Improved versions of Tardos’ fingerprinting scheme

We study the Tardos’ probabilistic fingerprinting scheme and show that its codeword length may be shortened by a factor of approximately 4. We achieve this by retracing Tardos’ analysis of the scheme and extracting from it all constants that were arbitrarily selected. We replace those constants with parameters and derive a set of inequalities that those parameters must satisfy so that the desired security properties of the scheme still hold. Then we look for a solution of those inequalities in which the parameter that governs the codeword length is minimal. A further reduction in the codeword length is achieved by decoupling the error probability of falsely accusing innocent users from the error probability of missing all colluding pirates. Finally, we simulate the Tardos scheme and show that, in practice, one may use codewords that are shorter than those in the original Tardos scheme by a factor of at least 16.      

The Trifluoromethyl Anion: Evidence for [K(crypt‐222)]+

[K(crypt‐222)]⁺ ( 1 ) and [K(crypt‐222)]⁺ ( 3 ) are isostructural, displaying nearly identical unit cell parameters. The two structures are similar to the extent that the previously reported [K(crypt‐222)]⁺ model can be refined against the new data for [K(crypt‐222)]⁺ , with extra electron density being observed from the fourth fluorine atom of the . In agreement with experimental observations, theoretical calculations suggest that deprotonated [K(crypt‐222)]⁺ is highly unstable even at as low as 195 K. The previously considered 1:1 CHF ₃ clathrate of deprotonated [K(crypt‐222)]⁺ (crystallographically indistinguishable from 1 ) is ruled out on the basis of all available data.     

A Novel and Efficient One‐Pot Synthesis of 2‐Aminopyrimidinones and Their Self‐Assembly

A three‐component reaction of benzaldehyde derivatives, methyl cyanoacetate, and guanidinium carbonate affords 2‐amino‐4‐aryl‐1,6‐dihydro‐6‐oxopyrimidine‐5‐carbonitriles and the four‐component reaction of benzaldehyde derivatives, methyl cyanoacetate, and guanidinium hydrochloride in the presence of piperidine leads to piperidinium salts of pyrimidinones. X‐ray crystallography data confirm self‐assembly and H‐bonding in these compounds.     

Monoterpenoids from the Fruit of Gardenia jasminoides

Eight new monoterpenoids, jasminoside J ( 1 ), jasminoside K ( 2 ), 6′‐O‐trans‐sinapoyljasminoside B ( 3 ), 6′‐O‐trans‐sinapoyljasminoside L ( 4 ), jasminosides M–P ( 5 – 8 ), together with three known analogues, jasminoside C ( 9 ), jasminol E ( 10 ), and sacranoside B ( 11 ), were isolated from the fruit of Gardenia jasminoides Ellis (Rubiaceae). Their structures were elucidated by spectral and chemical methods.     

Tri‐ and Tetrasubstituted N‐Phthalimidoaziridines in 1,3‐Dipolar Cycloaddition Reactions

The thermal reactions of the 2,2,3‐trisubstituted N‐phthalimidoaziridine 1a with dimethyl acetylenedicarboxylate (DMAD), thioketones 4a – 4d , and dimethyl azodicarboxylate ( 5 ) proceed even at room temperature leading to the five‐membered cycloadducts 2a, 6 – 8 , and 12 , respectively, with retention of the spatial arrangement of the aziridine substituents, in contrast to the expectation based on the conservation of orbital symmetry in concerted reactions. The analogous reactions of the tetrasubstituted phthalimidoaziridine 1b with thioketones at 40° lead to the 1,3‐thiazolidine derivatives 10 and 11 as mixtures of diastereoisomers. These unexpected results may be explained by either the isomerization of the intermediate azomethine ylides or a non‐concerted stepwise cycloaddition reaction of these ylides with the dipolarophiles. The structures of some adducts have been determined by X‐ray crystallography.     

