Modelling of stresses and strains in bonded concrete overlays subjected to differential volume changes

The differential volume changes between repair material and substrate concrete induces stresses in concrete overlays. These stresses could cause the repair material cracking or the interface delamination, which facilitate the penetration of harmful substances into concrete and hence accelerate the deterioration of concrete overlays. In order to investigate the characteristics of these stresses, an analytical model has been developed based on the plate theory and the assumption of the linear relation between shear stress and slip at the interface. This model is able to calculate the tensile stress in the repair material, shear and normal stresses at the interface and the corresponding strains. With this model, the influence of the interface shear stiffness, the dimension of the concrete overlay, and the elastic moduli of two materials on stresses and strains was studied.     

Studies on Monodispersed Microspheres of Zinc Sulfide Doped with Mn^2＋

In this paper,zinc acetate,manganese acetate and thiacetamide are used as raw materials to successfully synthesize monodispersed ZnS:Mn2+ microspheres by using hydrothermal method and taking P123 surfactant as a template. The products were characterized by XRD,STEM,FT-IR and N2 adsorption-desorption. And the results show that the diameter of this microsphere is 1.0 μm or so,which is larger than that of ZnS microsphere without Mn2+ doping,and it has monodispersion,smooth surface and uniform size. The doping of Mn2+ does not obviously change the structure of monodispersed ZnS microsphere. The photoluminescence peak lies in a wide band ranging from 450 to 650 nm,and the microspheres emit orange light; with the increase of Mn2+ concentration,fluorescence intensity of ZnS:Mn2+ microsphere changes,and when the mole ratio of Mn2+:Zn2+ is 0.3:1,the fluorescence intensity is the strongest.     

Studies on the sonochemical polymorphism of Sb2O3 on activated graphite for the electrochemical determination of imipramine

This work reports the simultaneous sonochemical activation of graphite and sonohydrolysis of antimony chloride (SbCl₃) in the alkaline medium. The experiments conducted by bath sonicator operated at 37 kHz of frequency and a maximum power of 150 W. The simple sonohydrolysis of SbCl₃ alone produced an orthorhombic phase of Sb₂O₃, whereas, it produced mixed phases of cubic and orthorhombic Sb₂O₃ when introduced with graphite. Herein, the activated graphite (aGR) provides the best support to the growth of cubic phase. This cubic Sb₂O₃ is grown only on the graphite basal planes, which confirmed by scanning electron microscope. Moreover, the phase changes have identified by the X-ray diffraction, Raman and X-ray photoelectron analysis. The prepared aGR-Sb₂O₃ composite has applied to the electroanalytical studies of anti-depressant drug imipramine (IMP). The results showed that aGR-Sb₂O₃ revealed better activity than Sb₂O₃; the reasons are discussed comprehensively. Furthermore, aGR-Sb₂O₃ exhibited comparable analytical results for the determination of IMP.     

The phenomenon of nucleon emission at high angular momentum states of fused compound systems

Nucleon emission from high spin fused compound systems is analyzed in the framework of the statistical theory of hot rotating (STHR) nuclei. This is an elaborate version of our earlier work and we present our results for¹⁵⁶Er,¹⁶⁶Er,¹⁶⁸ Yb and¹⁸⁸Hg. We predict an increase in neutron emission for¹⁶⁶Er due to the abrupt decrease in neutron separation energy aroundI ≈55ℏ. Since the drop in the separation energy is closely associated with the structural changes in the rotating nuclei, relative increase in neutron emission probability around certain values of angular momentum may be construed as evidence for the shape transition. A similar effect is predicted for¹⁶⁸Yb aroundI ≈55ℏ. We also extend the microscopic cranked Nilsson method (CNM) to hot nuclear systems and compare the results with that of the STHR method. The two methods yield different results for triaxially deformed nuclei although for biaxial deformations the results are identical. This is illustrated for¹⁸⁶Hg.     

