全文获取类型
收费全文 | 4636篇 |
免费 | 797篇 |
国内免费 | 341篇 |
专业分类
化学 | 979篇 |
晶体学 | 40篇 |
力学 | 313篇 |
综合类 | 21篇 |
数学 | 1395篇 |
物理学 | 3026篇 |
出版年
2024年 | 11篇 |
2023年 | 45篇 |
2022年 | 101篇 |
2021年 | 108篇 |
2020年 | 94篇 |
2019年 | 101篇 |
2018年 | 125篇 |
2017年 | 161篇 |
2016年 | 167篇 |
2015年 | 138篇 |
2014年 | 258篇 |
2013年 | 338篇 |
2012年 | 268篇 |
2011年 | 421篇 |
2010年 | 393篇 |
2009年 | 544篇 |
2008年 | 448篇 |
2007年 | 415篇 |
2006年 | 305篇 |
2005年 | 194篇 |
2004年 | 197篇 |
2003年 | 154篇 |
2002年 | 111篇 |
2001年 | 78篇 |
2000年 | 83篇 |
1999年 | 74篇 |
1998年 | 61篇 |
1997年 | 50篇 |
1996年 | 43篇 |
1995年 | 47篇 |
1994年 | 30篇 |
1993年 | 52篇 |
1992年 | 22篇 |
1991年 | 24篇 |
1990年 | 23篇 |
1989年 | 21篇 |
1988年 | 12篇 |
1987年 | 10篇 |
1986年 | 7篇 |
1985年 | 8篇 |
1984年 | 6篇 |
1983年 | 6篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1957年 | 1篇 |
排序方式: 共有5774条查询结果,搜索用时 15 毫秒
951.
针对二维球坐标系下中子输运方程的SN算法, 提出基于(单元, 方向)二元组的有向图模型, 在已有的基于有向图的并行流水线算法基础上, 设计粒度可控多级并行SN算法。其中, 采用区域分解和并行流水线相结合的方式挖掘空间-角度方向的并行度, 提出能群流水并行方法, 并通过设置合适的流水线粒度来平衡有向图调度、通信和空闲等待开销。实验结果表明: 该算法可以有效地求解二维球坐标系下的中子输运方程。在某国产并行机1920核上, 对于96万网格、60个方向、24能群、数十亿自由度的典型中子输运问题, 获得了71%的并行效率。 相似文献
952.
水下偏振成像技术是目前水下成像研究的热点,由于自然光在水中衰减大,水下成像系统多采用主动照明方式。针对分焦平面偏振成像系统中偏振照明光源与偏振探测像元偏振方向不匹配引起采集图像偏振信息存在的偏差,进而影响目标图像增强质量的问题,提出了一种分焦平面偏振成像系统光源标定方法。阐述了偏振光源的标定原理,然后给出偏振光源标定的实施步骤,最后采用偏振去雾算法和图像质量评价方法对标定前后的水下目标图像进行了图像增强和图像质量评价。评价结果表明,标定后的增强图像质量优于未标定的增强图像质量,平均梯度最大提升了2.48倍。该标定方法简单有效,实用性强,适用于分焦平面偏振成像系统偏振光源标定。 相似文献
953.
顶空固相微萃取-气相色谱-质谱法同时测定饮用水源水中24种VOCs 总被引:1,自引:0,他引:1
建立了同时测定饮用水源水中24种挥发性有机物(VOCs)的顶空固相微萃取-气相色谱-质谱法.用75 μm CarboxenTM-Polydimethylsiloxane(CAR-PDMS)固相微萃取柱顶空萃取水样中的VOCs,VOCs用气相色谱-质谱联用仪检测,采用内标法定量.对萃取柱涂层、样品盐度、萃取温度和萃取时间等样品前处理条件进行了优化,VOCs的检出限在0.03~0.31 μg/L之间,线性相关系数r>0.996(二氯甲烷和三氯甲烷除外).对饮用水源水实际水样0.50μg/L和1.00 μg/L两个加标浓度水平的回收率进行了测定,三氯甲烷回收率均值分别为104%和142%,其余VOCs回收率分别为90.0%~120%和88.0%~110%,除二氯甲烷和三氯甲烷外,其余VOCs测定结果的相对标准偏差均小于15.0%(n=6).该方法适用于饮用水源水中挥发性有机物的监测分析. 相似文献
954.
