. The reaction is catalyzed by hydrogen ions. The hydrogen-ion dependence has the form: kobs = a + b[H+]. The oxidation of [1,1-2H2] ethanol (MeCD2OH) exhibits a substantial primary kinetic isotope effect. Oxidation of aliphatic alcohol was studied in 19 different organic solvents. The solvent effect has been analysed using Kamlet’s and Swain’s multi-parametric equation. A suitable mechanism has been proposed. 相似文献
94.
《Arabian Journal of Chemistry》2022,15(2):103586
A series of metal ion complexes was prepared in solid state from Cu(II), Hg(II) and UO2(II) ions with 3-oxo-3-(2-(2-oxoindolin-3-ylidene)hydrazineyl)-N-phenylpropanamide (H3L) ligand through solvent free synthesis methodology. The chemical formulae of the new compounds were estimated according to variable spectral and analytical investigations. The ligand exhibited a neutral or mononegative tetradentate mode of coordination towards the central ions inside the octahedral arrangement that proposed for the three complexes. The DFT/B3LYP method was applied under different basis sets (6-31G*or SDD) to optimize the structures of new compounds except the UO2(II) complex. The computational data were investigated to verify the binding mode that suggested spectrally. Moreover, studies in solution regarding Cu(II) ion via cyclic voltammetry were performed in absence or presence of H3L, to realize the significant effect of complex formation on the electrochemical manners of copper. The shifts in the potential peaks accompanied by the changes in the values of parameters correspond to kinetic and thermodynamic. Also, the solvation and kinetic characteristics for the cathodic and anodic potential of Cu(II) ion in absence or presence of H3L at different scan rates, were estimated. Finally, the ligand and copper ion exhibited high affinity towards complexation in solution. Furthermore, the activity of the new compounds towards inhibiting microbes was studied against Staphylococcus aureus (G+) and Escherichia coli (G-) bacteria as well as Candida albicans (fungus) by determining the inhibition zone diameter. Also, both the antioxidant and cytotoxic activity of the isolated compounds were evaluated. Commonly, a remarkable antimicrobial and anticancer activity was appeared with UO2(II) complex and the ligand. While, the antioxidant activity of all compounds appeared lower. 相似文献
95.
《Arabian Journal of Chemistry》2022,15(6):103852
A simple and easily scalable “wet” procedure was used to prepare nanocrystalline cerium oxide capable of destroying the toxic organophosphate pesticide parathion methyl. The synthetic procedure consists of the direct precipitation of cerous salt with aqueous ammonia in the absence of CO2. The prepared cerium oxide was able to decompose the organophosphate compounds both in nonpolar (e.g., heptane) and polar aprotic (e.g., acetonitrile) solvents. However, in solvents with hydrogen-bond donating ability, the –OH groups on the cerium oxide surface were solvated and inactivated. The preferential solvation model was used to express the experimental dependencies of the cerium oxide degradation efficiency on the composition of the water-acetonitrile mixture. In certain solvent systems, some empirical polarity scales, such as the alpha-scale or the Dimrodth-Richardt parameter ET(30), may be correlated with the degradation efficiency of cerium oxide. 相似文献
96.
以邻苯二胺、 2,5-二氨基苯磺酸和三氯化铝为原料, 通过无溶剂法大量制备了高效的红色荧光碳点 (R-CDs). 制得的碳点尺寸大约为2.4 nm, 含有13%的氮元素, 主要由高度石墨化的碳核及覆盖在其表面的大量官能团构成. 在不同的波长光激发下, 碳点在乙醇溶液中表现出不依赖于激发的红光发射, 其荧光峰位于 704 nm, 最大量子产率达到22%. 由于R-CDs具有优异的光学性质, 利用其构筑了紫外光激发的碳基白色发光二极管, 其色坐标为(0.33, 0.33), 非常接近自然光. 该研究为高效红色荧光碳点的大量制备提供了一种新路径, 同时拓宽了其在白光器件中的应用. 相似文献
97.