Spectral changes of diffracted polychromatic Gaussian beams in the far field

The spectral behavior of polychromatic spatially fully coherent Gaussian beams diffracted at an aperture in the far field is studied based on the propagation law of the cross-spectral density function. Detailed numerical calculation results are presented, and illustrated. It is shown that the spectral changes take place in the vicinity of zeros of the Airy pattern, and the spectral modifier depends on the truncation parameter δ and diffraction angle α. The critical diffraction angle α_c, at which the spectrum is split into two lines with equal height i.e., the spectral switch appears, varies with truncation parameter δ. The spectral switch vanishes if δ becomes large enough. A detailed comparison with the previous publications is given, showing somewhat extension made in our work.     

Analysis of Long-Term Optical Effects in Double-Coated Optical Fibers Induced by Hydrostatic Pressure and Thermal Loading

The hydrostatic pressure and thermal loading simultaneously induced optical effects in double-coated optical fibers in the long-term are analyzed by the viscoelastic theory. Using the Laplace transformation method, close-form solutions for the microbending loss and refractive index changes are obtained. The results of the microbending loss are initially identical to those obtained by the elastic analysis, and then decrease gradually as time progresses. The microbending loss and refractive index changes of the glass fiber are functions of the material properties of the primary and secondary coatings. To minimize the microbending loss and refractive index changes in the long-term, the Young's modulus of the primary coating, and the viscosity and Poisson's ratio of the secondary coating should be increased. Nevertheless, the viscosity and Poisson's ratio of the primary coating, and the Young's modulus of the secondary coating should be decreased.     

Volume and compressibility effects in the formation of metal-EDTA complexes

We used precise measurements of ultrasonic velocity and density to study the complexation of ethylendiaminetetraacetic acid (EDTA) with Mg²⁺, Ca²⁺, Sr²⁺, and Ba²⁺ at 25‡C and pH 12. From these measurements we obtained the changes in the molar concentration increment of the ultrasonic velocity δA, the apparent molar adiabatic compressibility δK_sΦ, and the apparent molar volume δV_Φ of complex formation. The hydration contributions δ(AV_h) to the volume effect of binding range from 39.6 to 46.6 cm³-mol^-1 while the hydration contribution to the adiabatic compressibility change in the binding, δ(δK_h), ranges from 103.9X 10^-4 to 131.1 X 10^-4 cm³-mol^-1-bar^-1. These data are interpreted in terms of dehydration of interacting molecules,i.e., transfer of water molecules from the hydration shells of cations and EDTA into the bulk water. The ratio δ(δV_h)/ δ(δV_h) is in the range 0.35 to 0.38 bar, indicating a dominant contribution from the dehydration of charged atomic groups in the volume and the compressibility effects of complex formation.     

Dramatic selectivity changes on carrier gas flow change in a series-coupled GC capillary tandem

We describe the polarity of selectivity of a GC separation system in terms of Retention Index data. In a series-coupled capillary system having stationary phases of differing polarity even slight (independent!) carrier gas flow changes in one part of the capillary series result in a dramatic change of selectivity. “Dramatic” is a relative term! Using a simple electronically controlled flow changing device we found retention index changes of several hundred units for polar test compounds such as phenols on a SE30/Carbowax tandem. This means: The classical theoretical model for understanding retention (and selectivity) in chromatography must be corrected. We propose a very simple approach involving addition of the expression RESIDENCE TIME to the chromatographic vocabulary. Instead of using flow resistors, one can just add a pressure regulator to the coupling point. A powerful analytical concept is now in easy reach.     

Molecular dynamics simulation study on zwitterionic structure to maintain the normal conformations of Glutathione

Molecular dynamics simulations were applied to normal conformational Glutathione (GSH) and GSH over zwitterionic and hydrophobic surfaces respectively. Conformational analysis of GSH during the simulation time on RMSD, conformational flexibility and dihedral distribution were performed. The re- sults showed that zwitterionic structure maintains the normal conformations of GSH to a better extent, which should be a first good proof of the hypothesis of "maintain of normal structure".