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931.
Samples with the nominal composition Nd2B5 contain strongly disordered crystals composed of nanosized (100) lamellae. Most commonly, a polysynthetic twinning based on a fourfold rotation separates the lamellae at coherent boundaries. The structure of the twin interface contains a pseudo fourfold arrangement of B atoms as derived from electron microscopy techniques. Such pseudo-symmetry serves for a rationalization of the twinning. Additionally, a chemical intergrowth of Nd2B5 and NdB4 lamellae based on related structural building units can be observed. Further HRTEM examinations allow the identification of a new structural variant of neodymium borides. 相似文献
932.
铕和铽与3,4-呋喃二甲酸双核配合物的合成、表征及其晶体结构 总被引:1,自引:0,他引:1
本文首次合成了铕(Ⅲ)和铽(Ⅲ)与3,4-呋喃二甲酸配合物,研究了它们的IR、DTA、TG、DTG和荧光光谱等性质,并完成了单晶的晶体分析。结果表明,配合物为〔Ln·HL_2(H_2O)_2〕_2·2H_2O(Ln=Eu(Ⅲ),Tb(Ⅲ);H_2L=3,4-呋喃二甲酸),属单斜晶系,P2/c空间群,Z=2,晶胞参数对铕和铽配合物分别为α=10.842(1),10.801(4);b=8.725(2),8.664(2);c=16.366(4),16.308(6)A;β=93.50(1),93.67(3)°;V=1545.3(5),1523.0(8)A~3。 相似文献
933.
934.
Nd2O3改性PbTiO3陶瓷性能的研究 总被引:6,自引:0,他引:6
通过添加少量的Nd2O3可以改善PbTiO3陶瓷的性能。这种性能的改善是与用Nd2O3改性的PbTiO3陶瓷的显微结构物导电机制密切相关的。本文研究了Nd2O3改性的PbTiO3陶瓷的性能参数。 相似文献
935.
Determination of rare earth elements by quadrupole based inductively coupled plasma mass spectrometry (ICP-QMS) shows several spectroscopic overlaps from M+, MO+ and MOH+ ions. Especially, the spectroscopic interferences are observed from the atomic and molecular species of lighter rare earth elements including Ba during the determination of Eu, Gd and Tb. Mathematical correction methods, knowing the at.% abundances of different interfering isotopes, and the extent of formation of molecular species determined experimentally, have been used to account for various spectroscopic interferences. However, the uncertainty propagated through the mathematical correction limits its applicability. The uncertainty propagation increases with the increase in contribution from interfering species. However, for the same extent of total contribution, the overall error decreases when the interfering species are more than one. In this work, chondrite as well as a few geological reference materials containing different proportions of various rare earth elements have been used to study the contributions of different interfering species and the corresponding uncertainty in determining the concentrations of rare earth elements. A number of high abundant isotopes are proposed for determining the concentrations of various rare earth elements. The proposed isotopes are tested experimentally for determining the concentrations of different rare earth elements in two USGS reference materials AGV-1 and G-2. The interferences over those isotopes are corrected mathematically and the uncertainties propagated due to correction methodology are determined for those isotopes. The uncertainties in the determined concentrations of rare earth elements due to interference correction using the proposed isotopes are found to be comparable with those obtained by the commonly used isotopes for various rare earth elements. 相似文献
936.
A preconcentration method for trace amounts of rare earth elements (REs) based on the substoichiometric precipitation of calcium oxalate was developed. RE(III) was quantitatively coprecipitated with calcium oxalate which had been precipitated from the calcium of a macrocomponent in a biological sample by addition of a substoichiometric amount of oxalate. In this way high selectivity for RE(III) from other elements was achieved. The method was applied to the neutron activation analysis of a biological sample (NBS SRM 1572 Citrus Leaves), and Sc, La, Ce, Pf, Nd, Sm, Eu, Th, Dy, Ho, Yb and Lu were determined with a relative standard deviation of less than 5%. 相似文献
937.
铽锰基化合物TbMn6Sn6的结构和磁性 总被引:1,自引:0,他引:1
研究了重稀土金属化合物TbMn6Sn6的晶体结构、内禀磁性及其矫顽力随和外场变化的规律。TbMn6Sn6为HfFe6Ge6型六角型结构,晶格常数为:a=0.5561nm,c=0.90477nm,单胞体积为0.241nm^3,居里温度TC=421K。TMn6Sn6化合物在外场较弱时,热磁曲线呈亚铁磁性;当外场较强时,则表现出铁磁行为,具有变磁性,TbMn6Sn6的矫顽力随温度变化,当温度T=200K 相似文献
938.
稀土(Ⅲ)—三溴偶氮胂络合物极谱吸附波的研究 总被引:3,自引:0,他引:3
在PH9.0的氨水-氯化铵缓冲溶液中,稀土(Ⅲ)与三溴偶氮胂在-0.69V(vs.SCE)处产生一灵敏的极谱波,二次导数峰高与稀土浓度在3.O×10~(-8)~9.0×10~(-7)mol·L~(-1)范围内呈线性关系,检出限为2.O×10~(-8)mol·L~(-1).探讨了该极谱波的性质和电极反应机理.用此法测定了球墨铸铁中的稀土总量,结果满意. 相似文献
939.
超低硫微合金钢中稀土元素的作用 总被引:16,自引:14,他引:16
稀土在超低硫(S〈0.003%)铌钛微合金风中仍然有净化钢质、变质夹杂的作用。钢中CRE/CO+S控制在4左右,可获得最佳效果。超低硫钢中稀土固溶量可达到10^-5--10^-4数量级,显著减少晶界S、P的偏聚,推迟钢的动态再结晶,细化晶粒和沉淀相,促进铌钛碳氮化物析出。稀土在钢中还有微合化的作用。 相似文献
940.