The evolution of amorphous calcium carbonate (ACC) into crystals in ethanol/water binary solvents under ambient temperature was investigated, and it was found to depend on the volume ratio of ethanol to water (R). Calcite remained dominant when the amount of water was high (R = 1/3). A slight change in the amount of ethanol (R = 3/1) could lead to a dramatic change in the polymorph from calcite to aragonite. However, when poly (allylamine hydrochloride) (PAH) was added at R = 3/1, almost pure vaterite could be obtained, which has a specific morphological variation (from hollow microspheres to cloud‐like). This study provides an alternative polymorphic route for the CaCO3 mineral by using the evolution of ACC in different solvent environments, which provides some useful clues for understanding the importance of kinetic control of the morphologies and polymorphs of a wide range of inorganic materials. In addition, this simple mild phase‐controlled synthetic method could be scaled up as a green chemistry route for the industrial production of different polymorphs of CaCO3. 相似文献
98.
Maciej Jan Rybicki Anna Klimek-Turek Tadeusz Henryk Dzido 《Molecules (Basel, Switzerland)》2020,25(24)
Coccidiostats are drugs used against coccidiosis, a common disease among breeding animals. Their widespread application leads to the appearance of their residues in food, which is potentially harmful for human health and life. The European Union has established limits of concentrations of these drugs in premixtures and food. Nowadays, there are many methods for monitoring coccidiostats’ presence in market products, but their frequent weakness is sample preparation. Solvent Front Position Extraction is a planar chromatography-based sample preparation method that allows for effective assay of samples with coccidiostats when coupled with LC-MS/MS. The purpose of this research was to find common conditions for the effective isolation of eight coccidiostats from biological sample components with both lower and higher retention than the substances of interest. The acquired results were used for effective isolation of monensin and salinomycin from the premixture samples and allowed for their quantitative determination. The application of a semi-automatic device for the development of chromatograms positively impacted the results, confirming the effectiveness of the method for determining coccidiostats in biological samples. 相似文献
99.
《Particuology》2022
An innovative application of the solvent evaporation technique was suggested. Solvent evaporation technique is a technique for drug encapsulation and nanosphere preparation. The widely used technique is also facing the problem of low actual drug entrapment percent, which is not economic from the industrial view. The goal of this work is trying to use the advantage of this technique concerning the product sphericity and the ability to control particle size, to prepare a drug as pure crystals spheres. Ibuprofen is selected as a model drug. The spheres are formed by using Polyvinyl pyrrolidone (PVP) or Polyethylene glycol (PEG) as an anti-aggregating agent but not formed on using tween or span. Particle size and actual drug content depend on the concentrations the anti-aggregating agent used. Surfaces of the drug crystal spheres are porous with empty sphere internal structure on using PVP but spongy and rough on using PEG. The drug has its identity chemical form in the drug crystal spheres. IR scan of spheres prepared on using PEG showed a characteristic ether peak. DSC showed melting endothermic peak of PEG, but X-ray showed minor change in the drug crystal patterns. Drug release profiles from crystal spheres prepared with the same anti-aggregating agent are close to each other. The drug release profiles from drug crystal spheres prepared by using PEG are more controlled than that prepared by using PVP. The drug release mechanism is diffusion. It was concluded that, the same technique could be suggested for preparation of other biomedical material in pure crystals spheres with controlled particle size. These properties may encourage to prepare very small particles with spherical shape for inhalation or injection as an innovative particle technology application for the widely used technique. 相似文献
100.
依据SMM-601型超导量子干涉显微镜检测部分构建计算模型,采用电磁场有限元方法分析了残余应力引起的非磁性金属材料铍电导率变化对超导量子干涉仪(SQUID)检测信号的影响,并讨论了该方法实际应用于非磁性金属材料残余应力检测的条件和可能性。 相似文献