Curved ray tracing method for one-dimensional radiative transfer in the linear-anisotropic scattering medium with graded index

The curved ray tracing method (CRT) is extended to radiative transfer in the linear-anisotropic scattering medium with graded index from non-scattering medium. In this paper, the CRT is presented to solve one-dimensional radiative transfer in the linear-anisotropic scattering gray medium with a linear refractive index and two black boundaries. The predicted temperature distributions and radiative heat flux at radiative equilibrium are determined by the proposed method, and numerical results are compared with the data in references. The results show that the CRT has a good accuracy for radiative transfer in the linear-anisotropic scattering medium with graded index and the dimensionless emissive power and dimensionless radiative heat flux depend on the dimensionless refractive index gradient. It can also be seen that the dimensionless refractive index gradient has important effects on the temperature discontinuity at the boundaries.     

Building Functionality into 4′‐Hydrazone Derivatives of 2,2′: 6′,2″‐Terpyridine

The syntheses of the five 2,2′: 6′,2″‐terpyridine (tpy) ligands 5 – 9 functionalized in the 4′‐position with a hydrazone substituent RR′C?N? NH (R=R′=Me; R=H, R′=4‐BrC₆H₄, 4‐O₂NC₆H₄, 4‐MeOC₆H₄, or 3,5‐(MeO)₂C₆H₃) are described. Protonation of the tpy domain of the ligands is facile. Solution behaviour has been studied by NMR and electronic spectroscopies. Representative structural data are presented for neutral and monoprotonated ligands, and illustrate that H‐bonding involving the formal amine NH unit is a dominant structural motif in all cases.     

THGEM探测器X光斑寻迹和位置分辨实验研究

介绍了一种基于THGEM的X射线光斑寻迹探测器,用于X射线单光子计量技术研究和测量,探测器有效面积200 mm×200 mm,采用128路基于ASIC和FPGA的高速读出电子学,探测器分为中间高分辨区和外围低分辨区两部分,两部分共用一套读出电子学。实验在中国计量科学研究院利用X光机产生的束线,测试光斑位置、光斑精细分布以及探测器的位置分辨。实验结果表明,探测器实现了同时对光斑寻迹和光斑的精细测量,探测器中间高分辨区x方向的位置分辨率为0.63 mm（FWHM）,y方向位置分辨率为0.62mm（FWHM）,探测器各项性能指标均达到了预期目标。This paper introduces the detector of X-ray spot tracing based on the THGEM. It is used for X ray single photon measurement technology research and measurement with an effective area of 200 mm×200 mm. The circuit board has 128 array of high speed readout electronics based on ASIC and FPGA. And it is divided into two parts:the middle area of high sensitive and the peripheral area of low sensitive. The two parts share a set of readout electronics. The experiment tests the position and the fine structure of the beam line produced by X ray machine in National Institute of Metrology. The results of the experimental show that the detector realizes both the spot tracing and the fine structure of the spot. The position resolution is 0.63 mm in x direction and 0.62 mm in y direction in high sensitive of the detector, which achieve the desired goal of preliminary design.     

机械刻划光栅的光线追迹方法

为了评价光栅的光谱质量,完成所设计光栅的光线追迹,针对机械刻划光栅的光线追迹提出了一种改进方法.在费马原理的基础上利用光程函数法得到入射光通过光栅后的光谱分布情况,再使用传输矩阵的计算方法构造出光谱的点列图.该方法适用于刻划在平面、球面和非球面基坯上的等间距和变间距光栅,光栅的光谱面可以为平面或者二次曲面. 通过刻划在非球面基坯上的凹面光栅验证了光线追迹方法的可靠性.     

一维粗糙面散射的射线追踪法研究

在考虑遮蔽效应的情况下,应用射线追踪法对一维导体和介质的高斯粗糙面的散射系数进行了研究,并分别计算了考虑一次反射和二次反射的散射系数。同时,利用蒙特卡罗法生成一维高斯粗糙面,计算了考虑一次、二次反射和遮蔽时不同均方根斜率粗糙面的平均散射系数。