Sunlight curable hybrid organic–inorganic methacrylic‐based coatings: analysis of the cure mechanism and functional properties

An experimental ultraviolet (UV) polymerizable hybrid organic–inorganic protective coating, mainly intended for the surface protection of porous calcareous stone substrates, has been recently proposed and patented. The hybrid product evidenced an extraordinary hydrophobicity character, able to guarantee a high protection of the stone against water actions, as well as a high traspirability. Furthermore, it is able to equal the performance of commercial available coatings, with the important adjunctive advantage to be free solvent. The application of this product involves the use of a “dual curing” treatment, necessary to harden the coating applied on the substrate, representing this latter a technological limit. The dual curing treatment consists of 6 hr of exposure to a UV‐lamp plus 1 hr at 140°C in oven. In order to avoid this procedure, not easy to realize in situ, two different modifications of the composition of the hybrid product are proposed in this paper. The first one allows the photopolymerization of the hybrid coating only by sunlight exposure. The second one, even though requiring a UV exposure to photo‐polymerize the coating, does not need the subsequent thermal treatment at 140°C. Several experimental characterizations were performed on the newly developed hybrid products, in order to select an optimal composition for the formulations. The selected innovative products were, finally, applied on a calcareous stone substrate, typical of Apulia Region (Pietra Leccese, PL). Both coatings exhibit excellent water‐repellent action and a slight variation of the natural stone color. Copyright © 2014 John Wiley & Sons, Ltd.     

Stress concentration around a spheroidal crack caused by a harmonic wave incident at an arbitrary angle

A method is proposed to study the stress concentration around a shallow spheroidal crack in an infinite elastic body. The stress concentration is due to the diffraction of a low-frequency plane longitudinal wave by the crack. The direction of wave propagation is established in which the combined concentration of mode I and mode II stresses is maximum __________ Translated from Prikladnaya Mekhanika, Vol. 42, No. 1, pp. 70–77, January 2006.     

Interaction of shock waves during the passage of a disrupted meteoroid through the atmosphere

The motion of fragments following disintegration of a meteoroid during its flight through the Earth's atmosphere is investiated. Shock wave configurations, aerodynamical forces and moments acting on each fragment and the trajectories of the pieces are determined for hypothetical initial configurations. The results of numerical simulations show that a meteoroid's breakup may lead to both increase and decrease of the total cross section, drag forces and energy release in the atmosphere. As a consequence the emitted radiation varies.     

Bidirectional soliton street

The bidirectional long-wave model introduced by Wu (1994)^[1] and Yih & Wu (1995)^[2] is applied to evaluate interactions between multiple solitary waves progressing in both directions in a uniform channel of rectangular cross-section and undergoing collisions of two classes, one being head-on and the other overtaking collisions between these solitons. For a binary head-on collision, the two interacting solitary waves are shown to merge during a phase-locking period from which they reemerge separated, each asymptotically recovering its own initial identity while both being retarded in phase from their original pathlines. For a binary overtaking collision between a soliton of height α₁ overtaking a weaker one of height α₁, the two solition peaks are shown to either pass through each other or remain separated throughout the encounter according as α₁/α₂ or <3, respectively. With no phase locking during the overtaking, the two solitary waves re-emerge afterwards with their initial forms recovered and with the stronger wave being advanced whereas the weaker one retarded in phase from their original pathlines. By extension, the theory is generalized to apply to uniform channels of arbitrary cross-sectional shape. The Inaugural Pei-Yuan Chou Memorial Lecture, presented at The Sixth Asian Congress of Fluid Mechanics. Singapore, 21–26 May 1995     

Topography and Dispersion Effects in Bottom Layer Dynamics

A hyperbolic model of a shallow water flow is considered with allowance for nonlinear and dispersion effects. The structure of traveling waves above a flat bottom is studied. Stability of small disturbances of a homogeneous flow and development of instability of a nonstationary flow above an inclined bottom are analyzed.     

The estimate and measurement of longitudinal wave intensity

Quasi-longitudinal waves are one type of structural waves, which are important at high frequencies. This paper studies the estimate theory and measurement technique of quasi-longitudinal waves, analyzes the bias error due to the effect of bending waves. In a two-dimensional quasi-longitudinal wave field, the intensity vector is the sum of the effective intensity vector and the intensity variation vector. Its axial component is proportional to two imaginary parts of cross spectral densities and in the measurement, it is measured by a pair of two-transducer arrays. In a onedimensional quasi-longitudinal wave field, the intensity variation is zero, the intensity is proportional to only one imaginary part of a cross spectral density and it can be measured using a two-transducer array. If bending and quasi-longitudinal waves coexist and the contribution from bending waves cannot be eliminated or reduced to a certain extent, the measured quasi-longitudinal wave intensity will contain a large error. The results measured on the three-beam structure show that quasi-longitudinal wave intensity can be accurately measured using the intensity technique when bending waves are negligible in comparison with quasi-longitudinal waves. The project supported by the National Natural Science Foundation of China     

The wave attenuation on the mud bed

In the paper the wave attenuation in a two layer fluid system is studied. The fluid in the top layer is ideal and that in the lower layer is the Voigt model of the viscoelastic medium. A dispersion relation is derived and the rate of the wave decay is computed. The approximate explicit expressions of the decay rate for different water depth are given, where the viscoelasticity is either very large or very small. Compared with the numerical results, our results are very accurate, which can be used by an engineer. The project supported by the National Natural Science Foundation of China and by the Lianyungang Port Office, China     

THE EXACT SOLITARY WAVE SOLUTIONS FOR THE KLEIN-GORDON-SCHR(O)DINGER EQUATIONS

The solitary wave solutions for the Klein-Gordon-Schrodinger Equations were obtained by using the homogeaeous balance principle. The form of the solutions is more generalized than the result that has been proved by pure theoretical and qualitative method in literature;namely, the form of solutions in literature is a particular case of result of the present paper.     

Evolution of a fast flame behind an induction zone

It has been shown that pressure waves can have a large effect on the burning rate of flames. In this paper, the evolution of convection-driven fast flame, which is acoustically linked to a shock wave via an induction zone, is examined in detail. It is found that there is positive feedback mechanism and the asymptotic model breaks down as blow up occurs. Comparison is made between the case of a piston driving a shock wave into a combustible atmosphere with these studies of a shock wave passing through an existing premixed flame. Received 4 August 1995 / Accepted 20 March 1996     

Higher Harmonic Operations of Submillimeter Wave Gyrotrons (Gyrotron FU Series)

Higher harmonic operation of gyrotrons is necessary to obtain high frequencies. Some gyrotrons included in the Gyrotron FU series developed at Fukui University have achieved operation at the third and even fourth harmonics of the electron cyclotron frequency. The output lies in the millimeter to submillimeter wavelength range and the output powers are several watts to several tens of watts. In this paper, the gyrotrons and the conditions under which they operate are described in detail.