Multidimensional Scaling With Very Large Datasets

Multidimensional scaling has a wide range of applications when observations are not continuous but it is possible to define a distance (or dissimilarity) among them. However, standard implementations are limited when analyzing very large datasets because they rely on eigendecomposition of the full distance matrix and require very long computing times and large quantities of memory. Here, a new approach is developed based on projection of the observations in a space defined by a subset of the full dataset. The method is easily implemented. A simulation study showed that its performance are satisfactory in different situations and can be run in a short time when the standard method takes a very long time or cannot be run because of memory requirements.     

CARTscans: A Tool for Visualizing Complex Models

We present CARTscans, a graphical tool that displays predicted values across a fourdimensional subspace. We show how these plots are useful for understanding the structure and relationships between variables in a wide variety of models, including (but not limited to) regression trees, ensembles of trees, and linear regressions with varying degrees of interactions. In addition, the common visualization framework allows diverse complex models to be visually compared in a way that illuminates the similarities and differences in the underlying methods, facilitates the choice of a particular model structure, and provides a useful check for implausible predictions of future observations in regions with little or no data.     

Random Variable Generation Using Concavity Properties of Transformed Densities

Abstract

Algorithms are developed for constructing random variable generators for families of densities. The generators depend on the concavity structure of a transformation of the density. The resulting algorithms are rejection algorithms and the methods of this article are concerned with constructing good rejection algorithms for general densities.     

Predicting USCS soil classification from soil property variables using Random Forest

Soil classification systems are widely used for quickly and easily summarizing soil properties and provide a shorthand method of communication between scientists, engineers, and end-users. Two of the most widely used soil classification systems are the United States Department of Agriculture (USDA) textural soil classification system and the Unified Soil Classification System (USCS). Unfortunately, not all soil map units are classified according to the USDA or USCS systems, and previous attempts to provide a crosswalk table have been inconsistent. Random Forest machine learning model was used to create a USCS prediction model using USDA soil property variables. Important variables for predicting USCS code from available soil properties were USDA soil textures, percent organic material, and available water storage. Prediction error rates less than 2% were achieved compared to error rates of approximately 40% using crosswalk methods.     

A note on random walks with absorbing barriers and sequential Monte Carlo methods

In this article, we consider importance sampling (IS) and sequential Monte Carlo (SMC) methods in the context of one-dimensional random walks with absorbing barriers. In particular, we develop a very precise variance analysis for several IS and SMC procedures. We take advantage of some explicit spectral formulae available for these models to derive sharp and explicit estimates; this provides stability properties of the associated normalized Feynman–Kac semigroups. Our analysis allows one to compare the variance of SMC and IS techniques for these models. The work in this article is one of the few to consider an in-depth analysis of an SMC method for a particular model-type as well as variance comparison of SMC algorithms.     

Semiclassical matrix model for quantum chaotic transport with time-reversal symmetry

We show that the semiclassical approach to chaotic quantum transport in the presence of time-reversal symmetry can be described by a matrix model. In other words, we construct a matrix integral whose perturbative expansion satisfies the semiclassical diagrammatic rules for the calculation of transport statistics. One of the virtues of this approach is that it leads very naturally to the semiclassical derivation of universal predictions from random matrix theory.     

Random Copolymers of 1,5-Dioxepan-2-one

ABSTRACT

Copolymers of 1,5-dioxepan-2-one (DXO) and e-caprolactone (?-CL), δ-valerolactone (δ-VL) or L-lactide (LLA) have been synthesized and characterized. High molecular weight copolymers were obtained using stannous-2-ethyl hexanoate as catalyst in bulk. Reactivity ratios for the copolymerization of DXO and δ-VL were determined at 110°C as r_VL=0.5 and r_DXO=2.3. At high conversion, depolymerization of δ-VL occurred, resulting in lower molecular weight and variations in the copolymer composition.

Physical properties, such as crystallinity and melting temperature of the DXO-copolymers proved to be strongly dependent on the choice of comonomer and on the molar composition of the copolymers. DXO appears to be incorporated into the poly-?-caprolactone (PCL) crystals and to some extent into the poly-δ-valerolactone (PVL) crystals, resulting in a more gradual decrease in crystallinity with increasing amount of DXO.     

H_6P_2W_（18）O_（62）á18H_2O： A green and reusable catalyst for one-pot synthesis of pyrano[4,3-b]pyrans in water

A convenient,effcient and environmentally benign procedure has been developed for the synthesis of pyrano[4,3-b]pyran derivatives via a one-pot,three-component reaction of 4-hydroxy-6-methylpyran-2-one,aldehydes and malononitrile in water using H6P2W18O62á18H2O as catalyst.Reusability of the catalyst and reaction media,short reaction times and easy isolation of products are some added advantages of the present methodology.     

Synthesis of Schiff's bases in aqueous medium: a green alternative approach with effective mass yield and high reaction rates

Abstract

Schiff's bases constitute a class of pharmaceutical and medicinally important molecules. The conventional methods for the synthesis of Schiff's bases require long reaction times and use of organic solvents. We report a novel and eco-friendly condensation reaction method permitting the “green synthesis” of various Schiff's bases by stirring 1,2-diaminobenzene with various aromatic aldehydes in water as solvent. This method is experimentally simple, clean, high yielding, green, and with reduced reaction times. The product is purified by simple filtration followed by washing with water and drying processes.