Dr. Gesine Schmidt Dr. Christoph Timm Dr. Achim Grube Dr. Christian A. Volk Priv.‐Doz. Dr. Matthias Köck 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(26):8180-8189
Four new 3‐alkyl pyridinium alkaloids, the viscosalines B1 ( 1 a ), B2 ( 1 b ), E1 ( 2 a ), and E2 ( 2 b ), were isolated from the Arctic sponge Haliclona viscosa. The structure elucidation of these isomeric compounds was challenging due to ambiguous fragments that derive during “standard” mass spectrometric fragmentation experiments. The final structure elucidation relied on the use of a combination of synthesis, liquid chromatography, and mass spectrometry. Three different mass spectrometers were used to differentiate between the synthetic structural isomers: a time‐of‐flight (TOF) mass spectrometer and two ion‐trap mass spectrometers with different ion‐transfer technologies (i.e., skimmer versus funnel optics). Although at first none of the spectrometers returned spectra that permitted structure elucidation, all three mass spectrometers provided analysis that successfully differentiated between the isomers after thorough method optimization. The use of in‐source collision‐induced dissociation (CID) with the ion trap and TOF instrument returned the most interesting results. The mode of fragmentation of the viscosalines under different experimental conditions is described herein. After successful optimization of the mass spectrometric method applied, the chromatographic method was improved to distinguish the previously inseparable isomers. Finally, both the liquid chromatography and mass spectrometric methods were applied to the natural products and the results compared to those from the synthetic compounds. 相似文献
955.
Mohamed Mahmoud Nasef Ezzatollah ShamsaeiPayman Ghassemi Amgad Ahmed AlyAbdul Hamid Yahaya 《Radiation Physics and Chemistry》2012,81(4):437-444
The radiation induced grafting of 4-vinylpyridine (4-VP) onto poly(ethylene-co-tetrafluoroethene) (ETFE) was optimized using the Box-Behnken factorial design available in the response surface method (RSM). The optimized grafting parameters; absorbed dose, monomer concentration, grafting time and reaction temperature were varied in four levels to quantify their effect on the grafting yield (GY). The validity of the statistical model was supported by the small deviation between the predicted (GY=61%) and experimental (GY=57%) values. The optimum conditions for enhancing GY were determined at the following values: monomer concentration of 48 vol%, absorbed dose of 64 kGy, reaction time of 4 h and temperature of 68 °C. A comparison was made between the optimization model developed for the present grafting system and that for grafting of 1-vinylimidazole (1-VIm) onto ETFE to confirm the validly and reliability of the Box-Behnken for the optimization of various radiation induced grafting reactions. Fourier transform infrared (FTIR), thermogravimetric analysis (TGA) and X-ray diffraction (XRD) were used to investigate the properties of the obtained films and provide evidence for grafting. 相似文献
956.
This research paper reports about the change in optical spectra of alkali aluminoborate glasses under high dose of gamma irradiation. Effect of irradiation on visible spectra finds remarkable applications in optoelectronic materials.Glasses with a host matrix composed of M2O (where M=Na, K), Al2O3, B2O3 were prepared by conventional melt quench technique. Gamma irradiation was performed at a dose-rate of 573 Gy/h to a total dose of 50 kGy. Samples were characterised before and immediately after irradiation by UV-vis transmission spectra in the range of 200-800 nm. The induced absorption coefficient and loss of transmission due to irradiation were attributed to the nature of alkali metals as well as the host matrix. 相似文献
957.
We study a dynamic inventory and pricing optimization problem in a periodic review inventory system with setup cost and finite ordering capacity in each period. We show that the optimal inventory control is characterized by an (s,s′,p) policy in four regions of the starting inventory level. 相似文献
958.
We are concerned with an inverse problem for a degenerate linear evolution equation of first-order. Both hyperbolic and parabolic cases will be considered. We indicate sufficient conditions for the existence and uniqueness of a solution. All the results can be applied to inverse problems for equations from mathematical physics. As a possible application of the abstract theorems, some examples of partial differential equations are given. 相似文献
959.
Hongyinping Feng Shengjia Li 《Nonlinear Analysis: Theory, Methods & Applications》2012,75(4):2273-2280
In this paper we consider the wave equation with nonlinear damping and source terms. We are interested in the interaction between the boundary damping −|yt(L,t)|m−1yt(L,t) and the interior source |y(t)|p−1y(t). We find a sufficient condition for obtaining the blow-up solution of the problem. Furthermore, we also obtain that the solution may blow up even if m≥p. 相似文献
960.
Won Keun Min 《Applied Mathematics Letters》2012,25(3):310-314
We introduce and study the concept of similarity between soft sets, which is an extension of the equality for soft set theory. We also introduce the concepts of conjunction parameter (α∧β) and disjunction parameter (α∨β) of ordered pair parameter 〈α,β〉 for soft set theory, and we investigate modified operations of soft set theory in terms of ordered parameters. 相似文献